Biodiesel production from waste cooking oil using a new heterogeneous catalyst SrO doped CaO nanoparticles

Authors

  • Apisit Prokaewa Department of Chemistry, Faculty of Science and technology, Thammasat University, Khlong Luang, Pathum Thani 12120, Thailand
  • Siwaporn Meejoo Smith Department of Chemistry, Faculty of Science and technology, Mahidol University, Phuttamonthon, Nakorn Pathom 73170, Thailand
  • Apanee Luengnaruemitchai The Petroleum and Petrochemical College, Chulalongkorn University, Pathumwan, Bangkok 10330, Thailand
  • Mathi Kandiah School of Science, BMS, 591, Galle Road, Colombo 06, Sri Lanka
  • Supakorn boonyuen Department of Chemistry, Faculty of Science and technology, Thammasat University, Khlong Luang, Pathum Thani 12120, Thailand

DOI:

https://doi.org/10.55713/jmmm.v32i1.1149

Keywords:

Waste palm oil, Calcium oxide catalyst, Strontium modified catalyst, Transesterication

Abstract

Biodiesel production from waste palm cooking oil (WPCO) was studied. Calcium oxide with a strontium ion additive (Sr-CaO) was employed as a catalyst in transesterification reaction of used palm oil with methanol. The Sr-CaO was synthesized by co-precipitation method between SrCl2 and Ca(NO3)2, then calcined at 900°C for 5 h. The catalyst was characterized by using thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), Scanning electron microscope (SEM), and Fourier transform infrared spectrometer (FT-IR). The morphology and elements content of Sr and Ca in the catalyst were confirmed by SEM-EDX. The approximate catalyst diameter is 12.6±5.9 µm. The highest conversion was 99.33% (the reaction time 3 h, 5%w/w catalyst, methanol to oil molar ratio 9:1 and reaction temperature 80°C). The catalyst can be used up to the sixth cycles with a good yield. The synthesized biodiesel meet the requirement of standard biodiesel (EN 14103 and ASTM D445). These findings suggest that calcium oxide with a strontium ion additive (Sr-CaO) is an effective renewable biodiesel catalyst.

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Published

2022-03-29

How to Cite

[1]
A. . Prokaewa, S. . Meejoo Smith, A. . Luengnaruemitchai, M. . Kandiah, and S. boonyuen, “Biodiesel production from waste cooking oil using a new heterogeneous catalyst SrO doped CaO nanoparticles”, J Met Mater Miner, vol. 32, no. 1, pp. 79–85, Mar. 2022.

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Original Research Articles