Effect of carbon addition on microstructure and properties of boron-containing steel sintered under different atmospheres

ผู้แต่ง

  • Wantana Koetniyom Faculty of Applied Science, King Mongkut University of Technology North Bangkok and Lasers and Optics Research Center (Landos), King Mongkut University of Technology North Bangkok
  • Pisamorn Chantawet Faculty of Applied Science, King Mongkut University of Technology North Bangkok
  • Nattaya Tosangthum Particulate Materials Processing Technology Laboratory (PMPT), Thailand National Metal and Materials Technology Center
  • M Morakotjinda
  • Thanyaporn Yotkaew Particulate Materials Processing Technology Laboratory (PMPT), Thailand National Metal and Materials Technology Center
  • Pongsak Wila Particulate Materials Processing Technology Laboratory (PMPT), Thailand National Metal and Materials Technology Center
  • Ruangdaj Tongsri Particulate Materials Processing Technology Laboratory (PMPT), Thailand National Metal and Materials Technology Center

คำสำคัญ:

Liquid-phase sintering, Sintering atmosphere, Deboronization, Sintered steels

บทคัดย่อ

High performance sintered steels can be obtained by simultaneous tailoring microstructural feature and improving sintered density. Although sintered hardening is used to produce sintered components with microstructural features providing high tensile strength and hardness, but the performance is limited by low ductility due to the presence of porosity. Near full density can be achieved by liquid phase forming as a result of boron addition to a sintered steel. A liquid formed due to the eutectic reaction of Fe + Fe2B, spreads to interparticle spaces leading to densification improvement. Carbon is an indispensable element for high strength sintered steels. It plays important roles in both matrix microstructural development and intergranular liquid phase formation. This work has investigated the sintered Fe-1.5Mo-0.22B-xC steels (x = 0.1 - 0.4 wt.%) sintered under hydrogen and vacuum atmospheres. It was found that the hydrogen-sintered Fe-1.5Mo-0.22B-xC steels hardly showed evidences of intergranular liquid phase whereas all experimental vacuum-sintered steels showed intergranular boride. Deboronization is believed to contribute to the intergranular boride absence in the hydrogen-sintered steels. However, when the hardening effect was taken into account, the strengthening by intergranular liquid phase in the sintered steels was less important than precipitation strengthening. Advantage of ductility was only obtained in the vacuum-sintered steels with C contents £ 0.1 wt.%, whose microstructures contained discontinuous boride networks along polygonal ferrite grain boundaries. In contrast, the presence of continuous and thick boride networks caused embrittlement to the sintered steels.

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เอกสารอ้างอิง

P. K. Liao and K. E. Spear, “Alloy phase diagrams,” in ASM Handbook, vol. 3, ASM International, Ohio, 1992, pp. 2.8-9.8.

B. Loy and R. J. Dower, “The effect of boron on some properties of sintered iron- carbon alloys,” in Proceedings P/M-82, European International Powder Metallurgy Conference, Italy, 1982, pp. 377-391.

T. B. Sercombe, “Sintering of free formed maraging steel with boron additions,” Materials Science and Engineering A, vol. 363, pp. 242-252, 2003.

M. Sarasola, T. G. Acebo, and F. Castro, “Liquid generation during sintering of Fe- 3.5%Mo powder compacts with elemental boron additions,” Acta Materialia, vol. 52, pp. 4615-4622, 2004.

H. Ö. Gulsoy, “Influence of nickel boride additions on sintering behaviors of injection moulded 17-4 PH stainless steel powder,” Scripta Materialia, vol. 52, pp.187- 192, 2005.

M. W. Wu, “The influences of carbon and molybdenum on the progress of liquid phase sintering and the microstructure of boroncontaining powder metallurgy steel,” Metallurgical and Materials Transactions A, vol. 46, pp.467-475, 2015.

