Dissolved oxygen sensor film using ruthenium polypyridine complex as luminophore

ผู้แต่ง

  • Chanissnun Su-Ngam Faculty of Science, Kasetsart University and Center for Advanced Studies in Tropical Natural Resources National Research UniversityKasetsart University (CASTNAR,NRU-KU)
  • San H. Thang CSIRO Molecular and Health Technologies, Bayview Avenue
  • Atchana Wongchaisuwat Faculty of Science, Kasetsart University and Center for Advanced Studies in Tropical Natural Resources National Research UniversityKasetsart University (CASTNAR,NRU-KU)
  • Ladda Meesuk Faculty of Science, Kasetsart University and Center for Advanced Studies in Tropical Natural Resources National Research UniversityKasetsart University (CASTNAR,NRU-KU)

คำสำคัญ:

Ruthenium polypyridine complex, RAFT, Dissolved oxygen, Luminophore

บทคัดย่อ

Ruthenium polypyridine complex was synthesized by using RAFT process. The Ruthenium was immobilized in 2 silicone matrices, polydimethylsiloxane(PDMS) and KE 200 (silicone elastomer base)/CX200 (curing agent). KE 200/CX200 is the alcohols curing type silicone. Both sensor films showed absorption peak at 460 nm and  luminescence peak at 610 nm. The KE200/CX200 film gave linear response to dissolved oxygen up to 80% O2 (18 ppm) follow Stern-Volmer equation with R2 of 0.990. The measured luminescence intensity decreased with increasing dissolved oxygen water temperature from 25 to 70°c. After being irradiated with 460 nm light source for 3 hrs, the sensor film still showed good stability.

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เอกสารอ้างอิง

Di Marco, G. and Lanza, M. (2000). Optical solidstate oxygen sensors using metalloporphyrin complexes immobilized in suitable polymeric matrices. Sens. Actuators,B.63:42-48.

Chu, C.S. and Lo, Y.L. (2008). Ratiometric fiber-optic oxygen sensors based on sol-gel matrix doped with metalloporphyrin and 7- amino-4-trifluoromethyl coumarin. Sens. Actuators, B. 134(2) : 711-717.

Jones, R. G. (1995). Silicon-Containing Polymers. Cambridge : RoyalSociety of Chemistry.

Choi, M.M.F. and Xiao, D. (2000). Single standard calibration for an optical oxygen sensor based on luminescence quenching of a ruthenium complex. Anal. Chim. Acta. 403 : 57–65.

Chen, M., Ghiggino, K.P., Launikonis, A., Mau, A.W.H., Rizzardo, E., Sasse, W.H.F., Thang, S.H. and Wilson, G.J. (2003). RAFT synthesis of linear and star-shaped light harvesting polymers using di- and hexafunctional ruthenium polypyridine reagents. J. Mater. Chem. 13 : 2696-2700.

McDonald, J.C., Duffy, D.C., Anderson, J.R., Chiu, D.T., Wu, H. and Whitesides, G. M. (2000). Fabrication of microfluidic systems in poly (dimethylsiloxane). Electrophoresis. 21 : 27-40.

Lakowicz, J.R. (2006). Principle of Fluorescence Spectroscopy. 3rd ed. New York : Springer.

ดาวน์โหลด

เผยแพร่แล้ว

2013-06-30

วิธีการอ้างอิง

[1]
C. Su-Ngam, S. H. . Thang, A. . Wongchaisuwat, และ L. Meesuk, “Dissolved oxygen sensor film using ruthenium polypyridine complex as luminophore”, J Met Mater Miner, ปี 23, ฉบับที่ 1, มิ.ย. 2013.

ฉบับ

ปีที่ 23 ฉบับที่ 1 (2013)

บท

Original Research Articles

การอนุญาต

ลิขสิทธิ์ (c) 2013 วารสารโลหะ, วัสดุ และแร่

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