The usage of CoAl−layered double oxide for removal of toxic dye from aqueous solution

Pornnapa Tongchoo; Sonchai Intachai; Prakaidao Pankam; Chomponoot Suppaso; Nithima Khaorapapong

doi:10.55713/jmmm.v30i4.897

Authors

Pornnapa Tongchoo Department of Chemistry, Faculty of Science, Thaksin University, Phatthalung, 93210, Thailand
Sonchai Intachai Department of Chemistry, Faculty of Science, Thaksin University, Phatthalung, 93210, Thailand
Prakaidao Pankam Department of Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand
Chomponoot Suppaso Department of Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand
Nithima Khaorapapong Department of Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand

DOI:

https://doi.org/10.55713/jmmm.v30i4.897

Keywords:

Layered double oxide, Orange II, Methyl orange, Phenolphthalein, Methylene blue

Abstract

CoAl-layered double oxide derived from calcination of CoAl-layered double hydroxide at 400°C for 120 min, delivered the change in microstructure with increasing surface area. Spinel Co₃O₄ was the majority in the product as confirmed by X-ray diffraction, and Fourier transform infrared and UV-visible spectroscopies. The calcined product, CoAl-layered double oxide resulted in significant adsorption capacity on dye removal superior to that of CoAl-layered double hydroxide. The adsorbed amounts of the diverse dyes increased as follows: methylene blue < phenolphthalein < methyl orange < orange II. The adsorption affinity between adsorbent and dyes relied on electrostatic interaction and physical adsorption.

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