The usage of CoAl−layered double oxide for removal of toxic dye from aqueous solution
Keywords:Layered double oxide, Orange II, Methyl orange, Phenolphthalein, Methylene blue
CoAl-layered double oxide derived from calcination of CoAl-layered double hydroxide at 400°C for 120 min, delivered the change in microstructure with increasing surface area. Spinel Co3O4 was the majority in the product as confirmed by X-ray diffraction, and Fourier transform infrared and UV-visible spectroscopies. The calcined product, CoAl-layered double oxide resulted in significant adsorption capacity on dye removal superior to that of CoAl-layered double hydroxide. The adsorbed amounts of the diverse dyes increased as follows: methylene blue < phenolphthalein < methyl orange < orange II. The adsorption affinity between adsorbent and dyes relied on electrostatic interaction and physical adsorption.
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