Eco-friendly lake pigment from sappanwood: Adsorption study and its application as natural colorant for natural rubber toy balloon
Keywords:Sappanwood, lake pigment, adsorption, natural colorant, Toy balloon
Due to the awareness of the impact of synthetic dye on human health and the environment, natural dye and lake pigment have attracted considerable attention from researcher. Herein, pink−red lake pigment from sappanwood was prepared using adsorption approach. The effects of initial pH, pH and concentration of brazilein solution, dosage of aluminium hydroxide, and adsorption time on adsorption were also explored. Results showed that the maximum adsorption capacity of 30 mg g-1 was achieved when 0.25%w/v of aluminium hydroxide and 100 mg L-1 of brazilein solution were applied. The adsorption kinetics and adsorption isotherm fitted the pseudo second order model and Langmuir isotherm, respectively. Additionally, this lake pigment can be utilized as a natural colorant for natural rubber toy balloons, which could made toy balloon safer for children than synthetic dye. Thus, our lake pigment can be an alternative choice of safe and environmental friendly colorant for products including toys.
H. Rymbai, R. R. Sharma, and M. Srivastav, “Bio-colorants and its implications in health and food industry–A review,” International Journal of Pharmacological Research, vol. 3(4), pp. 2228-2244, 2011.
M. Yusuf, M. Shabbir, and F. Mohammad, “Natural colorants: Historical, processing and sustainable prospects,”Natural Products and Bioprospecting, vol. 7(1), pp. 123-145, 2017.
B. Lellis, C. Z. Fávaro-Polonio, J. A. Pamphile, and J. C. Polonio, “Effects of textile dyes on health and the environment and bioremediation potential of living organisms,” Biotechnology Research and Innovation, vol. 3, pp. 275-290, 2019.
P. S. Vankar, and D. Shukla, New Trends in Natural Dyes for Textiles, Woodhead Publishing, United Kingdom, 2019.
A. Guha, “A review on sources and application of natural dyes in textiles,” International Journal of Textile Science, vol. 8(2), pp. 38-40, 2019.
M. Shahid, F. Mohammad, and S. -u. Islam, “Recent advancements in natural dye applications: A review,” Journal of Cleaner Production, vol. 53, pp. 310-331, 2013.
M. Yusuf, A. Ahmad, M. Shahid, M. I. Khan, S. A. Khan, N. Manzoor, and F. Mohammad, “Assessment of colorimetric, antibacterial and antifungal properties of woollen yarn dyed with the extract of the leaves of henna (Lawsonia inermis),” Journal of Cleaner Production, vol. 27, pp.42-50, 2012.
S. A. Khan, M. I. Khan, M. Yusuf, M. Shahid, F. Mohammad, and M.A. Khan, Handbook of renewable materials for coloration and finishing. Yusuf, ed., John Wiley & Sons, 2011.
S. A. Khan, M. I. Khan, M. Yusuf, M. Shahid, F. Mohammad, and M.A. Khan, “Natural dye shades on woollen yarn dyed with
Kamala (Mallotus philippinensis)using eco-friendly metal
mordants and their combination,” Colourage, vol. 58(11), pp. 38-44, 2011.
A. P. Periyasamy, and J. Militky, “Sustainability in textile dyeing: Recent developments,” Sustainability in the Textile and Apparel Industries, pp.37-79, 2020.
M. Yusuf, “Synthetic dyes: A threat to the environment and water ecosystem,” in Textiles and Clothing, M. Shabbir (Ed.), 2019, pp. 11-26.
H. Ali, “Biodegradation of synthetic dyes—A review,” Water, Air, & Soil Pollution, vol. 213(1), pp. 251-273, 2010.
K. Prabhu, and A. S. Bhute, “Plant based natural dyes and mordants: A Review,” Journal of Natural Product and Plant Resources, vol. 2, pp. 649-664, 2012.
M. Yusuf, M. Shahid, M. I. Khan, S. A. Khan, M. A. Khan, and F. Mohammad, “Dyeing studies with henna and madder: A research on effect of tin (II) chloride mordant,” Journal of Saudi Chemical Society, vol. 19(1), pp. 64-72, 2015.
M. Yusuf, S. A. Khan, M. Shabbir, and F. Mohammad, “Developing a shade range on wool by madder (Rubia cordifolia) root extract with gallnut (Quercus infectoria) as biomordant,” Journal of Natural Fibers, vol. 14(4), pp. 597-607, 2017.
M. Yusuf, M. A. Khan, and F. Mohammad, “Investigations of the colourimetric and fastness properties of wool dyed with colorants extracted from Indian madder using reflectance spectroscopy,” Optik, vol. 127(15), pp. 6087-6093, 2016.
R. Naveed, I. A. Bhatti, S. Adeel, A. Ashar, I. Sohail, M. U. H. Khan, N. Masood, M. Iqbal, and A. Nazir, “Microwave-assisted extraction and dyeing of cotton fabric with mixed natural dye from Pomegranate Rind (Punica Granatum L.) and Turmeric Rhizome (Curcuma Longa L.),” Journal of Natural Fibers, pp.1-8, 2020.
