Effect of annealing temperature on the TiO\(_{2}\) anodized films properties for dental implant application

Phanawan WHANGDEE; Wittawat  SAENRANG; Nampueng  PANGPAIBOON; Pristanuch  MASAKUL; Dujreutai Pongkao  KASHIMA

doi:10.55713/jmmm.v33i3.1617

Authors

Phanawan WHANGDEE Department of Applied Physics, Faculty of Sciences and Liberal Arts, Rajamangala University of Technology Isan, Nakhon Ratchasima, 30000, Thailand
Wittawat SAENRANG School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
Nampueng PANGPAIBOON Department of Industrial Physics and Medical Instrumentation, Faculty of Applied Science, King Mongkut's University of Technology North Bangkok, Bangkok, 10800, Thailand
Pristanuch MASAKUL Department of Applied Physics, Faculty of Sciences and Liberal Arts, Rajamangala University of Technology Isan, Nakhon Ratchasima, 30000, Thailand
Dujreutai Pongkao KASHIMA Research Unit of Advanced Ceramics, Department of Materials Science, Faculty of Science, Chulalongkorn University, Patumwan, Bangkok, 10330, Thailand; Center of Excellence on Petrochemical and Materials Technology, Chulalongkorn University, Patumwan, Bangkok, 10330, Thailand

DOI:

https://doi.org/10.55713/jmmm.v33i3.1617

Keywords:

Anodized films, Sodium fluoride, Annealing, Ti-6Al-4V

Abstract

The TiO₂ anodized films generated at low current density after annealing are good candidates for surface coating, as a hydrophilicity is a crucial characteristic that determines dental implant applications. In this study, the hydrophilicity of TiO₂ anodized films annealed at various temperatures was examined. It was found that increasing the annealing temperature during the anodization procedure improves the hydrophilicity of the TiO₂ anodized films. This is related to the evolution of the TiO₂ anodized film structure produced by raising the annealing temperature, which converts the TiO₂ anodized amorphous phase to rutile phases. Moreover, increased annealing temperature results in more oxygen vacancies, hydroxyl groups, and roughness, which further improves hydrophilicity.

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References

N. G. Krishna, R. P. George, and J. Philip, "Anomalous enhancement of corrosion resistance and antibacterial property of commercially pure Titanium (CP-Ti) with nanoscale rutile titania film," Corrosion Science, vol. 172, pp. 1-12, 2020.

A. YazdanYar, L. Buswell, D. Pantaloni, U. Aschauer, and P. Bowen, "Interactions of Tris with rutile surfaces and consequences for in vitro bioactivity testing," Open Ceramics, vol. 7, pp. 1-7, 2021.

P. Whangdee, S. Chukasorn, V. Srimaneepong, T. Watanabe, and D. Pongkao Kashima, "Effects of surface roughness and chemical species on hydrophilicity of anodized film on Ti-6Al-4V formed at a low current density," Advanced Materials Research, vol. 664, pp. 774-779, 2013.

K. Archaapinun, N. Witit-Anun, and P. Visuttipitukul, "Effect of heat treatment on phase transformation of TiO2 and its reflectance properties," Journal of Metals, Materials and Minerals, vol. 23, pp. 43-49, 2013.

S. Nisaimun, P. Poolcharuansin, P. Visuttipitukul, and P. Klomjit, "Improving corrosion resistance of 3D printed Ti-6Al-4V by TiN coating," Journal of Metals, Materials and Minerals, vol. 31, pp. 137-146, 2021.

K. Sriprasertying, and S. Rhaiphu, "The change of surface alloy compositions and corrosion behavior after WEDM machining of commercially pure titanium (grade 4) and Ti-6Al-4V (grade 5)," Journal of Metals, Materials and Minerals, vol. 21, pp. 29-35, 2011.

P. Whangdee, S. Nilmoung, N. Pangpaiboon, and D. Pongkao Kashima, "Effect of ethanol on hydrophilicity of the anodized films performed by two-step anodization at low current density," Journal of Metals, Materials and Minerals, vol. 29, pp. 60-65, 2019.

