Interfacial polymerization of water-soluble polyaniline and its assembly using the layer-by-layer technique

Authors

  • Ekarat Detsri Graduate School of Nanoscience and Technology, Chulalongkorn University
  • Stephan Thierry Dubas Metallurgy and Materials Science Research Institute, Chulalongkorn University

Keywords:

Polyaniline, Interfacial polymerization, Layer-by-layer

Abstract

The interfacial polymerization of aniline has been used to prepare water-soluble polyaniline. Polyaniline was made water-soluble by interfacial polymerization in the presence of poly(styrene sulfonated, sodium salt) (PSS), which acted as bundling agent to provide water solubility. The prepared polymer composite was later used for the fabrication of polyaniline nano-thin films using the layer-by-layer (LbL) self-assembly technique. Film produced by the LbL technique can be used in electro-chromic films, sensors or electro-catalytic films depending on the type of architectures. This paper first presents, a brief review on conducting polymer prepared by interfacial polymerization. Special interest is given to the synthesis of water-soluble polyaniline by interfacial polymerization in the presence of PSS. In a second part, the authors provide original results concerning the LbL self-assembly of polyaniline into nano-thin films. The PSS concentration used in the polyaniline synthesis is discussed regarding its effect on the growth of LbL composite thin films.

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Published

2017-04-15

How to Cite

[1]
E. . Detsri and S. T. Dubas, “Interfacial polymerization of water-soluble polyaniline and its assembly using the layer-by-layer technique”, J Met Mater Miner, vol. 19, no. 1, Apr. 2017.

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