Temperature dependence of dielectric properties for BFO-BTO-BZT ceramics

Authors

  • Sujitra Unruan Faculty of Engineering and Architecture, Rajamangala University of Technology Isan
  • Muangjai Unruan Faculty of Sciences and Liberal Arts, Rajamangala University of Technology Isan
  • Rattikorn Yimnirun School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology

Keywords:

BFO-BTO-BZT, Ferromagnetism, Dielectric properties

Abstract

In this work, bismuth ferrite-barium titanate-barium zirconate titanate (BFO-BTO-BZT) ceramics were prepared using conventional solid state reaction method. The (1-x)BiFeO3-xBaTiO3 at x = 0.24-0.30 and Ba(Zr,Ti)O3 (Zr = 0.5) systems were separately prepared and calcined at 800 and 1250oC, respectively. All pallets were sintered at temperature of 1100oC. After that, the relationship between phase formation, dielectric and magnetic properties were examined. The XRD patterns revealed that more structural symmetry could be observed in all single-phase perovskite ceramics when more BTO concentration was added. The 0.75(0.70BFO-0.30BTO)-0.25BZT ceramic showed highest dielectric constant with high loss measured at low frequency observed, possibly due to space charges, interfacial and dipolar polarizations. The temperature-dependent dielectric properties of BFO-BTO-BZT solid solutions were measured in TN temperature range. It was found that the addition of BTO content affected the position of TN.  Especially, the BFO-BTO-BZT solid solutions successfully improved the magnetic properties of BFO-BTO with typical ferromagnetic hysteresis loops. The maximum Mr with 0.1632 emu·g-1 was observed in 0.75(0.72BFO-0.28BTO)-0.25BZT sample.

Downloads

Download data is not yet available.

References

K. F. Wang, J. M. Liu, and Z. F. Ren, “Multiferroicity: the coupling between magnetic and polarization orders,” Advances in Physics, vol. 58, pp. 321-448, 2009.

C. W. Nan, M. I. Bichurin, S. X. Dong, D. Viehland, and G. Srinivasan, “Multiferroic magnetoelectric composites L historical perspective, status, and future directions,” Journal of Applied Physics, vol. 103, pp. 1- 35, 2008.

W. Eerenstein, N. D. Mathur, and J. F. Scott, “Multiferroic and magnetoelectric materials,” Nature, vol. 442, pp. 759-765, 2006.

M. Bibes and A. Barthelemy, “Multiferroics: towards a magnetoelectric memory,” Nature Materials, vol. 7, pp. 425-426, 2008.

H. Palneedi, V. Annapureddy, S. Priya, and J. Ryu, “Status and perspectives of multiferroic magnetoelectric composite materials and applications,” Actuators, vol. 5, pp. 1-31, 2016.

H. Y. Dai, J. Chen, T. Li, D. W. Liu, R. Z. Xue, H. W. Xiang, and Z. P. Chen, “Effect of BaTiO3 doping on the structural, electrical and magnetic properties of BiFeO3 ceramics,” Journal of Materials Science: Materials in Electronics, vol. 26, pp. 3717-3721, 2016.

J. M. Moreau, C. Michel, R. Gerson, and W. J. James, “Ferroelectric BiFeO3 X-ray and neutron diffraction study,” Journal of Physics and Chemistry of Solids, vol. 32, pp. 1315- 1320, 1971.

J. G. Wu, J. Wang, D. Q. Xiao, and J. G. Zhu, “A method to improve electrical properties of BiFeO3 thin films,” ACS Applied Materials & Interfaces, vol. 4, pp. 1182-1185, 2012.

S. Pattanayak, R. N. P. Choudhary, and D. Pattanayak, “Comparative study of structural, electrical and magnetic properties rare-earth (Dy and Nd)-modified BiFeO3,” Journal of Materials Science: Materials in Electronics, vol. 25, pp. 3854-3861, 2014.

D. Khomskii, “Multiferroics: different ways to combine magnetism and ferroelectricity,” Journal of Magnetism and Magnetic Materials, vol. 306, pp. 1-8, 2006.

N. A, Hill, “Why are there so few magnetic ferroelectrics?,” The Journal of Physical Chemistry B, vol. 104, pp. 6694-6709, 2000.

S. W. Cheong and M. Mostovoy, “Multiferroics: a magnetic twist for ferroelectricity,” Nature Materials, vol. 6, pp. 13-20, 2007.

