UV radiation energy consumption in curing process of epoxidized sunflower oil-organoclay hybrid coatings
คำสำคัญ:
Epoxidized sunflower oil, UV curable coatingsบทคัดย่อ
Epoxidized sunflower oil (ESO) can be cured with ultraviolet radiation using either cationic or hybrid initiation. The organoclay was prepared by the cationic exchange process, in which sodium ions were replaced by alkyl ammonium ions. Organoclay was incorporated into epoxidized sunflower oil UVcurable systems. The effects of diluents and types of photo initiators were studied. It was found that the formulations with a hybrid photoinitiator required less energy in the curing process than those with a cationic photoinitator. Moreover, the formulations without diluent can be cured with lower radiation energy than those with diluent.Downloads
เอกสารอ้างอิง
Alexandre, M. and Dubois, P. 2000. Polymerlayered Silicate Nanocomposites : Preparation, Properties and uses of a new class of material. Mater. Sci. Eng. 28 : 1-6.
Vaia, R. A. and Giannelis, E.P.1997. Lattice model of Polymer melt intercalation in organically-modified layered silicates. Macromolecules. 30 : 7990.
Zhang, Q., Fu, Q., Jaing, L. and Lei, Y. 2000. Preparation and properties of polypropylene/montmorillonite layered nanocomposites. Polym. Int. 49 : 1561.
Kato, M., Usuki, A., and Okada, A. 1997. Synthesis of polypropylene oligomer-clay intercalation compounds. J. Appl. Polym. Sci. 66 : 1781.
Akelah, A. and Moet, A.1996. J. Mater Sci. 31 : 1064.
Doh, J. G. and Cho, I. 1998. Synthesis and properties of polystyrene-organoammomontmorillonite hybrid. Polym. Bull. 41 : 511.
Wang, Z. and Pinnavaia, T.J. 1998. Nanolayer reinforcement of elastomeric polyurethane. Chem. Mater. 10 : 3769.
Decker, C. 1996. Photoinitiated crosslinking polymerisation . Prog. Polym. Sci. 21 : 593.
Decker, C. 2002. Kinetic Study and New applications of UV radiation curing. Macromol. Rapid. Commun. 23 : 1067.
Technical Information, 2004. UV curing, Technical principle and mechanism. Ciba Specialty Chemicals
Crivello, V.J. and Ghoshai, R. 1994. UVcurable coating. US Patent 5318808, June.
Treybig, D. S., Wang, D. S. Sheih, P. S. and Ho, L. A. 1992. Advanced epoxy compositions, curable compositions and cured products. US Patent 5151485, Sept.
Wan Rosli, W.D., Kumar, R.N., Mek Zah, S. and Hilmi Mohd, M. 2003. UV radiation curing of epoxidized palm oil–cycloaliphatic diepoxide system induced by cationic photoinitiators for surface coatings. Eur. Polym. J. 39 : 593-600.
Raghavachar, R., Sarnecki, G., Baghdachi, J. and Massingill, J. 2000. Cationic, thermally cured coatings using epoxidized soybean oil. J. Coat. Tech. 72 : 125.
Thames, S.F. and Yu, H.1999. Cationic UVcured coatings of epoxide-containing vegetable oils. Surf. Coat. Tech. 115 : 208.
Jourdan-Laforte, Eric 1980. US Patent 4215058, Dec.
Jiratumnukul, N., Pruthipaitoon, S. and Pitsaroup, T. 2006. Nanocomposite alkyd coatings. J. Appl. Polym. Sci. 102 : 2639.
ดาวน์โหลด
เผยแพร่แล้ว
วิธีการอ้างอิง
ฉบับ
บท
การอนุญาต
ลิขสิทธิ์ (c) 2017 Journal of Metals, Materials and Minerals
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Authors who publish in this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.