Brazilein modified zinc oxide nanorods with enhanced visible light-responsive photocatalytic efficiency

Authors

  • Montri AIEMPANAKIT Department of Physics, Faculty of Science, Silpakorn University, Nakhon Pathom, 73000, Thailand
  • Penpicha SUDJAI Department of Chemistry, Faculty of Science, Silpakorn University, Nakhon Pathom, 73000, Thailand
  • Kittiyaporn SINGSUMPHAN Department of Physics, Faculty of Science, Silpakorn University, Nakhon Pathom, 73000, Thailand
  • Sakchai LAKSEE Nuclear Technology Research and Development Center, Thailand Institute of Nuclear Technology (Public Organization), Nakhon Nayok, 26120, Thailand
  • Cheewita SUWANCHAWALIT Nuclear Technology Research and Development Center, Thailand Institute of Nuclear Technology (Public Organization), Nakhon Nayok, 26120, Thailand

DOI:

https://doi.org/10.55713/jmmm.v32i2.1255

Keywords:

ZnO, Brazilein modified ZnO, Impregnation method, Visible light-responsive photocatalyst, Degradation of indigo carmine

Abstract

Photocatalytic efficiency of ZnO nanorods has been investigated with respect to the concentration of brazilein. Brazilein modified ZnO nanorods were prepared by an impregnation process with 1.0%w/v, 2.5%w/v, and 5.0%w/v of brazilein solution.  In order to correlate the variation in concentration distributions and photocatalytic performance, the phase composition, optical properties, and photo-catalytic activities of brazilein modified ZnO nanorods prepared with different brazilein concentrations have been investigated and compared to an unmodified ZnO nanorods. The photocatalytic properties were measured in terms of indigo carmine degradation under visible light irradiation. It was found that ZnO nanorods with the highest visible light-responsive photocatalytic efficiency were achieved by the modification of 5.0%w/v of brazilein resulting in indigo carmine degraded faster than the case of unmodified ZnO nanorod about 60% within 5 h.

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References

M. R. Hoffmann, S. T. Martin, W. Choi, and D. W. Bahnemann, “Environmenta applications of semiconductor photocatalysis,” Chemical Reviews, vol. 95, pp. 69-96, 1995. DOI: https://doi.org/10.1021/cr00033a004

J. M. Herrmann, “Heterogeneous photocatalysis: State of the art and present applications,” Topics in Catalysis, vol. 34, pp. 49-65, 2005. DOI: https://doi.org/10.1007/s11244-005-3788-2

S. Ye, Y. Chen, X. Yao, and J. Zhang, “Simultaneous removal of organic pollutants and heavy metals in wastewater by photo-electrocatalysis: A review,” Chemosphere, vol. 273, p. 128503, 2021. DOI: https://doi.org/10.1016/j.chemosphere.2020.128503

C. Hariharan, “Photocatalytic degradation of organic contaminants in water by ZnO nanoparticles revisited,” Applied Catalysis A General, vol. 304, pp. 55-61, 2006. DOI: https://doi.org/10.1016/j.apcata.2006.02.020

T. Pauporte, and J. Rathousky, “Electrodeposited mesoporous ZnO thin films as efficient photocatalysts for the degradation of dye pollutants,” Journal of Physical Chemistry C, vol. 111, pp. 7639-7644, 2007. DOI: https://doi.org/10.1021/jp071465f

D. Kong, Y. Zheng, M. Kobielusz, Y. Wang, Z. Bai, W. Macyk, X. Wang, and J. Tang, “Recent advances in visible light-driven water oxidation and reduction in suspension systems,” Materials Today, vol. 21, pp. 897-924, 2018. DOI: https://doi.org/10.1016/j.mattod.2018.04.009

H. Y. Shu, M. C. Chang, and T. H. Tseng, “Solar and visible light illumination on immobilized nano zinc oxide for the degradation and mineralization of orange G in wastewater,” Catalysts, vol. 7, p. 164, 2017. DOI: https://doi.org/10.3390/catal7050164

H. T. P. Nguyen, T. M. T. Nguyen, C. N. Hoang, T. K. Le, T. Lund, H. K. H. Nguyen, and T.K.X. Huynh, “Characterization and photocatalytic activity of new photocatalysts based on Ag, F-modified ZnO nanoparticles prepared by thermal shock method,” Arabian Journal of Chemistry, vol. 13, pp. 1837-1847, 2020. DOI: https://doi.org/10.1016/j.arabjc.2018.01.018

