Ferroelectric glass-ceramic sintering aid for lead titanate ceramics
Keywords:
lead titanate, glass-ceramics, sintering aids, dielectric, impedance spectroscopyAbstract
Silicate-based glass that devitrifies on heating to form ferroelectric lead titanate has been developed. The potential for use as sintering aid in PbO-based electroceramics has been evaluated by studying the densification of PbTiO3 (PT) with increasing wt% addition of glass powder. As the wt% glass content increased, the density increased, the maximum and room temperature relative permittivity decreased and there was also a decrease in Tc and the c/a ratio. The decrease in Tc is believed to be due to increased clamping from neighbouring grains as the density of the PT increases. The decrease in maximum and room temperature relative permittivity is related to the presence of secondary phases.
Downloads
References
Corker, D.L., Whatmore, R.W., Ringgaard, E. and Wolny, W.W. 2000. Liquid-phase sintering of PZT ceramics. J. Europ. Ceram. Soc. 20(12) : 2039 – 2045.
Chowdary, K.R. and Subbarao, E.C. 1981. Ferroelectrics. 37 : 689
Desgardin, G., Mey, I. and Raveau, B. 1985. Am. Ceram. Soc Bull. 64(4) : 560.
Sarkar, S.K. and Sharma, M.L. 1989. Mater. Res. Bull. 24 : 773.
Burn, I. 1982. J. Mater. Sci. 17(5) :1398-1408.
Lines, M.E. and Glass, A.M. 1979. Principles and Applications of Ferroelectrics and Related Materials. Oxford : University Press.
Palkar, V. R., Chattopadhyay, S., Ayyub, P., Multani, M., Paranjape, S.K. and Siruguri, V. 1997. A study of the structure and composition of Si-doped Pb TiO3. Mater. Lett. 32(2-3) :171 – 174.(1997)
Palkar, V. R., Purandare, S. C. and Pinto, R. 2000. Breakthrough in densification of ferroelectric Pb TiO3 with Si as sintering aid. Mater. Lett. 43(5-6) : 329 – 334.
Mendiola, J., Calzada, M.L., Ramos, P., Martin, M.J. and Agullo-Rueda, F. 1998. On the effects of stresses in ferroelectric (Pb, Ca) TiO3 thin films. Thin Solid Films. 315 (1- 2) : 195 – 201.
Tickoo, R., Tandon, R.P., Bamzai, K.K. and Kotru, P.N. 2003. Dielectric and piezoelectric characteristics of samarium modified lead titanate ceramics. Mater. Sci. Eng. B – Solid State Materials for Advanced Technology. 103(2) : 145 – 151.
Chu, S.Y. and Chen, T.Y. 2003. J. Europ. Ceram. Soc. 24 : 1993.
Shyu, J. J. and Yang, Y.S. J.Am. Ceram. Soc. 78(6) : 1463.
Sooksaen, P., Reaney, I.M. and Sinclair, D.C. 2005. Lead titanate glass-ceramics derived from a silicate-based melt. J. Mater. Res. 20(5) : 1316 – 1323.
Morrison, F. D., Sinclair D. C. and West, A. R. 2001. Characterization of lanthanumdoped barium titanate ceramics using impedance spectroscopy. J. Am. Ceram. Soc. 84(3) : 531 – 538.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2017 Journal of Metals, Materials and Minerals
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Authors who publish in this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.