Green synthesis of bimetallic CuO@NiO nanocomposite for the removal of glyphosate

Kornkanok  BOONSERM; Anan  SUTCHA; Rarm  PHINJAROENPHAN

doi:10.55713/jmmm.v34i1.1931

ผู้แต่ง

Kornkanok BOONSERM Department of Applied Chemistry, Faculty of Sciences and Liberal Arts, Rajamangala University of Technology Isan, 744, Suranarai Road, Muang District, Nakhon Ratchasima 30000, Thailand
Anan SUTCHA Department of Applied Physics, Faculty of Sciences and Liberal Arts, Rajamangala University of Technology Isan, 744, Suranarai Road, Muang District, Nakhon Ratchasima 30000, Thailand
Rarm PHINJAROENPHAN Department of Applied Physics, Faculty of Sciences and Liberal Arts, Rajamangala University of Technology Isan, 744, Suranarai Road, Muang District, Nakhon Ratchasima 30000, Thailand

DOI:

https://doi.org/10.55713/jmmm.v34i1.1931

คำสำคัญ:

CuO@NiO nanocomposite, Mango peel, Mangifera indica L, Glyphosate, Photocatalytic activity

บทคัดย่อ

Green synthesis of photocatalyst bimetallic CuO@NiO nanocomposite for eliminating organic hazardous glyphosate (Gly) solution has been introduced. The nanocomposite has been successfully developed from mango (Mangifera indica L.) peel extracted solution by a simultaneous reduction process. HRTEM, XRD, and EDX have also been used to explore the nanostructure, crystal conformation, and chemical compositions of CuO@NiO. Using UV-vis spectrometer, we have observed the photo-catalytic activity and kinetic removal rate constant of CuO@NiO in terms of glyphosate elimination under UV light illumination. Compared with pure CuO and NiO nanoparticles, CuO@NiO displayed improved and enhanced photocatalytic activity. This work demonstrates an eco-friendly, low-cost material with high efficiency for removing Gly, which has applications in environmental protection.

Downloads

Download data is not yet available.

เอกสารอ้างอิง

M. Rodríguez Páez, Y. Ochoa-Muñoz, and J. E. Rodriguez-Páez, “Efficient removal of a glyphosate-based herbicide from water using ZnO nanoparticles (ZnO-NPs),” Biocatalysis and Agricultural Biotechnology, vol. 22, pp. 101434, 2019.

M. Rani, and U. Shanker, “Degradation of traditional and new emerging pesticides in water by nanomaterials: recent trends and future recommendations,” International Journal of Environmental Science and Technology, vol. 15, pp. 1347-1380, 2018.

J. Z. Sandrini, R. C. Rola, F. M. Lopes, H. F. Buffon, M. M. Freitas, C. d. M. G. Martins, and C. E. Da Rosa, “Effects of glyphosate on cho-linesterase activity of the mussel Perna perna and the fish Danio rerio and Jenynsia multidentata: In vitro studies,” Aquatic Toxicology, vol. 130, pp. 171-173, 2013.

C. Feng, Y. Deng, L. Tang, G. Zeng, J. Wang, J. Yu, Y. Liu, B. Peng, H. Feng, and J. Wang, “Core-shell Ag2CrO4/N-GQDs @g-C3N4 composites with anti-photocorrosion performance for enhanced full-spectrum-light photocatalytic activities,” Applied Catalysis B: Environmental, vol. 239, pp. 525-536, 2018.

A. Zuorro, R. Lavecchia, M. M. Monaco, G. Iervolino, and V. Vaiano, “Photocatalytic degradation of azo dye reactive violet 5 on Fe-doped titania catalysts under visible light irradiation,” Catalysts, vol. 9, p. 645, 2019.

G. Iervolino, I. Zammit, V. Vaiano, and L. Rizzo, “Limitations and prospects for wastewater treatment by UV and Visi-ble-Light-Active heterogeneous photocatalysis: A critical review,” Topics in Current Chemistry, vol. 7, p. 378, 2020.

N. Tran, P. Drogui, T. L. Doan, T. S. Le, and H. C. Nguyen, “Electrochemical degradation and mineralization of glyphosate herbicide,” Environmental Technology, vol 38. pp. 2939-2948, 2017.