R. Ebrahimi, K. Hossienzadeh, A. Maleki, R. Ghanbari, R. Rezaee, M. Safari, B. Shahmoradi, H. Daraei, A. Jafari, K. Yetilmezsoy, and S. H. Puttaiah, “Effects of doping zinc oxide nanoparticles with transition metals (Ag, Cu, Mn) on photo-catalytic degradation of Direct Blue 15 dye under UV and visible light irradiation,” Journal of Environmental Health Science and Engineering, vol. 17, pp. 479-492, 2019. DOI: https://doi.org/10.1007/s40201-019-00366-x

E. Prabakaran, and K. Pillay, “Synthesis of N-doped ZnO nanoparticles with cabbage morphology as a catalyst for the efficient photocatalytic degradation of methylene blue under UV and visible light,” RSC Advances, vol. 9, pp. 7509-7535, 2019. DOI: https://doi.org/10.1039/C8RA09962F

S. Thaweesak, S. Wang, M. Lyu, M. Xiao, P. Peerakiatkhajohn, and L. Wang, “Boron-doped graphitic carbon nitride nanosheets for enhanced visible light photocatalytic water splitting,” Dalton Transactions, vol. 46, pp. 10714-10720, 2017. DOI: https://doi.org/10.1039/C7DT00933J

K. Xu, Z. Liu, S. Qi, Z. Yin, S. Deng, M. Zhang, and Z. Sun, “Construction of Ag-modified TiO2/ZnO heterojunction nanotree arrays with superior photocatalytic and photoelectrochemical properties,” RSC Advances, vol. 10, pp. 34702-34711, 2020. DOI: https://doi.org/10.1039/D0RA06596J

T. Munawar, F. Iqbal, S. Yasmeen, K. Mahmood, and A. Hussain, “Multi metal oxide NiO-CdO-ZnO nanocomposite–synthesis, structural, optical, electrical properties and enhanced sunlight driven photocatalytic activity,” Ceramics International, vol. 46, pp. 2421-2437, 2020. DOI: https://doi.org/10.1016/j.ceramint.2019.09.236

P. Peerakiatkhajohn, T. Butburee, J. -H. Yun, H. Chen, R. M. Richards, and L. Wang, “A hybrid photoelectrode with plasmonic Au@TiO2 nanoparticles for enhanced photoelectrochemical water splitting,” Journal of Materials Chemistry A, vol. 3, pp. 20127-20133, 2015. DOI: https://doi.org/10.1039/C5TA04137F

D. Chatterjee, and S. Dasgupta, “Visible light induced photo-catalytic degradation of organic pollutants,” Journal of Photo- chemistry and Photobiology C: Photochemistry Reviews, vol. 6, pp. 186-205, 2005. DOI: https://doi.org/10.1016/j.jphotochemrev.2005.09.001

G. C. C. Yang, and S. -W. Chan, “Photocatalytic reduction of chromium(VI) in aqueous solution using dye-sensitized nanoscale ZnO under visible light irradiation,” Journal of Nanoparticle Research, vol. 11, pp. 221-230, 2009. DOI: https://doi.org/10.1007/s11051-008-9423-y

A. Zyoud, M. Dwikat, S. Al-Shakhshir, S. Ateeq, J. Shteiwi, A. Zu’bi, M. H. S. Helal, G. Campet, D. Park, H. Kwon, T. W. Kim, M. Kharoof, R. Shawahna, and H. S. Hilal. “Natural dye-sensitized ZnO nano-particles as photo-catalysts in complete degradation of E. coli bacteria and their organic content,” Journal of Photochemistry and Photobiology A: Chemistry, vol. 328, pp. 207-216, 2016. DOI: https://doi.org/10.1016/j.jphotochem.2016.05.020

D. Chatterjee, S. Dasgupta, and N. N. Rao, “Visible light assisted photodegradation of halocarbons on the dye modified TiO2 surface using visible light,” Solar Energy Materials and Solar Cells, vol. 90, pp. 1013-1020, 2006.

M. Aiempanakit, T. Tabtimsri, N. Triamnak, and C. Suwanchawalit, “Curcumin modified titanium dioxide nanotubes with enhanced visible light photocatalytic performance,” International Journal of Electrochemical Science, vol. 14, pp. 1954-1967, 2019. DOI: https://doi.org/10.20964/2019.02.28

M. Aiempanakit, J. Sangkaworn, N. Worawannotai, K. Laohhasurayotin, W. Sangchay, S. Lakseee, and C. Suwanchawalit, “Enhancement of Visible Light-Responsive Photocatalytic Efficiency by Using a Laccaic Acid-Modified Titanium Dioxide Photocatalyst,” Journal of the Brazilian Chemical Society, vol. 00, pp. 1-9, 2022. DOI: https://doi.org/10.21577/0103-5053.20220006