M. W. Wu, W. Z. Cai, Z. J. Lin, and S. H. Chang, “Liquid phase sintering mechanism and densification behavior of boron-alloyed Fe-Ni-Mo-C-B powder metallurgy steel,” Materials and Design, vol. 133, pp. 536-548, 2017.

J. Liu, A. Cardamone, T. Potter, R. M. German, and F. J. Semel, “Liquid phase sintering of iron-carbon alloys with boron additions,” Powder Metallurgy, vol. 43, pp.57-60, 2000.

Z. M. Xiu, “Fe-Mo-B-C sintered steels produced by addition of master alloy powders,” Acta Metallurgica Sinica, vol. 12, pp. 1198-1201, 1999.

P. Ninpetch, A. Luechaisirikul, M. Morakotjinda, T. Yotkaew, R. Krataitong, N. Tosangthum, S. Mahathanabodee, and R. Tongsri, “Effect of boron nitride on microstructure of Fe-Cr-Mo-BN-C steel sintered in vacuum,” Materials Today: Proceedings, vol. 5, no.3, pp. 9409-9416, 2018.

M. Tsuda, “Deboronization phenomena in Fe-Ni alloys,” Tetsu-to-Hagane, vol. 82, pp. 153-158, 1996.

J. Karwan-Baczewska and M. Rosso, “Effect of boron on microstructure and mechanical properties of PM sintered and nitrided steels,” Powder Metallurgy, vol.44, pp. 221- 227, 2001.

M. V. Sundaram, K. B. Surreddi, E. H. Eiga, S. Berg, F. Castro, and L. Nyborg, “Enhanced densification of PM steels by liquid phase sintering with boron-containing master alloy,” Metallurgical and Materials Transactions A, vol. 49, pp. 255-263, 2018.

A. Hadhud, “Design of reducing agent for sintering of high-performance alloyed PM steels based on different carbon grades analysis,” Diploma work No. 95/2012, Chalmers University of Technology, Sweden 2012.

H. I. Aaronson, W. T. Reynolds Jr., and G. R. Purdy, “Coupled-solute drag effects on ferrite formation in Fe-C-X systems,” Metallurgical and Materials Transactions A, vol. 35, pp.1187-1210, 2004.

M. Momeni, H. Danninger, A. Avakemian, and C. Gierl, “Thermoanalytical sintering studies of Fe-C admixed with ferroboron performed in different atmospheres,” Powder Metallurgy, vol. 55, pp. 54-64, 2012.

J. Kazior, “The influence of boron on the mechanical properties of prealloyed CrM powders,” in Deformation and Fracture in Structural PM Materials (DFPM 2002), Slovakia, 2002, pp.125-131.

J. Wang and S. Van Der Zwaag, “Stabilization mechanisms of retained austenite in transformation-induced plasticity steel,” Metallurgical and Materials Transactions A, vol. 32, pp. 1527-1539, 2001.

E. Jimenez-Melero, N. H. van Dijk, L. Zhao, J. Sietsma, S. E. Offerman, J. P. Wright, and S. van der Zwaag, “Characterization of individual retained austenite grains and their stability in low-alloyed TRIP steels”, Acta Materialia, vol. 55, pp. 6713-6723, 2007.

R. Pérez, J. A. Benito, and J. M. Prado, “Study of the inelastic response of TRIP steels after plastic deformation”, ISIJ International, vol. 45, pp. 1925-1933, 2005.

P. J. Jacques, “Transformation-induced plasticity for high strength formable steels,” Current Opinion in Solid State and Materials Science, vol. 8, pp. 259-265, 2004.

I. B. Timokhina, P. D. Hodgson, and E. V. Pereloma, “Effect of microstructure on the stability of retained austenite in transformation-induced-plasticity steels,” Metallurgical and Materials Transactions A, vol. 35, pp. 2331-2341, 2004.

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2019-03-29

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[1]
W. Koetniyom, “Effect of carbon addition on microstructure and properties of boron-containing steel sintered under different atmospheres”, J Met Mater Miner, ปี 29, ฉบับที่ 1, มี.ค. 2019.

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