Nano-ZnO prepared by using chaya and mango leaves extract for photocatalyst of methylene blue

Sri Wahyu SUCIYATI; Junaidi JUNAIDI; Rudy  SITUMEANG; Posman  MANURUNG

doi:10.55713/jmmm.v34i1.1848

ผู้แต่ง

Sri Wahyu SUCIYATI Doctoral Program of Mathematics and Natural Science, University of Lampung, Bandar Lampung, 35145, Indonesia; Departement of Physics, University of Lampung, Bandar Lampung, 35145, Indonesia
Junaidi JUNAIDI Departement of Physics, University of Lampung, Bandar Lampung, 35145, Indonesia
Rudy SITUMEANG Department of Chemistry, University of Lampung, Bandar Lampung, 35145, Indonesia
Posman MANURUNG Departement of Physics, University of Lampung, Bandar Lampung, 35145, Indonesia

DOI:

https://doi.org/10.55713/jmmm.v34i1.1848

คำสำคัญ:

nano-ZnO, chaya, photocatalyst, leaves extract

บทคัดย่อ

This research aimed to synthesize nano-ZnO from chaya (Cnidoscolus aconitifolius) and mango leaves extract (Mangifera indica) as environmentally friendly photocatalysts. Nano-ZnO was synthesized using green synthesis, with leaves extracts as reducing agents and nanoparticle size stabilizers. The samples were prepared using two methods, namely nano-ZnO-1 and nano-ZnO-2. The results of Fourier transform infrared spectroscopy (FTIR) analysis showed the contribution of metabolite compounds in nano-ZnO synthesis. X-ray diffraction (XRD) and transmission electron microscopy (TEM) showed the crystal size in nano range, with spherical nanorod morphology observed. Ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS) determined the band gap energy of 2.97 eV and 3.17 eV. Furthermore, photocatalytic activity test showed that photocatalyst performance after 90 min was 68.86% (nano-ZnO-1) and 96.46% (nano-ZnO-2).

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H. Agarwal, S. Venkat Kumar, and S. Rajeshkumar, “A review on green synthesis of zinc oxide nanoparticles – An eco-friendly approach,” Resource-Efficient Technologies, vol. 3, pp. 406-413, 2017.

J. Jeevanandam, S. F. Kiew, S. Boakye-Ansah, S. Y. Lau, A. Barhoum, M. K. Danquah, J. Rodrigues, “Green approaches for the synthesis of metal and metal oxide nanoparticles using microbial and plant extracts,” Nanoscale, vol. 14, pp. 2534-2571, 2022.

O. V. Kharissova, B. I. Kharisov, C. M. O. González, Y. P. Méndez, and I. López, “Greener synthesis of chemical compounds and materials,” Royal Society Open Science, vol. 6, no. 11, p. 191378, 2019.

J. Iqbal, B. A. Abbasi, T. Yaseen, S. A. Zahra, A. Shahbaz, S. A. Shah, S. Uddin, X. Ma, B. Raouf, S. Kanwal, W. Amin, T. Mahmood, H. A. El-Serehy, and P. Ahmad, “Green synthesis of zinc oxide nanoparticles using Elaeagnus angustifolia L. leaf extracts and their multiple in vitro biological applications,” Scientific Reports, vol. 11, pp. 1-13, 2021.

J. Duraimurugan, G. S. Kumar, P. Maadeswaran, S. Shanavas, P. M. Anbarasan, and V. Vasudevan, “Structural, optical and photocatlytic properties of zinc oxide nanoparticles obtained by simple plant extract mediated synthesis,” Journal of Materials Science: Materials in Electronics, vol. 30, pp. 1927-1935, 2019.

Y. Xu, J. Jin, X. Li, Y. Han, H. Meng, T. Wang, X. Zhang, “Simple synthesis of ZnO nanoflowers and its photocatalytic performances toward the photodegradation of metamitron,” Materials Research Bulletin, vol. 76, pp. 235-239, 2016.

S. T. Fardood, F. Moradnia, A. H. Ghalaichi, S. Danesh Pajouh, and M. Heidari, “Facile green synthesis and characterization of zinc oxide nanoparticles using tragacanth gel: investigation of their photocatalytic performance for dye degradation under visible light irradiation,” Nanochemistry Research, vol. 5, pp. 69-76, 2020.

