Photocatalytic degradation of ciprofloxacin drug utilizing novel PVDF/polyaniline/ lanthanum strontium manganate@Ag composites

Authors

  • Swayam Aryam BEHERA Department of Chemistry, Faculty of Engineering and Technology (ITER), Siksha ‘O’ Anusandhan, Deemed to be university, Bhubaneswar, Odisha, 751030, India
  • Ali AMANAT Department of New Materials and Nanotechnology, National University of Science and Technology MISiS, Moscow, Russia
  • P. Ganga Raju ACHARY Department of Chemistry, Faculty of Engineering and Technology (ITER), Siksha ‘O’ Anusandhan, Deemed to be university, Bhubaneswar, Odisha, 751030, India

DOI:

https://doi.org/10.55713/jmmm.v34i1.1896

Keywords:

PVDF, LMSO, Polyaniline, Photocatalysis, Drug reduction

Abstract

Poly (vinylidene fluoride) (PVDF) is the first-choice ferroelectric support or membrane material. The lanthanum strontium manganite (LSMO) is a well-known electrode material in the class of the solid oxide fuel cell (SOFC) materials. A set of four polymer composites PVDF-LSMO-PANI(5.0 wt%) with different amount of silver doping were fabricated with the silver nitrate and reducing agent. The characterization of these four novel PVDF based composites were characterized by the XRD, FTIR, SEM, UV-Visible DRS. The present communication highlights: (I) the effect of PANI in the PVDF-LSMO-PANI (PLP) composites towards the photocatalytic degradation of ciprofloxacin drug. (II) the effect of Ag doping in the Ag-PVDF-LSMO-PANI (Ag-PLP) composites towards the photocatalytic degradation of ciprofloxacin drug. It is observed that the incorporation of PANI in PVDF-LSMO and Ag in PVDF-LSMO-PANI polymer ceramic composites showed enhanced photocatalytic degradation of ciprofloxacin in the irradiation of visible radiation. The plausible separation of photo-generated e- hole pairs (e- and h+) carried on by charge migration kind of mechanism is being studied here to understand the improved photocatalytic activity of Ag-PVDF-LSMO-PANI composites.

Downloads

Download data is not yet available.

References

P. M. Rajaitha, S. Hajra, M. Sahu, K. Mistewicz, B. Toron, R. Abolhassani, S. Pando, Y. K. Mishra, and H. J. Kim, “Unraveling highly efficient nanomaterial photocatalyst for pollutant removal: a comprehensive review and future progress,” Materials Today Chemistry, vol. 23, p. 100692, 2022.

K. Wirandorn, N. Panyayao, and V. Siriwongrungson, “Characterization and photocatalytic activity of titanium dioxide deposited on stainless steel by pulsed-pressure MOCVD,” Journal of Metals, Materials and Minerals, vol. 28, no. 2, 2018.

P. Norranattrakul, K. Siralertmukul, and R. Nuisin, “Fabrication of chitosan/titanium dioxide composites film for the photocatalytic degradation of dye,” Journal of Metals, Materials and Minerals., vol. 23, no. 2, 2013.

J. Swain, A. Priyadarshini, S. Hajra, S. Panda, J. Panda, R. Samantaray, Y. Yamauchi, M. Han, H. J. Kim, and R. Sahu, “Photocatalytic dye degradation by BaTiO3/zeolitic imidazolate framework composite,” Journal of Alloys and Compounds, vol. 965, p. 171438, 2023.

S. Saha, R. P. Singh, A. Rout, A. Mishra, A. Ali, H. Basumatary, and R. Ranjan ,“Inducing ferromagnetism and magnetoelectric coupling in the ferroelectric alloy system BiFeO3--PbTiO3 via additives,” Journal of Applied Physics, vol. 133, no. 6, 2023.

H. Wang, J. Li, P. Huo, Y. Yan, and Q. Guan, “Preparation of Ag2O/Ag2CO3/MWNTs composite photocatalysts for enhancement of ciprofloxacin degradation,” Applied Surface Science, vol. 366, pp. 1-8, 2016.

N. R. Alluri, B. Saravanakumar, and S.-J. Kim, “Flexible, hybrid piezoelectric film (BaTi (1--x) Zr x O3)/PVDF nanogenerator as a self-powered fluid velocity sensor,” ACS Applied Materials & interfaces, vol. 7, no. 18, pp. 9831-9840, 2015.

Y. Zhang, Y. Zhang, X. Xue, C. Cui, B. He, Y. Nie, P. Deng, and Z. L. Wang, “PVDF--PZT nanocomposite film based self-charging power cell,” Nanotechnology, vol. 25, no. 10, p. 105401, 2014.

D. Olmos, G. González-Gaitano, A. L. Kholkin, and J. González-Benito, “Flexible PVDF-BaTiO3 nanocomposites as potential materials for pressure sensors,” Ferroelectrics, vol. 447, no. 1, pp. 9-18, 2013.

J. Prokeš, and J. Stejskal, “Polyaniline prepared in the presence of various acids: 2. Thermal stability of conductivity,” Polymer Degradation and Stability, vol. 86, no. 1, pp. 187-195, 2004.

