A comparative study of nanofibrillated cellulose and microcrystalline cellulose as reinforcements in all-cellulose composites
Keywords:
Cellulose, Composites, Biodegradability, Mechanical properties, Films, Rule of mixturesAbstract
The reinforcing abilities of nanofibrillated cellulose (NFC) and microcrystalline cellulose (MCC) in composites were investigated and compared. All-cellulose composites were prepared using the dissolved MCC as the matrix, and NFC and MCC were introduced as the reinforcing phase. With the addition of MCC, tensile strength of the composites decreased; on the other hand, the higher tensile strength of the composites with NFC was found with increasing a NFC content. Strong interfacial interaction between the matrix and reinforcing phase could be obtained at a low content of the reinforcement was observed. At a higher content of the reinforcement the fiber pull-out was found from the fracture surface of the composites after tensile deformation. The reinforcing abilities of NFC and MCC were also confirmed by the comparison between values of the Young’s moduli of the composites obtained from the experiments and calculations using the rule of mixtures equation. From these results it could be summarized that NFC had the higher reinforcing ability than MCC.Downloads
References
T. Nishino, I. Matsuda, and K. Hirao, "Allcellulose composite," Macromolecules, vol. 37, pp. 7683-7687, 2004.
M. Ghaderi, M. Mousavi, H. Yousefi, and M. Labbafi, "All-cellulose nanocomposite film made from bagasse cellulosenanofibers for food packaging application," Carbohydrate Polymers, vol. 104, pp. 59-65, 2014.
S. Tanpichai and S. Witayakran, "All-cellulose composites from pineapple leaf microfibers: Structural, thermal, and mechanical properties," Polymer Composites, vol. 39, pp. 895-903, 2018.
S. Tanpichai and S. Witayakran, "All-cellulose composite laminates prepared from pineapple leaf fibers treated with steam explosion and alkaline treatment," Journal of Reinforced Plastics and Composites, vol. 36, pp. 1146- 1155, 2017.
S. Tanpichai and S. Witayakran, "Mechanical properties of all-cellulose composites made from pineapple leaf microfibers," Key Engineering Materials, vol. 659, pp. 453-457, 2015.
N. Soykeabkaew, T. Nishino, and T. Peijs, "All-cellulose composites of regenerated cellulose fibres by surface selective dissolution," Composites Part A: Applied Science and Manufacturing, vol. 40, pp. 321- 328, 2009.
W. Gindl and J. Keckes, "All-cellulose nanocomposite," Polymer, vol. 46, pp. 10221- 10225, 2005.
T. Huber, J. Mussig, O. Curnow, S. S. Pang, S. Bickerton, and M. P. Staiger, "A critical review of all-cellulose composites," Journal of Materials Science, vol. 47, pp. 1171-1186, 2012.
J. Zhao, X. He, Y. Wang, W. Zhang, X. Zhang, X. Zhang, Y. Deng, and C. Lua, "Reinforcement of all-cellulose nanocomposite films using native cellulose nanofibrils," Carbohydrate Polymers, vol. 104, pp. 143-150, 2014.
K.-Y. Lee, Y. Aitomaki, L. A. Berglund, K. Oksman, and A. Bismarck, "On the use of nanocellulose as reinforcement in polymer matrix composites," Composites Science and Technology, vol. 105, pp. 15-27, 2014.
S. J. Eichhorn, A. Dufresne, M. Aranguren, N. E. Marcovich, J. R. Capadona, S. J. Rowan, C. Weder, W. Thielemans, M. Roman, S. Renneckar, W. Gindl, S. Veigel, J. Keckes, H. Yano, K. Abe, M. Nogi, A. N. Nakagaito, A. Mangalam, J. Simonsen, A. S. Benight, A. Bismarck, L. A. Berglund, and T. Peijs, "Review: Current international research into cellulose nanofibres and nanocomposites," Journal of Materials Science, vol. 45, pp. 1-33, 2010.
S. Tanpichai and J. Wootthikanokkhan, "Mechanical properties of poly (lactic acid) composites reinforced with microfibrillated cellulose prepared using high speed blending," Journal of Metals, Materials and Minerals, vol. 24, pp. 55-60, 2014.
F. W. Herrick, R. L. Casebier, J. K. Hamilton, and K. R. Sandberg, "Microfibrillated cellulose: morphology and accessibility," Journal of Applied Polymer Science: Applied Polymer Symposium, vol. 37, pp. 797-813,
A. F. Turbak, F. W. Snyder, and K. R. Sandberg, "Microfibrillated cellulose, a new cellulose product: Properties, uses, and commercial potential," Journal of Applied Polymer Science: Applied Polymer Symposium, vol. 37, pp. 815-827, 1983.
I. Siro and D. Plackett, "Microfibrillated cellulose and new nanocomposite materials: A review," Cellulose, vol. 17, pp. 459-494, 2010.
N. Lavoine, I. Desloges, A. Dufresne, and J. Bras, "Microfibrillated cellulose – Its barrier properties and applications in cellulosic materials: A review," Carbohydrate Polymers, vol. 90, pp. 735-764, 2012.
M. Jonoobi, R. Oladi, Y. Davoudpour, K. Oksman, A. Dufresne, Y. Hamzeh, and R. Davoodi, "Different preparation methods and properties of nanostructured cellulose from various natural resources and residues: A review," Cellulose, vol. 22, pp. 935-969, 2015.
A. Iwatake, M. Nogi, and H. Yano, "Cellulose nanofiber-reinforced polylactic acid," Composites Science and Technology, vol. 68, pp. 2103-2106, 2008.
J. Lu, T. Wang, and L. T. Drzal, "Preparation and properties of microfibrillated cellulose polyvinyl alcohol composite materials," Composites Part A: Applied Science and Manufacturing, vol. 39, pp. 738-746, 2008.
M. O. Reis, J. Zanela, J. Olivato, P. S. Garcia, F. Yamashita, and M. V. E. Grossmann, "Microcrystalline cellulose as reinforcement in thermoplastic starch/poly (butylene adipate-coterephthalate) films," Journal of Polymers and the Environment, vol. 22, pp. 545-552, 2014.
S. J. Eichhorn and R. J. Young, "The Young's modulus of a microcrystalline cellulose," Cellulose, vol. 8, pp. 197-207, 2001.
S. Tanpichai, F. Quero, M. Nogi, H. Yano, R. J. Young, T. Lindström, W. W. Sampson, and S. J. Eichhorn, "Effective young's modulus of bacterial and microfibrillated cellulose fibrils in fibrous networks," Biomacromolecules, vol. 13, pp. 1340-1349, 2012.
H. Krenchel, fibre reinforcement. Copenhagen: akademisk forlag, 1964.
A. P. Mathew, K. Oksman, and M. Sain, "Mechanical properties of biodegradable composites from poly lactic acid (PLA) and microcrystalline cellulose (MCC)," Journal of Applied Polymer Science, vol. 97, pp. 2014- 2025, 2005. 1983.
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