Ultraviolet‐shielding and water resistance properties of graphene quantum dots/ polyvinyl alcohol composite-based film


  • Sutthipoj Wongrerkdee Department of Physics, Faculty of Liberal Arts and Science, Kasetsart University Kamphaeng Saen Campus, Nakhon Pathom 73140, Thailand
  • Pichitchai Pimpang Faculty of Science and Technology, Pibulsongkram Rajabhat University, Phitsanulok 65000, Thailand




Graphene quantum dots, UV‐shielding, Optical transmittance, UV absorption, Water resistance


The Ultraviolet‐shielding (UV‐shielding) and water resistance properties of graphene quantum dots/polyvinyl alcohol (GQDs/PVA) composite-based film have been investigated. The GQDs/PVA composite-based films were fabricated with different GQDs concentrations of 0, 5, 10, 15, and 20 wt%. The optical property of GQDs was carried out by utilizing fluorescence spectroscopy. Characterizations of GQDs/PVA composite-based films were performed by using FT-IR spectroscopy, and UV-vis spectroscopy. It was found that GQDs exhibited the strongest excitation wavelength in the UV range. GQDs/PVA composite-based films offered an improved UV-shielding capacity when compared to PVA films and glass. Particularly, the GQDs/PVA composite-based film containing 20 wt% GQDs exhibited a UV transmittance of 9.8%, combined with 84% optical transparency. For humidity environment application, the highest contact angle was explored for the 10 wt% GQDs contents suggesting sustainability for humidity environment application. Accordingly, GQDs played an important role in UV-shielding by considering the effect of UV absorption of GQDs and the UV absorption of GQDs can be explained in terms of the photon excitation by UV light. This GQDs/PVA composite could be potentially applied as transparent UV-protective coatings for pharmaceutical packing, food products packing, and UV-shielding or UV filter glass.


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B.L. Diffey, “Sources and measurement of ultraviolet radiation,” Methods, vol. 28, pp. 4-13, 2002.

A.R. Young, J. Claveau and A.B. Rossi, “Ultraviolet radiation and the skin: Photobiology and sunscreen photoprotection,” Journal of the American Academy of Dermatology, vol. 76, pp. S100-S109, 2017.

S.C. Harrison, and W.F. Bergfeld, “Ultraviolet light and skin cancer in athletes,” Sports health, vol. 1, pp. 335-340, 2009.

I. Savoye, C.M. Olsen, D.C. Whiteman, A. Bijon, L. Wald, L. Dartois, F. Clavel-Chapelon, M.C. Boutron-Ruault and M. Kvaskoff, “Patterns of ultraviolet radiation exposure and skin cancer risk: The E3N-SunExp study,” Journal of epidemiology, vol. 28(1), pp. 27-33, 2018.

S.E. Duncan, and S. Hannah, “Light-protective packaging materials for foods and beverages,” in Emerging Food Packaging Technologies, K.L. Yam and D.S. Lee, Eds., 1st ed., Cambridge, England: Woodhead Publishing, 2012, pp. 303-322.

D.D. Shah, J. Zhang, H. Maity, and K.M.G. Mallela, “Effect of photo-degradation on the structure, stability, aggregation, and function of an IgG1 monoclonal antibody,” International Journal of Pharmaceutics, vol. 547, pp. 438-449, 2018.

J. Zhu, S. Yan, N. Feng, L. Ye, J.Y. Ou, and Q.H. Liu, “Near unity ultraviolet absorption in graphene without patterning,” Applied Physics Letters, vol. 112, pp. 153106, 2018.

P. Tian, L. Tang, K.S. Teng, and S.P. Lau, “Graphene quantum dots from chemistry to applications,” Materials Today Chemistry, vol. 10, pp. 221-258, 2018.

N.F. Attia, J. Park, and H. Oh, “Facile tool for green synthesis of graphene sheets and their smart free-standing UV protective film,” Applied Surface Science, vol. 458, pp. 425-430, 2018.