M. Shahid, A. Ahmad, M. Yusuf, M. I. Khan, S. A. Khan, N. Manzoor, and F. Mohammad, “Dyeing, fastness and anti-microbial properties of woolen yarns dyed with gallnut (Quercus infectoria Oliv.) extract,” Dyes and Pigments, vol. 95(1), pp.53-61, 2012.
M. I. Khan, S. A. Khan, M. Yusuf, M. Shahid, F. Mohammad, and M. A. Khan, “Eco-friendly shades on wool using mixed mordants with Acacia catechu (Cutch),” Colourage, vol. 57(8), pp.81-88, 2010.
J. G. Krishna, S. M. Basheer, P. S. Beena, and M. Chandrasekaran, “Marine bacteria as source of pigment for application as dye in textile industry,” In Proc Internatl Conf Biodiv Conserv Mgt, vol. 1, pp. 743-744, 2008.
M. Norman, P. Bartczak, J. Zdarta, H. Ehrlich, and T. Jesionowski, “Anthocyanin dye conjugated with Hippospongia communis marine demosponge skeleton and its antiradical activity,” Dyes and Pigments, vol. 134, pp.541-552, 2016.
K. Mekala, and R. Radha, “A review on sappan wood-a therapeutic dye yielding tree,” Research Journal of Pharmacognosy and Phytochemistry, vol. 7(4), pp. 227-231, 2015.
R. Rondão, J. S. R. Seixas de Melo, J. O. Pina, M. J. Melo, T. Vitorino, and A. J. Parola, “Brazilwood reds: the (photo) chemistry of brazilin and brazilein”, Journal of Physical Chemistry A, vol. 117 (41), pp. 10650-10660, 2013.
L. F. de Oliveira, H. G. Edwards, E.S. Velozo, and M. Nesbitt, “Vibrational spectroscopic study of brazilin and brazilein, the main constituents of brazilwood from Brazil,” Vibrational Spectroscopy. vol. 28, pp. 243-249, 2002.
D-K. Lee, D-H. Cho, J-H. Lee, and H Y. Shin, “Fabrication of nontoxic natural dye from sappan wood,” Korean Journal of Chemical Engineering, vol. 25, pp. 354-358, 2008.
P. Ohama, and N. Tumpat, “Textile dyeing with natural dye from Sappan tree (Caesalpinia sappan Linn) extract,” International Journal of Chemical, Biomolecular, Metallurgical, Materials Science and Engineering, vol. 8, pp. 432-435, 2014.
R. Carle, and R. Schweiggert, Handbook on natural pigments in food and beverages: Industrial applications for improving food color, Woodhead Publishing, United Kingdom, 2016.
H. De Clermont-Gallerande, C. Dacruz, C. Brunet, and A. De La Sayette-Saby, “Cosmetic material comprising a sappan wood extract on a clay substrate,” Google Patents, 2013.
R. Dapson, and C. Bain, “Brazilwood, sappanwood, brazilin and the red dye brazilein: From textile dyeing and folk medicine to biological staining and musical instruments,” Biotechnic & Histochemistry, vol. 90(6), pp. 401-423, 2015.
N. P. Nirmal, M. S. Rajput, R. G. Prasad, and M. Ahmad, “Brazilin from Caesalpinia sappan heartwood and its pharma-cological activities: A review,” Asian Pacific Journal of Tropical Medicine, vol. 8(6), pp. 421-430, 2015.
H. Hridya, A. Amrita, M. Sankari, C. G. P. Doss, M. Gopalakrishnan, C. Gopalakrishnan, and R. Siva, “Inhibitory effect of brazilein on tyrosinase and melanin synthesis: Kinetics and in silico approach,” International Journal of Biological Macromolecules, vol. 81, pp. 228-234, 2015.
L-Y. Tao, J-Y. Li, and J-Y. Zhang, “Brazilein, a compound isolated from Caesalpinia sappan Linn, induced growth inhibition in breast cancer cells via involvement of GSK-3β/β-Catenin/cyclin D1 pathway,” Chemico-Biological Interactions, vol. 206(1), pp. 1-5, 2015.
A. Petdum, T. Sooksimuang, N. Wanichacheva, and J. Sirirak, “Natural colorimetric sensor from sappanwood for turn-on selective Fe2+ detection in aqueous media and its application in water and pharmaceutical samples,” Chemistry Letters, vol. 48(7), pp. 678-681, 2019.
J. Kirby, M. van Bommel, and A. Verhecken, Natural colorants for dying and lake pigments:practical recipes and their historical sources, Archetype Publications Ltd, London, United Kingdom, 2014.
S. Marras, “Natural colorants for dyeing and lake pigments”, Ge-conservación, pp. 61-62, 2015.
S. V. Berbers, D. Tamburini, M. R. van Bommel, and J. Dyer, “Historical formulations of lake pigments and dyes derived from lac:A study of compositional variability,”Dyes and Pigments, vol. 170, pp. e107579, 2019.