R. Chandran and A. Mallik, “Facile, seedless and surfactant-free synthesis of ZnO nanostructures by wet chemical bath method and their characterization,” Applied Nanoscience, vol. 8, pp. 1823-1830, 2018.

H. Chemingui, T. Missaoui, J. C. Mzali, T. Yildiz, M. Konyar, M. Smiri, N. Saidi, A. Hafiane, and H. C. Yatmaz, “Facile green synthesis of zinc oxide nanoparticles (ZnO NPs): Antibacterial and photocatalytic activities,” Materials Research Express, vol. 6, p. 1050b4, 2019.

R. Vinayagam, S. Pai, G. Murugesan, T. Varadavenkatesan, and R. Selvaraj, “Synthesis of photocatalytic zinc oxide nanoflowers using Peltophorum pterocarpum pod extract and their characterization,” Applied Nanoscience, vol. 13, pp. 847-857, 2021.

U. Wijesinghe, G. Thiripuranathar, F. Menaa, H. Iqbal, A. Razzaq, and H. Almukhlifi, “Green synthesis, structural characterization and photocatalytic applications of ZnO nano-conjugates using Heliotropium indicum,” Catalysts, vol. 11, p. 0831, 2021.

V. N. Kalpana and V. Devi Rajeswari, “A review on green synthesis, biomedical applications, and toxicity studies of ZnO NPs,” Bioinorganic Chemistry and Applications, vol. 2018, pp. 1-12, 2018.

C. Vidya, C. Manjunatha, M. Sudeep, S. Ashoka, and M. A. Lourdu Antony Raj, “Photo-assisted mineralisation of titan yellow dye using ZnO nanorods synthesised via environmental benign route,” SN Applied Sciences, vol. 2, pp. 1-15, 2020.

M. G. Batterjee, A. Nabi, M. R. Kamli, K. A. Alzahrani, E. Y. Danish, and M. A. Malik, “Green hydrothermal synthesis of zinc oxide nanoparticles for uv-light-induced photocatalytic degradation of ciprofloxacin antibiotic in an aqueous environment,” Catalysts, vol. 12, pp. 1-17, 2022.

M. A. Tănase, M. Marinescu, P. Oancea, A. Răducan, C. I. Mihaescu, E. Alexandrescu, C. L. Nistor, L. I. Jinga, L. M. Ditu, C. Petcu, and L. O. Cinteza, “Antibacterial and photocatalytic properties of ZnO nanoparticles obtained from chemical versus Saponaria officinalis extract-mediated synthesis,” Molecules, vol. 26, 2021.

J. Gangwar and J. K. Sebastian, “Unlocking the potential of biosynthesized zinc oxide nanoparticles for degradation of synthetic organic dyes as wastewater pollutants,” Water Science Technology, vol. 84, pp. 3286-3310, 2021.

M. Cai, Y. Liu, K. Dong, X. Chen, and S. Li, "Floatable S‐scheme Bi2WO6/C3N4/ carbon fiber cloth composite photocatalyst for efficient water decontamination," Chinese Journal of Catalysis, vol. 52, pp. 239-251, 2023.

A. Singh, N. B. Singh, S. Afzal, T. Singh, and I. Hussain, “Zinc oxide nanoparticles: a review of their biological synthesis, antimicrobial activity, uptake, translocation and biotransformation in plants,” Journal of Materials Science, vol. 53, pp. 185-201, 2018.

P. Raizada, A. Sudhaik, and P. Singh, “Photocatalytic water decontamination using graphene and ZnO coupled photo-catalysts: A review,” Materials Science for Energy Technologies, vol. 2, pp. 509-525, 2019.

L. V Bora, and R. K. Mewada, “TiO2 and ZnO as Heterogeneous Photocatalysts for Wastewater Treatment,” Irjet, vol. 3, pp. 1610-1616, 2016.

M. Golmohammadi, M. Honarmand, and S. Ghanbari, “A green approach to synthesis of ZnO nanoparticles using jujube fruit extract and their application in photocatalytic degradation of organic dyes,” Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, vol. 229, p. 117961, 2020.

S. Pai, S. H, T. Varadavenkatesan, R. Vinayagam, and R. Selvaraj, “Photocatalytic zinc oxide nanoparticles synthesis using Peltophorum pterocarpum leaf extract and their characterization,” Optik, vol. 185, pp. 248-255, 2019.