X. D. Qi, J. Dho, R. Tomov, M. G. Blamire, and J. L. Macmanus-Driscoll, “Greatly reduced leakage current and conduction mechanism in aliovalent-ion-doped BiFeO3,” Applied Physics Letters, vol. 86, pp. 062903-1-3, 2005.

Y. Yoneda, K. Yoshii, S. Kohara, S. Kitagawa, and S. Mori “Local structure of BiFeO3- BaTiO3 mixture,” Japanese Journal of Applied Physics, vol. 47, pp. 7590-7594, 2008.

M. Shariq, D. Kaur, V. S. Chandel, and M. A. Siddiqui, “Electrical, surface morphology and magneto-capacitance properties of Pb free multiferroic (BiFeO3)1−x(BaTiO3)x solid solutions,” Acta Physica Polonica A, vol. 127, pp. 1675-1679, 2015.

N. Itoh, T. Shimura, W. Sakamoto, and T. Yogo, “Fabrication and characterization of BiFeO3-BaTiO3 ceramics by solid state reaction,” Ferroelectrics, vol. 357, pp. 19-23, 2007.

R. A. M. Gotardo, D. S. F. Viana, M. OlzonDionysio, S. D. Souza, and D. Garcia, “Ferroic states and phase coexistence in BiFeO3-BaTiO3 solid solutions,” Journal of Applied Physics, vol. 112, pp. 1-7, 2012.

T. Futakuchi, T. Kakuda, and Y. Sakai, “Multiferroic properties of BiFeO3-BaTiO3 based ceramics,” Journal of the Ceramic Society of Japan, vol. 122, pp. 464-468, 2014.

P. A. Jha, P. K. Jha, A. K. Jha, and R. K. Dwivedi, “Dielectric behavior of (1−x) BaZr0.025Ti0.975O3–(x)BiFeO3 solid solutions,” Materials Research Bulletin, vol. 48, pp. 101–105, 2013.

W. Cai, S. Zhong, C. Fu, G. Chen, and X. Deng, “Microstructure, dielectric and ferroelectric properties of xBaZr0.2Ti0.8O3-(1-x)BiFeO3 solid solution ceramics,” Materials Research Bulletin, vol. 50, pp. 259-267, 2014.

M. M. Kumar, A. Srinivas, and S. V. Suryanarayana, “Structure property relations in BiFeO3/BaTiO3 solid solutions,” Journal of Applied Physics, vol. 87, pp. 855-862, 2000.

T. H. Wang, C. S. Tu, Y. Ding, T. C. Lin, C. S. Ku, W. C. Yang, H. H. Yu, K. T. Wu, Y. D. Yao, and H. Y. Lee, “Phase transition and ferroelectric properties of xBiFeO3-(1-x)BaTiO3 ceramics,” Current Applied Physics, vol. 11, pp. S240-S243, 2011.

H. Zhang, W. Jo, K. Wang, and K. G. Webber, “Compositional dependence of dielectric and ferroelectric properties in BiFeO3-BaTiO3 solid solutions,” Ceramics International, vol. 40, pp. 4759-4765, 2014.

S. Chandarak, M. Unruan, T. Sareein, A. Ngamjarurojana, S. Maensiri, P. Laoratanakul, S. Ananta, and R. Yimnirun, “Fabrication and characteriazation of (1-x)BiFeO3-xBaTiO3 ceramics prepared by solid state reaction method,” Journal of Magnetics, vol. 14, pp. 120-123, 2009.

S. O. Leontsev and R. E. Eitel, “Dielectric and piezoelectric properties in Mn-modified (1-x)BiFeO3-xBaTiO3 ceramics,” Journal of the American Ceramic Society, vol. 92, pp. 2957–2961, 2009.

X. H. Liu, Z. Xu, S. B. Qu, X. Y. Wei, and J. L. Chen, “Ferroelectric and ferromagnetic properties of Mn-doped 0.7BiFeO3-0.3BaTiO3 solid solution,” Ceramics International, vol. 34, pp. 797-801, 2008.

Downloads

Published

2019-01-10

How to Cite

[1]
S. . Unruan, M. Unruan, and R. Yimnirun, “Temperature dependence of dielectric properties for BFO-BTO-BZT ceramics”, J Met Mater Miner, vol. 28, no. 2, Jan. 2019.

Issue

Vol. 28 No. 2 (2018)

Section

Original Research Articles

License

Copyright (c) 2018 Journal of Metals, Materials and Minerals

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Authors who publish in this journal agree to the following terms:

    1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.

 

    1. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.