P. Marin, R. Bergamasco, A. N. Módenes, P. R. Paraiso, and S. Hamoudi, “Synthesis and characterization of graphene oxide functionalized with MnFe2O4 and supported on activated carbon for glyphosate adsorption in fixed bed column,” Process Safety and Environmental Protection, vol. 123, pp. 59-71, 2019.

C. A. Villamar-Ayala, J. V. Carrera-Cevallos, R. Vasquez-Medrano, and P. J. Espinoza-Montero, “Fate, eco-toxicological characteristics, and treatment processes applied to water polluted with glyphosate: A critical review,” Critical Reviews in Environmental Science and Technology, vol. 49, pp. 1476-1514, 2019.

R. K. Ibrahim, M. Hayyan, M. A. AlSaadi, A. Hayyan, and S. Ibrahim, “Environmental application of nanotechnology: Air, soil, and water,” Environmental Science and Pollution Research, vol. 23, no. 14, pp. 13754-13788, 2016.

K. D. Gilroy, A. Ruditskiy, H. -C. Peng, D. Qin, and Y. Xia, “Bimetallic nanocrystals: syntheses, properties, and applications,” Chemical Reviews, vol. 116, no. 18, pp. 10414-10472, 2016.

A. M. Alansi, M. A. Al-Qunaibit, I. O. Alade, T. F. Qahtan, and T. A. Saleh, “Visible- light responsive BiOBr nanoparticles loaded on reduced graphene oxide for photocatalytic degradation of dye,” Journal of Molecular Liquids, vol. 253, pp. 297-304, 2018.

N. N. Becknell, Y. Kang, C. Chen, J. Resasco, N. Kornienko, J. Guo, N. M. Markovic, G. A. Somorjai, V. R. Stamenkovic, and P. Yang, “Atomic structure of Pt3Ni nonoframe electro-catalysts by in situ X-ray absorption spectroscopy,” Journal of the American Chemical Society, vol. 137, pp. 15817-15824, 2015.

Z. K. Ghouri, A. Badreldin, K. Elsaid, D. Kumar, K. Youssef, and A. Abdel-Wahab, “Theoretical and experimental investigations of Co-Cu bimetallic alloys-incorporated carbon nanowires as an efficient bi-functional electrocatalyst for water splitting,” Journal of Industrial and Engineering Chemistry, vol. 96, pp. 243-253, 2021.

N. Lee, and T. Hyeon, “Designed synthesis of uniformly sized iron oxide nanoparticles for efficient magnetic resonance imaging contrast agents,” Chemical Society Reviews, vol. 41, pp. 2575-2589, 2012.

L. M. Rossi, M. A. S. Garcia, and L. L. R. Vono, “Recent advances in the development of magnetically recoverable metal nanoparticle catalysts,” Journal of the Brazilian Chemical Society, vol. 23, pp. 1959-1971, 2012.

P. Srinoi, Y. T. Chen, V. Vittur, M. D. Marquez, and T. R. Lee, “Bimetallic nanoparticles: enhanced magnetic and optical properties for emerging biological applications,” Applied Sciences, vol. 8, pp. 1-32, 2018.

C. Y. Fu, K. W. Kho, U. S. Dinish, Z. Y. Koh, and O. Malini, “Enhancement in SERS intensity with hierarchical nano-structures by bimetallic deposition approach,” Journal of Raman Spectroscopy, vol. 43, pp. 977-985, 2011.

A. Baldi, T. C. Narayan, A. L. Koh, and J. A. Dionne, “In situ Detection of Hydrogen- Induced Phase Transitions in Individual Palladium Nanocrystals,” Nature Mater, vol. 13, pp. 1143-1148, 2014.

S. Medda, A. Hajra, U. Dey, P. Bose, and N. K. Mondal, “Biosynthesis of silver nanoparticles from Aloe vera leaf extract and antifungal activity against Rhizopus sp. and Aspergillus sp.,” Applied Nanoscience, vol. 5, pp. 875-880, 2015.

S. Mondal, N. Roy, R. A. Laskara, I. Sk, S. Basu, D. Mandal, and N. A. Begum, “Biogenic synthesis of Ag, Au and bimetallic Au/Ag alloy nanoparticles using aqueous extract of mahogany (Swietenia mahogani JACQ.) leaves,” Colloids and Surfaces B: Biointerfaces, vol. 82, pp. 497-504, 2010.