V. Poshyananda, J. Darayen, K. Tumkhanon, C. Puncreobutr, A. Khamkongkaeo, and B. Lohwongwatana, "Consideration of key process parameters for achieving robust and uniform cutting of Ti-6Al-4V sheet metal using fiber laser with nitrogen assisted gas," Journal of Metals, Materials and Minerals, vol. 28, pp. 1-10, 2018.

A. Toffoli, L. Parisi, R. Tatti, A. Lorenzi, R. Verucchi, E. Manfredi, S. Lumetti, and G. M. Macaluso, "Thermal-induced hydrophilicity enhancement of titanium dental implant surfaces," The Journal of Oral Science, vol. 62, pp. 217-221, 2020.

P. Whangdee, W. Saenrang, and D. P. Kashima, "Effect of fluoride and hydroxyl group on bioactivity of the anodized films prepared by two-step anodization at low current density," Surface and Interface Analysis, vol. 54, pp. 724-733, 2022.

P. Whangdee, S. Nilmoung, N. Pangpaiboon, and D. P. Kashima, "The effect of low current density on the hydrophilicity and surface properties of the anodized films performed by two-step anodization," SNRU Journal of Science and Technology, vol. 11, pp. 45-54, 2019.

P. Whangdee, W. Saenrang, and D. Pongkao Kashima, "Effect of surface fluorination on the hydrophilicity of the anodised films for dental implant applications," Materials Research Innovations, vol. 24, pp. 321-325, 2020.

P. Whangdee, S. Sriprasertsuk, V. Srimaneepong, and D. P. Kashima, "Surface characteristics and hydrophilicity of the as-anodized films formed at high current density on Ti-6Al-4V in Different Electrolytes," Key Engineering Materials, vol. 608, pp. 274-279, 2014.

S. Banerjee, D. D. Dionysiou, and S. C. Pillai, "Self-cleaning applications of TiO2 by photo-induced hydrophilicity and photo-catalysis," Applied Catalysis B: Environmental, vol. 176-177, pp. 396-428, 2015.

T. Kobayashi,and S. Konishi, "Acceleration of wettability switching on TiO2 thin films under ultraviolet irradiation and direct current bias voltage," Surface and Coatings Technology, vol. 363, pp. 80-86, 2019.

Y. Sun, S. Sun, X. Liao, J. Wen, G. Yin, X. Pu, Y. Yao, and Z. Huang, "Effect of heat treatment on surface hydrophilicity-retaining ability of titanium dioxide nanotubes," Applied Surface Science, vol. 440, pp. 440-447, 2018.

Y. Bai, I. S. Park, H. H. Park, M. H. Lee, T. S. Bae, W. J. Duncan, and M. V. Swain, "The effect of annealing temperatures on surface properties, hydroxyapatite growth and cell behaviors of TiO2 nanotubes," Surface and Interface Analysis, vol. 43, pp. 998-1005, 2011.

F. Nasirpouri, I. Yousefi, E. Moslehifard, and J. Khalil-Allafi, "Tuning surface morphology and crystallinity of anodic TiO2 nanotubes and their response to biomimetic bone growth for implant applications," Surface and Coatings Technology, vol. 315, pp. 163-171, 2017.

F. Hilario, V. Roche, R. P. Nogueira, and A. M. J. Junior, "Influence of morphology and crystalline structure of TiO2 nano-tubes on their electrochemical properties and apatite-forming ability," Electrochimica Acta, vol. 245, pp. 337-349, 2017.

Y. Jiang, H. Liu, K. Shi, C. Tang, and J. Song, "Effect of annealing temperature on wettability of TiO2/PDA thin films," Surface and Coatings Technology, vol. 411, pp. 1-6, 2021.

P. Rychtowski, J. Orlikowski, G. Żołnierkiewicz, and B. Tryba, "Mechanism of hydroxyl radicals formation on the reduced rutile," Materials Research Bulletin, vol. 147, pp. 1-10, 2022.

P. Wang, C. Jia, J. Li, and P. Yang, "Ti3+-doped TiO2(B)/ anatase spheres prepared using thioglycolic acid towards super photocatalysis performance," Journal of Alloys and Compounds, vol. 780, pp. 660-670, 2019.

