Processing of nano fillers in nitrile rubber – A novel technique
Keywords:
Nano-TiO2, Nano Silica, NBR, Liquid NBR, Morphology, Mechanical properties, Microstructure characterizationAbstract
Dispersion of various nano fillers like Nano silica, nano clay, Nano TiO2, etc has been attempted in NBR rubbers using new technique of dispersion. Liquid NBR is taken as dispersion media for nano fillers in polymer matrix and polymer nano composites were characterized by Rubber Process Analyzer [RPA-2000, USA]. The dispersion of the nano fillers were investigated by XRD, SEM-EDS. The effect of increasing nano- fillers on mechanical properties like tensile strength, modulus and Elongation at break was studied. Hot air ageing of polymer nano composites was also studied. Dispersion of various nano fillers like Nano silica, nano clay, Nano TiO2, etc has been attempted in NBR rubbers using new technique of dispersion. Liquid NBR is taken as dispersion media for nano fillers in polymer matrix and polymer nano composites were characterized by Rubber Process Analyzer [RPA-2000, USA]. The dispersion of the nano fillers were investigated by XRD, SEM-EDS. The effect of increasing nano- fillers on mechanical properties like tensile strength, modulus and Elongation at break was studied. Hot air ageing of polymer nano composites was also studied.Downloads
References
Novak, B.M. (1993). Hybrid nanocomposite materials-between inorganic glasses and organic polymers. Adv. Mater. 5(6) : 422-433.
Mark, J. E. (1996). Ceramic-reinforced polymers and polymer-modified ceramics. Polym. Eng. Sci. 36(24) : 2905-2920.
Vollath, D. and Szabó, D.V. (2004). Synthesis and Properties of Nanocomposites. Adv. Eng. Mater. 6(3) : 117-127.
Messersmith, P.B. and Giannelis, E.P. (1993). Polymer-layered silicate nanocomposites: in situ intercalative polymerization of epsilon-caprolactone in layered silicates. Chem. Mater. 5(8) : 1064-1066.
Giannelis, E.P. (1996). Polymer layered silicate nanocomposites. Adv. Mater. 8(1) : 29-35.
Zilg, C., Thomann, R., Finter, J. and Mulhaupt, R. (2000). The influence of silicate modification and compatibilizers on mechanical properties and morphology of anhydride-cured epoxy nanocomposites. Macromol. Mater. Eng. 280 : 41-46.
Ray, S.S. and Okamoto, M. (2003). Polymer/layered silicate nanocomposites : a review from preparation to processing. Prog. Polym. Sci. 28(11) : 1539-1641.
Usuki, A., Hasegawa, N. and Kato, M. (2005). Polymer-clay nanocomposites. Adv. Polym. Sci. 179 : 135-195.
Wu, Y.P., Wang, Y.Q., Zhang, H.F., Wang, Y.Z., Yu, D.S., Zhang, L.Q. and Yang, J. (2005). Rubber-pristine clay nanocomposites prepared by co-coagulating rubber latex and clay aqueous suspension. Compos. Sci. Technol. 65(7-8) : 1195-1202.
Ajayan, P. M. and Zhou, O. Z. (2001). Applications of carbon nanotubes. Topics in Appl. Phys. 80 : 391-425.
Dai, L.M. and Mau, A.W.H. (2001). Controlled synthesis and modification of carbon nanotubes and C-60 : Carbonnanostructures for advanced polymer composite materials. Adv. Mater. 13 : 899-913.
Coleman, J. N., Khan, U. and Gun’ko, Y. K. (2006). Mechanical reinforcement of polymers using carbon nanotubes. Adv. Mater. 18 : 689-706.
Rajkumar, K., Kumari, N., Ranjith, P., Chakraborty, S. K., Thavamani, P., Pazhanisamy, P. and Jeyanthi, P. (2011). High temperature resistance properties of NBR based polymer nanocomposites. Int. J. Chem. Tech. Res. 3(3) : 1343-1348.
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