Interfacial polymerization of water-soluble polyaniline and its assembly using the layer-by-layer technique
Keywords:
Polyaniline, Interfacial polymerization, Layer-by-layerAbstract
The interfacial polymerization of aniline has been used to prepare water-soluble polyaniline. Polyaniline was made water-soluble by interfacial polymerization in the presence of poly(styrene sulfonated, sodium salt) (PSS), which acted as bundling agent to provide water solubility. The prepared polymer composite was later used for the fabrication of polyaniline nano-thin films using the layer-by-layer (LbL) self-assembly technique. Film produced by the LbL technique can be used in electro-chromic films, sensors or electro-catalytic films depending on the type of architectures. This paper first presents, a brief review on conducting polymer prepared by interfacial polymerization. Special interest is given to the synthesis of water-soluble polyaniline by interfacial polymerization in the presence of PSS. In a second part, the authors provide original results concerning the LbL self-assembly of polyaniline into nano-thin films. The PSS concentration used in the polyaniline synthesis is discussed regarding its effect on the growth of LbL composite thin films.Downloads
References
Ambrosi, A., Morrin, A., Smyth, M.R. and Killard, A.J. 2008. The application of conducting polymer nanoparticle electrodes to the sensing of ascorbic acid. Anal. Chim. Acta. 609 : 37–43.
Brazdziuviene, K., Jureviciute, I. and Malinauskas, A. 2007. Raman spectroelectrochemical study of polyaniline and sulfonated polyaniline in solutions of different pH. Electrochim. Acta. 53 : 785–791.
Wang, Y.Y. and Jing, X.L. 2004. Preparation of an epoxy/polyaniline composite coating and its passivation effect on cold rolled steel. Polym. J. 36 : 374–379.
Ghanbari, K., Mousavi, M.F. and Shamsipur, M. 2007. Synthesis of polyaniline/graphite composite as a cathode of Zn-polyaniline rechargeable battery. J. Power. Sources. 170 : 513–519.
Paul, R.K., Pillai, C.K.S. and Mattes, B.R. 2000. Melt/solution processable conducting polyaniline with novel sulfonic acid dopants and its thermoplastic blends. Synth. Met. 114 : 27-35.
Blinova, N.V., Stejskal, J., Trchova, M., Prokes, J. and Omastova, M. 2007. Polyaniline and polypyrrole: A comparative study of the preparation. Eur. Polym. J. 43 : 2331-2341.
Nuraje, N., Su, K., Yang, N.L. and Matsui, H. 2008. Liquid/liquid interfacial polymerization to grow single crystalline nanoneedles of various conducting polymers. ACS Nano 2 : 502-506.
Sarkar, N., Ram, M.K., Sarkar, A., Narizzana, R., Paddeu, S. and Nicolini, C. 2000. Nanoassemblies of sulfonated polyaniline multilayers, Nanotechnology. 11 : 30-36.
Barros, R.A., Azevedo, W.M. and Aguiar, F.M. 2003. Photo-induced polymerization of polyaniline. Mater. Charact. 50 : 131-134.
Lui, W., Kumar, J. and Tripathy, S. 1999. Enzymatically synthesized conducting polyaniline. J. Am. Chem. Soc. 121 : 71-78.
Dong, H., Prasad, S., Nyame, V. and Jones, W. 2004. Sub-micrometer conducting polyaniline tubes prepared from polymer fiber templates. Chem. Mater. 16 : 371-373.
Wei, X.L., Wang, Y.Z., Long, S.M., Bobeczko, C. and Epsteib, A.J. 1996. Synthesis and physical properties of highly sulfonated polyaniline. J. Am. Chem. Soc. 118 : 2545 -2555.
Roy, B.C., Gupta, M.D., Bhowmik, L. and Ray, J.K. 1999. Studies on water soluble conducting polymer-Aniline initiated polymerization of m-aminobenzene sulfonic acid. Synth. Met. 100 : 233-236.
Mirmohseni, A. and Houjaghan, M.R. 2008. Synthesis and characterization of water-soluble conducting poly (3-amino-4-methoxybenzenesulfonic acid). Mol. Cryst. Liq. Cryst. 484 : 722- 727.
Atkinson, S., Chan, H.S.O. and Neuendorf, A.J. 2000. Synthesis of the water-soluble, electrically conducting poly(5-aminonaphthalene- 2-sulfonic acid). Chem. Lett. 3 : 276-277.
Feng, J.L., Huang, L.M. and Wen, T.C. 2007. Interfacial synthesis of platinum loaded polyaniline nanowires in poly(styrene sulfonic acid). Mat. Lett. 61 : 4400-4405.
Zhang, X.Y., Chan-Yu-King, R. and Jose, A. 2004. Nanofibers of polyaniline synthesized by interfacial polymerization. Synth. Met. 145 : 23-29.
Hopkins, A.R., Sawall, D.D., Villahermosa, R.M. and Lipeles R.A. 2004. Electrically conducting polyaniline microtube blends. Thin. Solid. Films. 469 : 304-308.
Dallas, P., Stamopoulos, D., Boukos, N., Tzitzios, V., Niarchos, D. and Petridis, D. 2007. Characterization, magnetic and transport properties of polyaniline synthesized through interfacial polymerization. Polymers. 48 : 3162-3169.
Kaner, R.B. and Huang, J. 2004. A general chemical route to polyaniline nanofibers. J. Am. Chem. Soc. 126 : 851-855.
Nohria, R., Khillan, R.K. and Su. Y. 2006. Humidity sensor based on ultrathin polyaniline film deposited using layer-by-layer nano-assembly. Sensor Actuat. B-Chem. 114 : 218-222.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2017 Journal of Metals, Materials and Minerals
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Authors who publish in this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.