A. Jimtaisong, “Aluminium and calcium lake pigments of Lac natural dye,” Brazilian Journal of Pharmaceutical Sciences, vol. 56, pp. e18140, 2020.
T. Vitorino, M. J. Melo, L. Carlyle, and V. Otero, “New insights into brazilwood lake pigments manufacture through the use of historically accurate reconstructions,” Studies in Conservation, vol. 61, pp. 255-273, 2016.
C. Clementi, B. Doherty, P. L. Gentili, C. Miliani, A. Romani, B. G. Brunetti, and A. Sgamellotti, “Vibrational and electronic properties of painting lakes,” Applied Physics A, vol. 92, pp. 25-33, 2018.
J. Sirirak, N. Worawannotai, C. Suwanchawalit, and S. Chayabutra, “Preparation and characterization of lake pigments from sappan wood using Thai local clays,” Journal of Metals, Materials and Minerals, vol. 30(1), pp. 20-28, 2020.
S. Girdthep, J. Sirirak, D. Daranarong, R. Daengngern, and S. Chayabutra, “Physico-chemical characterization of natural lake pigments obtained from Caesalpinia Sappan Linn. and their composite films for poly (lactic acid)-based packaging materials,” Dyes and Pigments, vol. 157, pp. 27-39, 2018.
C. Vadeesirisak, S. Chayabutra, and J. Sirirak, “Effect of species and preparation of mango leaves on lake pigments from mango leaves prepared by adsorption Method,” Burapha Science Journal, vol. 25(2), pp. 545-562, 2020.
S. Singla, M. Mathur, C. S. Chauhan, S. Goyal, and M. Junaid, “Formulation and charcterization of lake color obtained from red cabbage,” Indian Journal of Pharmaceutical and Biological Research, vol. 4(01), pp. 50-56, 2016.
F. Fournier, L. de Viguerie, S. Balme, J.-M, Janot, P. Walter, and M. Jaber, “Physico-chemical characterization of lake pigments based on montmorillonite and carminic acid,” Applied Clay Science, vol. 130, pp. 12-17, 2016.
S. Shivali, S. Goyal, H. Paliwal, M. Mathur, C. C. Singh, and D. Shashi, “Lake color formulation of beet root extract and its optimization,” International Journal of Pharmaceutical Sciences Review and Research, vol. 40, pp. 86-91, 2016.
D. Krewski, R. A. Yokel, E. Nieboer, D. Borchelt, J. Cohen, J. Harry, S. Kacew, J. Lindsay, A.M. Mahfouz, and V. Rondeau, “Human health risk assessment for aluminium, aluminium oxide, and aluminium hydroxide,” Journal of Toxicology and Environmental Health, Part B, vol. 10, pp. 1-269, 2007.
R. A. Robinson, and H. T. S. Britton, “CCCXCII.—The amphoteric nature of aluminium hydroxide,” Journal of the Chemical Society (Resumed), pp. 2817-2820, 1931.
C. M. Reinke, J. Breitkreutz, and H. Leuenberger, “Aluminium in over-the-counter drugs,” Drug Safety, vol.26(14), pp.1011-1025, 2003.
H. Kathyayini, I. Willems, A. Fonseca, J. B. Nagy, and N. Nagaraju, “Catalytic materials based on aluminium hydroxide, for the large scale production of bundles of multi-walled (MWNT) carbon nanotubes,” Catalysis Communications, vol. 7(3), pp. 140-147, 2006.
B. Uçar, A. Güvenç, and Ü. Mehmetoglu, “Use of aluminium hydroxide sludge as adsorbents for the removal of reactive dyes: equilibrium, thermodynamic, and kinetic studies,” Hydrology: Current Research, vol. 2(2), pp. e1000112, 2011.
L. Gianfreda, M. Rao, and A. Violante, “Adsorption, activity and kinetic properties of urease on montmorillonite, aluminium hydroxide and AL (OH) x-montmorillonite complexes,” Soil Biology and Biochemistry, vol. 24(1), pp. 51-58, 1992.
G. Micera, C. Gessa, P. Melis, A. Premoli, R. Dallocchio, and S. Deiana, “Zinc (II) adsorption on aluminium hydroxide”, Colloids and Surfaces, vol. 17(4), pp. 389-394, 1986.
S. Berger, and D. Sicker, Classics in spectroscopy: isolation and structure elucidation of natural products, John Wiley & Sons, New York, 2009.
M. Fatiha, and B. Belkacem, “Adsorption of methylene blue from aqueous solutions using natural clay,” Journal of Materials and Environmental Science, vol. 7(1), pp. 285-292, 2016.
P. Suppharatthanya, S. Chaneam, P. Limpachayaporn, and J. Sirirak, “Kinetics and isotherm study of the adsorption of brazilien from sappanwood on montmorillonite,”Thai Science and Technology Journal, vol 27(6), pp. 989-1001, 2018.
P. Suppharatthanya, S. Chayabutra, and J. Sirirak, “Adsorption kinetics of natural dye (sappanwood)on aluminium oxide,” Proceeding the 13th International Conference on Ecomaterials (ICEM2017), 2017, pp. 88-92.
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