Z. Sun, "V. F. Pichugin, K. Evdokimov, M. E. Konischev, M. Syrtanov, V. N. Kudiiarov, K. Li, and S. I. Tverdokhlovov, "Effect of nitrogen-doping and post annealing on wettability and band gap energy of TiO2 thin film," Applied Surface Science, vol. 500, pp. 1-21, 2020.

E. Blasco-Tamarit, B. Solsona, R. Sánchez-Tovar, D. García-García, R. M. Fernández-Domene, and J. García-Antón, "Influence of annealing atmosphere on photoelectrochemical response of TiO2 nanotubes anodized under controlled hydro-dynamic conditions," Journal of Electroanalytical Chemistry, vol. 897, pp. 1-13, 2021.

F. Güzelçimen, B.Tanören, Ç. Çetinkaya, M. D. Kaya, H. I. Efkere, Y. Özen, D. Bingöl, M. Sirkeci, B. Kınacı, M. B. Ünlü, S. Özçelik, "The effect of thickness on surface structure of rf sputtered TiO2 thin films by XPS, SEM/EDS, AFM and SAM," Vacuum, vol. 182, pp. 1-14, 2020.

K. H. Cheung, M. B. Pabbruwe, W.-F. Chen, P. Koshy, and C. C. Sorrell, "Thermodynamic and microstructural analyses of photocatalytic TiO2 from the anodization of biomedical-grade Ti6Al4V in phosphoric acid or sulfuric acid," Ceramics International, vol. 47, pp. 1609-1624, 2021.

Ł. Haryński, J. Karczewski, J. Ryl, K. Grochowska, and K. Siuzdak, "Rapid development of the photoresponse and oxygen evolution of TiO2 nanotubes sputtered with Cr thin films realized via laser annealing," Journal of Alloys and Compounds, vol. 877, pp. 1-9, 2021.

R. Kawakami, Y. Yoshitani, A. Shirai, S.-I. Yanagiya, H. Koide,

Y. Mimoto, K. Kajikawa, M. Niibe, Y. Nakano, C. Azuma, T. Mukai, "Effects of nonequilibrium atmospheric-pressure O2 plasma-assisted annealing on anatase TiO2 nanoparticles," Applied Surface Science, vol. 526, pp. 1-12, 2020.

H. Heydari, M. Elahifard, and R. Behjatmanesh-Ardakani, "Role of oxygen vacancy in the adsorption and dissociation of the water molecule on the surfaces of pure and Ni-doped rutile (110): a periodic full-potential DFT study," Surface Science, vol. 679, pp. 218-224, 2019.

Z. Duan, Y. Zhu, Z. Hu, J. Zhang, D. Liu, X. Luo, M. Gao, L. Lei, X. Wang, and G. Zhao, "Micro-patterned NiFe2O4/Fe–TiO2 composite films: Fabrication, hydrophilicity and application in visible-light-driven photocatalysis," Ceramics International, vol. 46, pp. 27080-27091, 2020.

Y. Jiang, K. Shi, H. Tang, and Y. Wang, "Enhanced wettability and wear resistance on TiO2/PDA thin films prepared by sol-gel dip coating," Surface and Coatings Technology, vol. 375, pp. 334-340, 2019.

K. Guan, "Relationship between photocatalytic activity, hydro-philicity and self-cleaning effect of TiO2/SiO2 films," Surface and Coatings Technology, vol. 191, pp. 155-160, 2005.

Y. C. Lee, Y. P. Hong, H. Y. Lee, H. Kim, Y. J. Jung, K. H. Ko, H. S. Jung, and K. S. Hong, "Photocatalysis and hydrophilicity of doped TiO2 thin films," Journal of Colloid and Interface Science, vol. 267, pp. 127-131, 2003.

B. Li, X. Zhang, J. Ma, L. Zhou, H. Li, C. Liang, and H. Wang, "Hydrophilicity of bioactive titanium surface with different structure, composition, crystal form and grain size," Materials Letters, vol. 218, pp. 177-180, 2018.

Y. He, Q. Yan, X. Liu, M. Dong, and J. Yang, "Effect of annealing on the structure, morphology and photocatalytic activity of surface-fluorinated TiO2 with dominant {001} facets," Journal of Photochemistry and Photobiology A: Chemistry, vol. 393, pp. 1-24, 2020.