A Preliminary Study on the Preparation of Environmentally Friendly Materials from Modified Glutinous Starch
Keywords:
glutinous starch, modification, biodegradableAbstract
Modified glutinous starch was prepared from the reaction between glutinous starch and maleic anhydride using sodium hydroxide as a catalyst and water as a solvent at 50oC. The modification conditions with respect to the amounts of maleic anhydride were 5%, 15%, 25%, 35%, 50%, 65%, 75% and 85% and to the reaction times were 30, 60, 90 and 120 minutes. After the reaction finished, the obtained products were neutralized by adding hydrochloric acid solution and the chemical structures of the modified glutinous starches were determined by FT-IR spectroscopy. The sheet samples were prepared from modified starches by casting and their characteristics including drying time, moisture absorption ability and tensile properties were investigated. It was found that both the amount of maleic anhydride and the reaction time affected the characteristics of the obtained sheets. Suitable modification conditions which result in the sheet sample exhibiting better overall characteristics than those prepared with other conditions was at 35% of maleic anhydride and a reaction time of 30 minutes.
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