P. K. Kahol, K. K. S. Kumar, S. Geetha, and D. C. Trivedi, “Effect of dopants on electron localization length in polyaniline,” Synthetic Metals, vol. 139, no. 2, pp. 191-200, 2003.

F. Davodi, M. Tavakkoli, J. Lahtinen, and T. Kallio, “Straightforward synthesis of nitrogen-doped carbon nanotubes as highly active bifunctional electrocatalysts for full water splitting,” Journal of Catalysis, vol. 353, pp. 19-27, 2017.

T. Rasheed, M. Bilal, F. Nabeel, M. Adeel, and H. M. N. Iqbal, “Environmentally-related contaminants of high concern: potential sources and analytical modalities for detection, quantification, and treatment,” Environment International, vol. 122, pp. 52-66, 2019.

A. K. Al-Buriahi, M. M. Al-shaibani, R. M. S. R. Mohamed, A. A. Al-Gheethi, A. Sharma, and N. Ismail, “Ciprofloxacin removal from non-clinical environment: A critical review of current methods and future trend prospects,” Journal of Water Process Engineering, vol. 47, p. 102725, 2022.

M. Danish, L. L. Estralla, I. M. A. Alemaida, A. Lisin, N. Moiseev, M. Ahmadi, M. Nazari, M. Wali, H. Zaheb, and T. Senjyu, “Photocatalytic applications of metal oxides for sustainable environmental remediation,” Metals (Basel)., vol. 11, no. 1, p. 80, 2021.

P. G. R. Achary, P. Pattanaik, and B. Nanda, “Facile synthesis of lanthanum doped strontium manganite for photocatalytic decolourization of malachite green,” Inorganic Chemistry Communications., vol. 158, p. 111545, 2023.

X. Du, Y. Xu, L. Xiong, Y. Bai, J. Zhu, and S. Mao, “Polyaniline with high crystallinity degree: Synthesis, structure, and electro-chemical properties,” Journal of Applied Polymer Science, vol. 131, no. 19, 2014.

A. N. Jarad, K. Ibrahim, and N. M. Ahmed, “Synthesis and characterization thin films of conductive polymer (PANI) for optoelectronic device application,” in AIP Conference Proceedings, 2016, vol. 1733, no. 1, p. 20020.

J. Coates, “Interpretation of infrared spectra, a practical approach.” 2000.

P. A. Tamirisa, Kn. C. Liddell, P. D. Pedrow, and M. A. Osman, “Pulsed-plasma-polymerized aniline thin films,” Journal of Applied Polymer Science, vol. 93, no. 3, pp. 1317-1325, 2004.

T. Ohsaka, Y. Ohnuki, N. Oyama, G. Katagiri, and K. Kamisako, “IR absorption spectroscopic identification of electroactive and electroinactive polyaniline films prepared by the electro-chemical polymerization of aniline,” Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol. 161, no. 2, pp. 399-405, 1984.

R. gregorio jr and M. cestari, “Phase content and morphology of poly (vinylidene fluoride)”.

A. Abulizi, K. Kadeer, H. Maimaitizi, Y. Tursun, and D. Talifu, “In situ ultrasound-assisted ion exchange synthesis of sphere-like AgClxBr1-x composites with enhanced photocatalytic activity and stability,” Environmental Science and Pollution Research, vol. 27, pp. 43615-43624, 2020.

M. Sharma, J. K. Quamara, and A. Gaur, “Behaviour of multiphase PVDF in (1-x) PVDF/(x) BaTiO3 nanocomposite films: structural, optical, dielectric and ferroelectric properties,” Journal of Materials Sciecnce: Materials in Electronics, vol. 29, pp. 10875-10884, 2018.

Y. Lu, Y. Ma, T. Yang, and J. Guo, “Hydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO2,” Green Processing and Synthesis, vol. 10, no. 1, pp. 538-546, 2021.

S. Sathiyanarayanan, S. S. Azim, and G. Venkatachari, “Preparation of polyaniline--Fe2O3 composite and its anti-corrosion performance,” Synthetic Metals, vol. 157, no. 18-20, pp. 751–757, 2007.

S. M. Ambalagi, M. Devendrappa, S. Nagaraja, and B. Sannakki, “Dielectric properties of PANI/CuO nanocomposites,” in IOP Conference Series: Materials Science and Engineering, 2018, vol. 310, no. 1, p. 12081.

J. Li, S. K. Cushing, F. Meng, T. R. Senty, A. D. Bristow, and N. Wu, “Plasmon-induced resonance energy transfer for solar energy conversion,” Nature Photonics, vol. 9, no. 9, pp. 601-607, 2015.

K. A. Willets, and R. P. Van Duyne, “Localized surface plasmon resonance spectroscopy and sensing,” Annual Reviews of Physical Chemistry, vol. 58, pp. 267-297, 2007.

Downloads

Published

2023-12-19

How to Cite

[1]
S. A. . BEHERA, A. AMANAT, and P. G. R. . ACHARY, “Photocatalytic degradation of ciprofloxacin drug utilizing novel PVDF/polyaniline/ lanthanum strontium manganate@Ag composites”, J Met Mater Miner, vol. 34, no. 1, p. 1896, Dec. 2023.

Issue

Section

Original Research Articles