Corrosion behavior of AISI 4140 steel surface coated by physical vapor deposition


  • Chonthicha Keawhan School of Metallurgical Engineering, Institute of Engineering, Suranaree University of Technology
  • Pornwasa Wongpanya School of Metallurgical Engineering, Institute of Engineering, Suranaree University of Technology
  • Nirun Witit-anun Department of Physics, Burapha University
  • Prayoon Songsiriritthigul Synchrotron Light Research Institute (Public Organization), Nakhon Ratchasima


AISI 4140 steel, Chromium nitride coating, Electrochemical technique, 3.5-wt% NaCl solution


The corrosion behavior of uncoated and CrN-coated onto AISI 4140 steel was studied by electrochemical technique. Firstly, the AISI 4140 steel samples were solution heat treated and oil quenched in order to achieve proper hardness. Then, they were surface-prepared with alteration of surface roughness by using SiC paper at different numbers of 180, 600, and 1200 prior to CrN coating. The samples were coated with CrN film by physical vapor deposition (PVD) technique. The corrosion behavior of the uncoated and CrN-coated samples was studied in air-saturated 3.5 wt% NaCl solution at the pH values of 2, 7 and 10 at room temperature. Before and after corrosion testing, the surface of the uncoated and CrN-coated samples was characterized by scanning electron microscopy (SEM) with chemical composition analysis by energy dispersive X-rays (EDX).The results showed that the CrN-coated samples exhibited lower corrosion rate than the uncoated samples at all pH values. In addition, it was found that corrosion rate of the uncoated and CrNcoated samples significantly altered with the surface roughness of the substrate prior to coating. The finer surface roughness is, the more corrosion resistance is.


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Sivitski, A., Ajaots, M. and Podra, P. (2008) . Wear PVD Hard Coatings in Sliding Contacts. In : Proceedings of the 6th International DAAAM Baltic Conference Industrial Engineering. Tallinn, Estonia : 549-554.

Darja, K.M., Peter, P., Miha, C. and Marijan, M. (2004). The corrosion behavior of Cr-(C,N) PVD hard coatings deposited on various substrates. Electrochim. Acta 49 (9-10) : 1527-1533.

Zhou, Q.G., Bai, X.D., Chen, X.W., Peng, D.Q., Ling, Y.H. and Wang, D.R. (2003). Corrosion Resistance of Duplex and Gradient CrNx Coated H13 Steel. Appl. Surf. Sci. 211 (1-11) : 293-299.

Cunha, L., Andritschky, M., Rebouta, L. and Pischow, K. (1999). Corrosion of CrN TiAlN coatings in chloride - containing atmosphere. Surf. Coat. Technol. 116-119 : 1152-1160.

Chyou, S. D. and Shih, H. C.(1991). The effect of nitrogen on the corrosion of plasma - nitrided 4140 steel. Corrosion. 47(1) : 31-34.

Grabke, H. J. (1996) . The role of nitrogen in the corrosion of iron and steels (review). ISIJ. Int. 36(7) : 777-786.

Hui, P.F., Cheng, H.H., Jung, K.L. and Yih, H.S. (2003). Effects of PVD sputtered coating on the corrosion resistance of AISI304 stainless steel. Mater. Sci. Eng. 347(1-2): 123-129.

Jones, D. A. (1996). Principles and prevention of corrosion. 2nd ed. London : Prentice Hall : 292-304.

Liu, C., Leyland, A., Lyon, S. and Matthews, A. (1995). An a.c impedance study on PVD-coated mild steel with different surface roughness. Surf. Coat. Technol. (part2) : 76-77 : 623-631.

Walter, R. and Bobby Kannan, M. (2011). Influence of surface roughness on the corrosion behavior of magnesium alloy. Mater. Des. 32(4) : 2350-2354.

Ahn, S.H., Yoo, J.H., Choi, Y.S., Kim, J.G. and Han, J.G. (2003). Corrosion behavior of PVD-Grown WC–(Ti1-x Alx)N Films in a 3.5 wt% NaCl solution. Surf. Coat. Technol. 162(2-3) : 212-221.




How to Cite

C. Keawhan, P. . Wongpanya, N. . Witit-anun, and P. Songsiriritthigul, “Corrosion behavior of AISI 4140 steel surface coated by physical vapor deposition”, J Met Mater Miner, vol. 22, no. 1, Jun. 2012.



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