A contribution to the exploration of the chemical durability, thermal stability, and structural ability of glasses from the Fe\(_{2}\)O\(_{3}\)-K\(_{2}\)O-MoO\(_{3}\)-P\(_{2}\)O\(_{5}\) quaternary system

Asmae ER-RAFAI; Yasmina ALAOUI; Mohamed  LAOURAYED; Mohamed  OUNACER; Mouloud EL MOUDANE; Mohammed   SAJIEDDINE; Abdelkbir BELLAOUCHOU

doi:10.55713/jmmm.v34i1.1787

Authors

Asmae ER-RAFAI Laboratory of Materials, Nanotechnology, and Environment, Faculty of Science, Mohammed V University in Rabat, P.O. Box. 1014, Agdal-Rabat, Morocco
Yasmina ALAOUI Laboratory of Materials, Nanotechnology, and Environment, Faculty of Science, Mohammed V University in Rabat, P.O. Box. 1014, Agdal-Rabat, Morocco
Mohamed LAOURAYED Laboratory of Materials, Nanotechnology, and Environment, Faculty of Science, Mohammed V University in Rabat, P.O. Box. 1014, Agdal-Rabat, Morocco
Mohamed OUNACER Physic of Materials Laboratory, FST, Sultan Moulay Slimane University, Beni-Mellal, Morocco
Mouloud EL MOUDANE Laboratory of Materials, Nanotechnology, and Environment, Faculty of Science, Mohammed V University in Rabat, P.O. Box. 1014, Agdal-Rabat, Morocco
Mohammed SAJIEDDINE Physic of Materials Laboratory, FST, Sultan Moulay Slimane University, Beni-Mellal, Morocco
Abdelkbir BELLAOUCHOU Laboratory of Materials, Nanotechnology, and Environment, Faculty of Science, Mohammed V University in Rabat, P.O. Box. 1014, Agdal-Rabat, Morocco

DOI:

https://doi.org/10.55713/jmmm.v34i1.1787

Keywords:

Phosphate glasses, Iron oxide, IR et Raman, Mössbauer spectroscopy, Chemical durability

Abstract

The relationships between the properties and structure of xFe₂O₃-(40-x)K₂O-10MoO₃-50P₂O₅glasses have been reported in this paper. Homogeneous glasses are formed for different Fe₂O₃contents. The density and molar volume evolution of these glasses shows that Fe₂O₃ acts as a glass former and strengthens the structural bonds of the glass. Experimental ⁵⁷Fe Mössbauer spectroscopy graphs suggest the existence of divalent Iron (Fe^II) and trivalent Iron (Fe^III). The boost in chemical durability agrees with the growth in glass transition temperature due to more powerful bonding in the structural network. P-O-Fe bonds replace P-O-P bonds when Fe₂O₃ is present in the phosphate network.

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