S. Narath, S. K. Koroth, S. S. Shankar, B. George, V. Mutta, S. Waclawek, M. Černík, V. V. T. Padil, and R. S. Varma, “Cinnamomum tamala leaf extract stabilized zinc oxide nanoparticles: A promising photocatalyst for methylene blue degradation,” Nanomaterials, vol. 11, 2021.

H. Veisi, S. Azizi, and P. Mohammadi, “Green synthesis of the silver nanoparticles mediated by Thymbra spicata extract and its application as a heterogeneous and recyclable nano-catalyst for catalytic reduction of a variety of dyes in water,” Journal of Cleaner Production, vol. 170, pp. 1536-1543, 2018.

C. A. Soto-Robles, P. A. Luque, C. M. Gómez-Gutiérrez, O. Nava, A. R. Vilchis-Nestor, E. Lugo-Medina, R. Ranjithkumar, and A. Castro-Beltrán, “Study on the effect of the concentration of Hibiscus sabdariffa extract on the green synthesis of ZnO nanoparticles,” Results in Physics, vol. 15, p. 102807, 2019.

N. A. Al-Dhabi and M. V. Arasu, “Environmentally-friendly green approach for the production of zinc oxide nanoparticles and their anti-fungal, ovicidal, and larvicidal properties,” Nanomaterials, vol. 8, 2018.

S. Rajeshkumar, S. V. Kumar, A. Ramaiah, H. Agarwal, T. Lakshmi, and S. M. Roopan, “Biosynthesis of zinc oxide nanoparticles usingMangifera indica leaves and evaluation of their antioxidant and cytotoxic properties in lung cancer (A549) cells,” Enzyme and Microbial Technology, vol. 117, pp. 91-95, 2018.

N. I. Rasli, H. Basri, and Z. Harun, “Zinc oxide from aloe vera extract: two-level factorial screening of biosynthesis parameters,” Heliyon, vol. 6, p. e03156, 2020.

S. Zafar, A. Ashraf, M. U. Ijaz, S. Mauzammil, M. H. Siddique, S. Afzal, R. Andleeb, K. A. Al-Ghanim, F. Al-Misned, Z. Ahmed, and S. Mahboob, “Eco-friendly synthesis of antibacterial zinc nanoparticles using Sesamum indicum L. extract,” Journal of King Saud University - Science, vol. 32, pp. 1116-1122, 2020.

M. H. Kahsay, “Synthesis and characterization of ZnO nanoparticles using aqueous extract of Becium grandiflorum for antimicrobial activity and adsorption of methylene blue,” Applied Water Science, vol. 11, pp. 1-12, 2021.

S. Bognár, P. Putnik, and D. Š. Merkulov, “Sustainable green nanotechnologies for innovative purifications of water: Synthesis of the nanoparticles from renewable sources,” Nanomaterials, vol. 12, 2022.

L. G. Eduardo, J. M. C. Francisco, J. Q. V. Fernanda, Q. R. David, C. F. Maribel, and G. N. P. Maria, “Effects of the combination of Cnidoscolus aconitifolius and Metformin on the glycemia in streptozotocin-induced diabetes rats,” Journal of Diabetes Endocrinology, vol. 10, pp. 30-35, 2019.

K. U. Osuocha, A. V Iwueke, and E. C. Chukwu, “Phyto-chemical profiling, body weight effect and anti-hyper-cholesterolemia potentials of Cnidoscolus aconitifolius leaf extracts in male albino rat,” Journal of Pharmacognosy and Phytherapy, vol. 12, pp. 19-27, 2020.

O. B. John and O. A. Opeyemi, “Effect of processing methods on nutritional composition, phytochemicals, and anti-nutrient properties of chaya leaf (Cnidoscolus aconitifolius),” African Journal of Food Science, vol. 9, pp. 560-565, 2015.

M. J. Sierra, A. P. Herrera, and K. A. Ojeda, “Synthesis of zinc oxide nanoparticles from mango and soursop leaf extracts,” Contemporary Engineering Sciences, vol. 11, pp. 395-403, 2018.