S. Xie, J. Zhao, B. Zhang, Z. Wang, H. Ma, C. Yu, M. Yu, L. Li, and J. Li, “Graphene oxide transparent hybrid film and its ultraviolet shielding property,” ACS Applied Materials & Interfaces, vol. 7, pp. 17558-17564, 2015.

Y. Dong, J. Shao, C. Chen, H. Li, R. Wang, Y. Chi, X. Lin, and G. Chen, “Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid,” Carbon, vol. 50(12), pp. 4738-4743, 2012.

P. Pimpang, R. Sumang, and S. Choopun, “Effect of concentration of citric acid on size and optical properties of fluorescence graphene quantum dots prepared by tuning carbonization degree,” Chiang Mai Journal of Science, vol. 45(5), pp. 2005-2014, 2018.

G. Eda, G. Fanchini, and M. Chhowalla, “Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material,” Nature Nanotechnology, vol. 3, pp. 270-274, 2008.

K.S. Kim, Y. Zhao, H. Jang, S.Y. Lee, J.M. Kim, K.S. Kim, J.H. Ahn, P. Kim, J.Y. Choi, and B.H. Hong, “Large-scale pattern growth of graphene films for stretchable transparent electrodes,” Nature, vol. 457, pp. 706-710, 2009.

M.L. Tsai, W.C. Tu, L. Tang, T.C. Wei, W.R. Wei, S.P. Lau, L.J. Chen, and Jr.H. He, “Efficiency enhancement of silicon heterojunction solar cells via photon management using graphene quantum dot as downconverters,” Nano Letters, vol. 16(1), pp. 309-313, 2016.

S. Bak, D. Kim, and H. Lee, “Graphene quantum dots and their possible energy applications: A review,” Current Applied Physics, vol. 16(9), pp. 1192-1201, 2016.

Z. Xie, Q. Du, Y. Wu, X. Hao, and C. Liu, “Full-band UV shielding and highly daylight luminescent silane-functionalized graphene quantum dot nanofluids and their arbitrary polymerized hybrid gel glasses,” Journal of Materials Chemistry C, vol. 4, pp. 9879-9886, 2016.

C. Ge, and G. Devar, “Formation of Polyvinyl Alcohol film with graphene nanoplatelets and carbon black for electrostatic discharge protective packaging,” Journal of Electrostatics, vol. 89, pp. 52-57, 2017.

F.F. Hilmi, M.U. Wahit, N.A. Shukri, Z.Ghazali, and A.Z. Zanuri, “Physico-chemical properties of biodegradable films of polyvinyl alcohol/sago starch for food packaging,” Materials Today: Proceedings, vol. 16(4), pp. 1819-1824, 2019.

N. Jain, V.K. Singh, and S. Chauhan, “A review on mechanical and water absorption properties of polyvinyl alcohol based composites/films,” Journal of the Mechanical Behavior of Materials, vol. 26(5-6), pp. 213-222, 2017.

T. Pauporté, “Highly transparent zno/polyvinyl alcohol hybrid films with controlled crystallographic orientation growth,” Crystal Growth & Design, vol. 7(11), pp. 2310-2315, 2007.

A.A. Tager, A.A. Anikeyeva, L.V. Adamova, V.M. Andreyeva, T.A. Kuz'mina, and M.V. Tsilipotkina, “The effect of temperature on the water solubility of polyvinyl alcohol,” Polymer Science USSR, vol. 13(3), pp. 751-758, 1971.

M.H. Makled, E. Sheha, T.S. Shanap, and M.K. El-Mansy, “Electrical conduction and dielectric relaxation in p-type PVA/CuI polymer composite,” Journal of advanced research, vol. 4(6), pp. 531-538, 2013.