T. M. S. Rosbero, and D. H. Camacho, “Green preparation and characterization of tentacle-like silver/copper nanoparticles for catalytic degradation of toxic chlorpyrifos in water,” Journal of Environmental Chemical Engineering, vol. 5, pp. 2524-2532, May. 2017.

S. Kaviya, J. Santhanalakshmi, B. Viswanathan, J. Muthumary, and K. Srinivasan, “Biosynthesis of silver nanoparticles using citrus sinensis peel extract and its antibacterial activity,” Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 79, pp. 594-598, 2011.

Y. Xing, X. Liao, X. Liu, W. Li, R. Huang, J. Tang, Q. Xu, X. Li, and J. Yu, “characterization and antimicrobial activity of silver nanoparticles synthesized with the peel extract of mango,” Materials, vol. 14, p. 5878, 2021.

S. M. Roopan, A. Bharathi, R. Kumar, V. G. Khanna, and A. Prabhakarn, “Acaricidal, insecticidal, and larvicidal efficacy of aqueous extract of Annona squamosa L peel as biomaterial for the reduction of palladium salts into nanoparticles,” Colloids Surf B Biointerfaces, vol. 1, pp. 209-212, 2012

R. K. Das, V. L. Pachapur, L. Lonappan, M. Naghdi, R. Pulicharla, S. Maiti, M. Cledón, L. M. A. Dalila, S. J. Sarma, and S. K. Brar, “Biological synthesis of metallic nanoparticles: Plants, animals and microbial aspects,” Nanotechnology for Environmental Engineering, vol. 2, pp. 1-21, 2017.

J. Singh, T. Dutta, K. H. Kim, M. Rawat, P. Samddar, and P. Kumar, “Green synthesis of metals and their oxide nano-particles: Applications for environmental remediation,” Journal of Nanobiotechnology, vol. 16, pp. 1-24, 2018.

P. K. Dikshit, J. Kumar, A. K. Das, S. Sadhu, S. Sharma, S. Singh, P. K. Gupta, and B. S. Kim, “Green synthesis of metallic nanoparticles: Applications and limitations,” Catalysts, vol. 11, pp. 1-35, 2021.

N. K. Ojha, G. V. Zyryanov, A. Majee, V. N. Charushin, O. N. Chupakhin, and S. Santra, “Copper nanoparticles as inexpensive and efficient catalyst: a valuable contribution in organic synthesis,” Coordination Chemistry Reviews, vol. 353, pp. 1- 57, 2017.

L. Chen, H. Xu, H. Cui, H. Zhou, H. Wan, and J. Chen,

“Preparation of Cu–Ni bimetallic nanoparticles surface-capped with dodecanethiol and their tribological properties as lubricant additive,” Particuology, vol. 34, pp. 89-96, 2017.

S. A. Hashemizadeh, and M. Biglari, “Cu:Ni bimetallic nano-particles: facile synthesis, characterization and its application in photodegradation of organic dyes,” Journal of Materials Science: Materials in Electronics, vol. 29, pp. 13025-13031, 2018.

A. G. Ramu, M. L. A. Kumari, M. S. Elshikh, H. H. Alkhamis, A. F. Alrefaei, and D. Choi, “A facile and green synthesis of CuO/NiO nanoparticles and their removal activity of toxic nitro compounds in aqueous medium,” Chemosphere, vol. 271, pp. 129475, 2021.

U. Younas, A. Gulzar, F. Ali, M. Pervaiz, Z. Ali, S. Khan, Z. Saeed, M. Ahmed, and A. A. Alothman, “Antioxidant and organic dye removal potential of Cu-Ni bimetallic nanoparticles synthesized using gazania rigens extract,” Water, vol. 13, p. 2653, 2021.

Abdullah, T. Hussain, S. Faisal, M. Rizwan, S. N. Zaman, M. Iqbal, A. Iqbal, and Z. Ali, “Green synthesis and characterization of copper and nickel hybrid nanomaterials: Investigation of their biological and photocatalytic potential for the removal of organic crystal violet dye,” Journal of Saudi Chemical Society, vol. 26, p. 101486, 2022.