M. Kumar, V. Saurabh, M. Tomar, M. Hasan, S. Changan, M. Sasi, C. Maheshwari, U. Prajapati, S. Singh, R. K. Prajapat, S. Dhumal, S. Punia, R. Amarowicz, and M. Mekhemar, “Mango (Mangifera indica L.) leaves: Nutritional composition, phyto-chemical profile, and health-promoting bioactivities,” Antioxidants, vol. 10, pp. 1-23, 2021.

A. Hussain, M. Oves, M. F. Alajmi, I. Hussain, S. Amir, J. Ahmed, Md. T. Rehman, and H. R. El-Seedi, I. Ali, “Biogenesis of ZnO nanoparticles using: Pandanus odorifer leaf extract: Anticancer and antimicrobial activities,” Royal Society of Chemistry Advances, vol. 9, pp. 15357-15369, 2019

E. D. Mohamed Isa, K. Shameli, H. J. Ch’ng, N. W. Che Jusoh, and R. Hazan, “Photocatalytic degradation of selected pharmaceuticals using green fabricated zinc oxide nanoparticles,” Advanced Powder Technology, vol. 32, pp. 2398-2409, 2021.

S. V. Saraswathi, J. Tatsugi, P. K. Shin, and K. Santhakumar, “Facile biosynthesis, characterization, and solar assisted photo-catalytic effect of ZnO nanoparticles mediated by leaves of L. speciosa,” Journal of Photochemistry Photobiology B: Biology, vol. 167, pp. 89-98, 2017.

P. C. Nagajyothi, S. J. Cha, I. J. Yang, T. V. M. Sreekanth, K. J. Kim, and H. M. Shin, “Antioxidant and anti-inflammatory activities of zinc oxide nanoparticles synthesized using Polygala tenuifolia root extract,” Journal of Photochemistry Photo-biology B: Biology, vol. 146, pp. 10-17, 2015.

R. Rathnasamy, P. Thangasamy, R. Thangamuthu, S. Sampath, and V. Alagan, “Green synthesis of ZnO nanoparticles using Carica papaya leaf extracts for photocatalytic and photovoltaic applications,” Journal of Materials Science: Materials in Electronics, vol. 28, pp. 10374-10381, 2017.

M. Gupta, R. S. Tomar, S. Kaushik, R. K. Mishra, and D. Sharma, “Effective antimicrobial activity of green ZnO nano particles of Catharanthus roseus,” Frontiers in Microbiology, vol. 9, pp. 1-13, 2018.

S. Alamdari, M. S. Ghamsari, C. Lee, W. Han, H. Park, M.J. Tafreshi, and H. Afarideh, “Preparation and Characterization of Zinc Oxide Nanoparticles Using Leaf Extract of Sambucus ebulus,” Applied Sciences, vol. 10, pp. 1-19, 2020.

P. Basnet, T. Inakhunbi Chanu, D. Samanta, and S. Chatterjee, “A review on bio-synthesized zinc oxide nanoparticles using plant extracts as reductants and stabilizing agents,” Journal of Photochemistry and Photobiology B: Biology, vol. 183, pp. 201-221, 2018.

A. Garcia, Kuri, J.L. Chavez, “Phenolic profile and antioxidant capacity of Cnidoscolus chayamansa and Cnidoscolus aconitifolius: A review,” Journal of Medicinal Plants Research, vol. 11, pp. 713-727, 2017.

B. Cullity and S. Stock, Elements of X-Ray Diffraction, Third. United States of America: Pearson, 2014.

H. Sawada, R. Wang, and A. W. Sleight, “An electron density residual study of zinc oxide,” Journal of Solid State Chemistry, vol. 122, pp. 148-150, 1996.

G. Will, Powder diffraction: The rietveld method and the two stage method to determine and refine crystal structures from powder diffraction data. Berlin Heidelberg: Springer, 2006.

S. Agarwal, L. K. Jangir, K. S. Rathore, M. Kumar, and K. Awasthi, “Morphology-dependent structural and optical properties of ZnO nanostructures,” Applied Physics A: Materials Science and Processing, vol. 125, 2019.

V. Gowthambabu, A. Balamurugan, R. Dhivya bharathy, S. Satheeshkumar, and S. S. Kanmani, “ZnO nanoparticles as efficient sunlight driven photocatalyst prepared by solution combustion method involved lime juice as biofuel,” Spectro-chimica Acta - Part A: Molecular and Biomolecular Spectroscopy, vol. 258, p. 119857, 2021.