G.S. Kumar, U. Thupakula, P.K. Sarkar, and S. Acharya, “Easy extraction of water-soluble graphene quantum dots for light emitting diodes,” RSC Advances, vol. 5(35), pp. 27711-27716, 2015.

S. Ye, F. Xiao, Y.X. Pan, Y.Y. Ma, and Q.Y. Zhang, “Phosphors in phosphor-converted white light-emitting diodes: Recent advances in materials, techniques and properties,” Materials Science and Engineering: R: Reports, vol. 71(1), pp. 1-34, 2010.

P. Yang, L. Zhou, S. Zhang, N. Wan, W. Pan, and W. Shen, “Facile synthesis and photoluminescence mechanism of graphene quantum dots,” Journal of Applied Physics, vol. 116(24), pp. 244306-1-7, 2014.

J. Gu, X. Zhang, A. Pang, and J. Yang, “Facile synthesis and photoluminescence characteristics of blue-emitting nitrogen-doped graphene quantum dots,” Nanotechnology, vol. 27(16), pp. 165704, 2016.

H. Guo, F. Pang, X. Zeng, and T. Wang, “PbS quantum dot fiber amplifier based on a tapered SMF fiber,” Optics Communications, vol. 285, pp. 3222-3227, 2012.

D. Raeyani, S. Shojaei, S.A. Kandjani, and W. Wlodarski, “Synthesizing graphene quantum dots for gas sensing applications,” Procedia Engineering, vol. 168, pp. 1312-1316, 2016.

I.M. Jipa, A. Stoica, M. Stroescu, L. M. Dobre, T. Dobre, S. Jinga, and C. Tardei, “Potassium sorbate release from poly (vinyl alcohol)-bacterial cellulose films,” Chemical Papers, vol. 66(2), pp. 138-143, 2012.

Q. Luo, Y. Shan, X. Zuo, and J. Liu, “Anisotropic tough poly(vinyl alcohol)/graphene oxide nanocomposite hydrogels for potential biomedical applications,” RSC Advances, vol. 8(24), pp. 13284-13291, 2018.

G. Yang, X. Wan, Y. Liu, R. Li, Y. Su, X. Zeng, and J. Tang, “Luminescent poly(vinyl alcohol)/carbon quantum dots composites with tunable qater-induced shape memory behavior in different pH and temperature environments,” ACS Applied Materials & Interfaces, vol. 8(50), pp. 34744-34754, 2016.

T. Cheng-an, Z. Hao, W. Fang, Z. Hui, Z. Xiaorong, and W. Jianfang, “Mechanical properties of graphene oxide/polyvinyl alcohol composite film,” Polymers and Polymer Composites, vol. 25(1), pp. 11-16, 2017.

T. Wang, Y. Li, S. Geng, C. Zhou, X. Jia, F. Yang, L. Zhang, X. Ren, and H. Yang, “Preparation of flexible reduced graphene oxide/poly(vinyl alcohol) film with superior microwave absorption properties,” RSC Advances, vol. 5(108), pp. 88958-88964, 2015.

X. Yang, Y. Li, Q. Du, X. Wang, S. Hu, L. Chen, Z. Wang, Y. Xia, and L. Xia, “Adsorption of methylene Bblue from aqueous solutions by polyvinyl alcohol/graphene oxide composites,” Journal of Nanoscience and Nanotechnology, vol. 16(2), pp. 1775-1782, 2016.

P. Chouwatat, P. Polsana, P. Noknoi, K. Siralertmukul, and K. Srikulkit, “Preparation of hydrophobic chitosan using complexation method for PLA/Chitosan blend,” Journal of Metals, Materials and Minerals, vol. 20(1), pp. 41-44, 2010.




How to Cite

S. Wongrerkdee and P. Pimpang, “Ultraviolet‐shielding and water resistance properties of graphene quantum dots/ polyvinyl alcohol composite-based film”, J Met Mater Miner, vol. 30, no. 4, pp. 90–96, Dec. 2020.



Original Research Articles