Synthesis of zeolite A membrane from rice husk ash

ผู้แต่ง

  • Chayakorn Bhavornthanayod Faculty of Science, King Mongkut’s Institute of Technology Ladkrabang
  • Pesak Rungrojchaipon Faculty of Science, King Mongkut’s Institute of Technology Ladkrabang

คำสำคัญ:

RHA, Zeolite A, Hydrothermal, Direct synthesis

บทคัดย่อ

Rice husk is a major by-product of the rice-processing industries. The burning of rice husk in air results in the formation of rice husk ash (RHA) with a content in SiO2 that varies from 85 to 98% depending on the burning conditions, the furnace type and the rice variety. Numerous studies aimed at using RHA as a cheap alternative source of amorphous silica for the production of silicon based materials with industrial and technological interests. The zeolite gel was prepared with the following batch composition: 3.1Na2O : Al2O3: 1.9SiO2: 128H2O synthesized by hydrothermal treatment with various times from 15 min to 4 hrs. Zeolite A crystals have been successfully coated on the substrate surface (Al2O3) by direct synthesis method. The silica source was characterized by FTIR and X-ray diffraction (XRD). Zeolite A and zeolite A membrane, the patterns of which showed a unique characteristic of zeolite A respectively were characterized by XRD. They were also examined by Scanning electron microscope (SEM) which at 2 hrs. synthesis time reported the layer thickness of 5.92 μm ± 0.152 and 12.295 μm ± 1.052 at 4 hrs. synthesis time.

Downloads

Download data is not yet available.

เอกสารอ้างอิง

Pak, A. and Mohammadi, T. 2006. Zeolite NaA membranes synthesis. Desalination. 200(1-3): 68–70.

Chareonpanich, M., Namto, T., Kongkachuichaya, P. and Limtrakul, J. 2004. Synthesis of ZSM-5 zeolite from lignite fly ash and rice husk ash. Fuel Process. Technol. 85(15):1623– 1634.

Della, V.P., Kühn, I. and Hotza, D. 2002. Rice husk ash as an alternate source for active silica production. Mater. Lett. 57(4): 818– 821.

Petkowicz, D.I., Rigo, R.T., Radtke, C., Pergher, S.B. and dos Santos, J.H.Z. 2008. Zeolite NaA from Brazilian chrysotile and rice husk. Microporous Mesoporous Mater. 116(1-3): 548–554.

Jackson, K.D.O., Loadman, M.J.R., Jones, C.H. and Ellis, G. 1990. A guide to identifying common inorganic fillers and activators using vibrational spectroscopy. Spectrochim. Acta. 46A: 217.

Soto, K., Sugimoto, K. and Nakane, T. 2008. Synthesis of industrial scale NaY zeolite membranes and ethanol permeatin performance in pervaporation and vapor permeation up to 130°C and 570 kPa. J. Membr. Sci. 310(1-2): 161–173.

Boudreau, L.C. and Tsapatsis, M. 1997. A highly oriented thin film of zeolite A. Chem. Mater. 9(8): 1705-1709

Hadi, N. 2001. Direct synthesis of NaA zeolite from rice husk and carbonaceous rice husk ash. Indonesian J. Agric. Sci. 1: 40-45.

Sookumnerd, C., Ito, N. and Kito, K. 2005. Financial viabilities of husk-fueled steam engines as an energy-saving technology in Thai rice mills. Appl. Energy 82(1): 64–80.

Cheng, Z., Gao, E. and Wan, H. 2004. Novel synthesis of FAU-type zeolite membrane with high performance. Chem. Commun. 1718–1719.

ดาวน์โหลด

เผยแพร่แล้ว

2017-04-15

วิธีการอ้างอิง

[1]
C. Bhavornthanayod และ P. . Rungrojchaipon, “Synthesis of zeolite A membrane from rice husk ash”, J Met Mater Miner, ปี 19, ฉบับที่ 2, เม.ย. 2017.

ฉบับ

บท

Original Research Articles