Enhanced photocatalytic reduction of Cr(VI) under visible light a magnetically separable TiO\(_{2}\)-Fe/Fe\(_{3}\)O\(_{4}\) photocatalyst prepared from iron rusty waste

Khoirunisa KHOIRUNISA; Novianti Dwi LESTARI; Endang Tri WAHYUNI; Taufik Abdillah NATSIR

doi:10.55713/jmmm.v35i1.2162

ผู้แต่ง

Khoirunisa KHOIRUNISA Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara POB 21 BLs, Yogyakarta, 55281, Indonesia
Novianti Dwi LESTARI Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara POB 21 BLs, Yogyakarta, 55281, Indonesia
Endang Tri WAHYUNI Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara POB 21 BLs, Yogyakarta, 55281, Indonesia
Taufik Abdillah NATSIR Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara POB 21 BLs, Yogyakarta, 55281, Indonesia

DOI:

https://doi.org/10.55713/jmmm.v35i1.2162

คำสำคัญ:

Photoreduction, TiO2, doping, Fe3O4, rusty waste

บทคัดย่อ

This research deals with enhancing the visible activity and generating the magnetic property of TiO₂ by Fe doping and Fe₃O₄ impregnation respectively, using rusty iron waste as Fe source. The prepared TiO₂-Fe/Fe₃O₄ photocatalysts were characterized by SR-UV/Visible, FTIR, XRD, and SEM-EDX instruments. The resulting photocatalysts are responsive to visible light and can be separated magnetically and used for photoreduction of Cr (VI) ions. In the photoreduction of Cr(VI) over TiO₂-Fe/Fe₃O₄ photo-catalysts with various amounts of Fe dopant and alteration of Fe₃O₄ fraction, the photocatalyst mass, irradiation time, and solution pH were optimized. The research results assign that doping Fe to TiO₂ photo-catalysts can decrease the band gap energy (Eg) consequently improving its activity under visible irradiation. Furthermore, the magnetization of TiO₂-Fe allows it to be separated practically and effectively. The best detachable and the most active photocatalyst is shown by TiO₂-Fe/Fe₃O₄ having a Ti/Fe mole ratio of 1:0.05 and Fe₃O₄ fraction of 50.00%. The highest photo-reduction of Cr(VI) 10 mg∙L^‒1 in 100 mL solution, 92.5%, can be achieved by applying 0.2 g of the photocatalyst mass, solution pH 3, in 90 min of reaction time under visible light.

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