C. López-Esmerio, C. Ruiz-Rojas, J. Angulo-Rocha, E. Lizárraga-Medina, F. Ramos-Brito, E. Camarillo-García, R. Martinez-Martinez, M. Aguilar-Frutis, and M. García-Hipólito, “Study of the electrical, optical and morphological properties in submicron and microstructured ZnO thin films obtained by spin coating and chemical bath deposition,” Science and Technology Indonesia, vol. 7, no. 3, p. 291-302, 2022.

J. Tauc and A. Menth, “States in the gap,” Journal of Non-Crystalline Solids, vol. 8-10, pp. 569-585, 1972.

Y. Gu, I. L. Kuskovsky, M. Yin, S. O’Brien, and G. F. Neumark, “Quantum confinement in ZnO nanorods,” Applied Physics Letters, vol. 85, pp. 3833-3835, 2004.

P. Devaraji, M. Mapa, H. M. A. Hakkeem, V. Sudhakar, K. Krishnamoorthy, and C. S. Gopinath, “ZnO-ZnS heterojunctions: A potential candidate for optoelectronics applications and mineralization of endocrine disruptors in direct sunlight,” ACS Omega, vol. 2, pp. 6768-6781, 2017.

Y. Köseoǧlu, “A simple microwave-assisted combustion synthesis and structural, optical and magnetic characterization of ZnO nanoplatelets,” Ceramics International, vol. 40, pp. 4673-4679, 2014.

F. Afifah, A. Tjahjono, A. Ridhova, P. Yuniar, D. Maulida, A. Noviyanto, and D. Aryanto, “Influence of Al and Cu doping on the structure , morphology , and optical properties of ZnO thin film,” Indonesian Journal of Chemistry, vol. 23, pp. 44-52, 2023.

J. Santhoshkumar, S. V. Kumar, and S. Rajeshkumar, “Synthesis of zinc oxide nanoparticles using plant leaf extract against urinary tract infection pathogen,” Resource-Efficient Technologies, vol. 3, pp. 459-465, 2017.

S. Mondal, S. R. Bhattacharyya, and P. Mitra, “Effect of Al doping on microstructure and optical band gap of ZnO thin film synthesized by successive ion layer adsorption and reaction,” Pramana - Journal of Physics, vol. 80, pp. 315-326, 2013.

M. G. Batterjee, A. Nabi, M. R. Kamli, K. A. Alzahrani, E. Y. Danish, and M. A. Malik, “Green hydrothermal synthesis of zinc oxide nanoparticles for UV-light-induced photocatalytic degradation of ciprofloxacin antibiotic in an aqueous environment,” Catalysts, vol. 12, pp. 1-18, 2022.

M. Satheshkumar, B. Anand, A. Muthuvel, M. Rajarajan, V. Mohana, and A. Sundaramanickam, “Enhanced photocatalytic dye degradation and antibacterial activity of biosynthesized ZnO-NPs using curry leaves extract with coconut water,” Nanotechnology for Environmental Engineering., vol. 5, 2020.

M. Aiempanakit, P. Sudjai, K. Singsumphan, S. Laksee, and C. Suwanchawalit, “Brazilein modified zinc oxide nanorods with enhanced visible light-responsive photocatalytic efficiency,” Journal of Metals, Materials and Minerals. vol. 32, pp. 70-76, 2022.

I. Fatimah, G. Purwiandono, P. W. Citradewi, S. Sagadevan, and W. Oh, “Influencing factors in the synthesis of photoactive nanocomposites of ZnO / SiO2 -Porous heterostructures from montmorillonite and the study for methyl violet photo-degradation,” Nanomaterials, vol. 11, p. 3427, 2021.

C. Aiempanakit, T. Phantaporn, and K. Aiempanakit, “Enhanced photocatalytic activity of ZnO nanostructures deposited on mesh through electrochemical deposition and thermal oxidation,” Journal of Metals, Materials and Minerals, vol. 32, pp. 63-69, 2022.

S. T. Algarni, N. A. Y. Abduh, A. Al Kahtani, and A. Aouissi, “Photocatalytic degradation of some dyes under solar light irradiation using ZnO nanoparticles synthesized from Rosmarinus officinalis extract,” Green Chemistry Letters and Reviews, vol. 15, pp. 460-473, 2022.