Integration of jackfruit seed-derived carbon dots and electronic nose for a sensitive detection of formaldehyde vapor

ผู้แต่ง

  • Thitarat PRATHUMSUWAN Department of Chemistry, Faculty of Science and Technology, Thammasat University, Pathumthani, 12120 Thailand
  • Sumana KLADSOMBOON Department of Radiological Technology, Faculty of Medical Technology, Mahidol University, Nakhon Pathom, 73170 Thailand
  • Alfred Antony CHRISTY Department of Science, Faculty of Engineering and Science, University of Agder, Kristiansand, Norway
  • Insik IN Department of IT Convergence (Brain Korea PLUS 21), Korea National University of Transportation, Chungju 380-702, South Korea; Department of Polymer Science and Engineering, Korea National University of Transportation, Chungju 380-702, South Korea
  • Xiao LIANG College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, P. R. China
  • Shufeng SONG College of Aerospace Engineering, Chongqing University, Chongqing 400044, China
  • Yao WANG Guangdong Provincial Key Laboratory of Optical Information Materials and Technology, Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou, 510006, China; National Center for International Research on Green Optoelectronics, South China Normal University, Guangzhou, 510006, China
  • Thitirat INPRASIT Department of Materials and Textile Technology, Faculty of Science and Technology, Thammasat University, Pathumthani, 12120 Thailand
  • Peerasak PAOPRASERT Department of Chemistry, Faculty of Science and Technology, Thammasat University, Pathumthani, 12120 Thailand
  • Natee SIRISIT Department of Chemistry, Faculty of Science and Technology, Thammasat University, Pathumthani, 12120 Thailand

DOI:

https://doi.org/10.55713/jmmm.v34i1.1846

คำสำคัญ:

carbon dot, electronic nose, formaldehyde, jackfruit seed

บทคัดย่อ

The preparation of carbon dots from jackfruit seeds through a pyrolysis method at 280℃ and their use for the detection of formaldehyde were reported. The as-prepared carbon dots showed a high fluorescence efficiency with a quantum yield of 12.7% and excellent photostability and dispersibility in aqueous solution with a zeta potential of ‒62.5 mV. The integration of carbon dot thin film and a home-made optical electronic nose system possessed sensitivity towards formaldehyde vapor with a detection limit of 24.7%v/v across a linear range of 25%v/v to 100%v/v. Furthermore, the sensor showed the highest sensitivity towards formaldehyde against other volatile organic compounds through a strong interaction between the carbonyl groups and the carbon dots. Additionally, principal component analysis (PCA) was conducted to achieve quantitative measurements of formaldehyde content in different formaldehyde volume ratios with substantial variance. Due to the significance of methanol as a typical chemical precursor for the industrial manufacturing of formaldehyde, the quantitative analytical method is essential to determining formaldehyde or methanol concentration. The sensing ability of carbon dot film-integrated electronic nose towards formaldehyde in formaldehyde/methanol mixtures was measured to be 10.74%v/v in a linear range of 25%v/v to 100%v/v. The PCA showed orderly linear combinations of the data set, which can be potentially utilized to analyze formaldehyde and methanol content in industrial processes. The results indicate the significant potential of carbon dots and optical electronic nose system as an effective formaldehyde sensing platform. Potential applications include the quantification of formaldehyde from methanol conversion and determination of methanol contaminant in formaldehyde.

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เอกสารอ้างอิง

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2024-02-01

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[1]
T. . PRATHUMSUWAN, “Integration of jackfruit seed-derived carbon dots and electronic nose for a sensitive detection of formaldehyde vapor”, J Met Mater Miner, ปี 34, ฉบับที่ 1, น. 1846, ก.พ. 2024.

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