R. Rahimi, J. Shokraiyan, M. Rabbani, and F. Fayyaz, “Enhanced photobactericidal activity of ZnO nanorods modified by meso-tetrakis(4-sulfonatophenyl)porphyrin under visible LED lamp irradiation,” Water Science and Technology, vol. 71, pp. 1249-1254, 2015. DOI: https://doi.org/10.2166/wst.2015.098

S. Radhika, and J. Thomas, “Solar light driven photocatalytic degradation of organic pollutants using ZnO nanorods coupled with photosensitive molecules,” Journal of Environmental Chemical Engineering, vol. 5, pp. 4239-4250, 2017. DOI: https://doi.org/10.1016/j.jece.2017.08.013

X. Li, Y. Cheng, S. Kang, and J. Mu, “Preparation and enhanced visible light-driven catalytic activity of ZnO microrods sensitized by porphyrin heteroaggregate,” Applied Surface Science, vol. 256, pp. 6705-6709, 2010. DOI: https://doi.org/10.1016/j.apsusc.2010.04.074

A. Haghighatzadeh, “Visible-light-active chlorophyll/flavonoid- sensitized ZnO nanoparticles: preparation and optical and photocatalytic studies,” Journal of the Australian Ceramic Society, vol. 57, pp. 137-147, 2021. DOI: https://doi.org/10.1007/s41779-020-00520-x

S. Landuma, D. A. Haryanto, and A. Purwanto, “Application of sappan wood (Caesalpinia Sappan Linn) as sensitizer for dye-sensitized solar cell (DSSC),” AIP Conference Proceedings, vol. 1586, pp. 109-112, 2014. DOI: https://doi.org/10.1063/1.4866741

P. Ohama, and N. Tumpat, “Textile dyeing with natural dye from sappan tree (Caesalpinia sappan Linn.) extract,” International Journal of Fashion and Textile Engineering, vol. 8, pp. 432-434, 2014.

T. E. Purbaningtias, I. D. Lestari, B. Wiyantoko, P. Kurniawati, and D. Sriadryani, “Utilization of natural indicators for borax identification in the Indonesian tofu,” AIP Conference Proceedings, vol. 1823, p. 020057, 2017. DOI: https://doi.org/10.1063/1.4978130

A. Petdum, T. Sooksimuang, N. Wanichacheva, and J. Sirirak, “Natural colorimetric sensor from sappanwood for turn-on selective Fe2+ detection in aqueous media and its application in water and pharmaceutical samples,” Chemistry Letters, vol. 48, pp. 678-681, 2019. DOI: https://doi.org/10.1246/cl.190158

N. P. Nirmal, M. S. Rajput, R. G. S. V. Prasad, and M. Ahmad, “Brazilin from Caesalpinia sappan heartwood and its pharma-cological activities: A review,” Asian Pacific Journal of Tropical Medicine, vol. 8, pp. 421-430, 2015. DOI: https://doi.org/10.1016/j.apjtm.2015.05.014

K. Mekala and R. Radha, “A review on sappan wood – A therapeutic dye yielding tree,” Research Journal of Pharma-cognosy and Phytochemistry, vol. 7, p. 227, 2015. DOI: https://doi.org/10.5958/0975-4385.2015.00035.7

C. Suwanchawalit, S. Wongnawa, P. Sriprang, and P. Meanha, “Enhancement of the photocatalytic performance of Ag-modified TiO2 photocatalyst under visible light” Ceramics International, vol. 38, pp. 5201-5207, 2012. DOI: https://doi.org/10.1016/j.ceramint.2012.03.027

O. Mehraj, N. A. Mir, B. M. Pirzada, S. Sabir, and M. Muneer, “In-situ anion exchange synthesis of AgBr/Ag2CO3 hybrids with enhanced visible light photocatalytic activity and improved stability,” Journal of Molecular Catalysis A: Chemical, vol. 395, pp. 16-24, 2014. DOI: https://doi.org/10.1016/j.molcata.2014.07.027

H. Slimani, N. Bessous, S. Dagher, A. Hilal-Alnaqbi, M. El Gamal, B. Akhozheya, and M. Mohammed, “Growth of ZnO nanorods on FTO glass substrate,” Materials Research Express, vol. 7, p. 025026, 2020. DOI: https://doi.org/10.1088/2053-1591/ab727b

L. Ngamwonglumlert, S. Devahastin, N. Chiewchan, and G. S. Vijaya Raghavan “Color and molecular structure alterations of brazilein extracted from Caesalpinia sappan L. under different pH and heating conditions,” Scientific Reports, vol. 10, p. 12386, 2020. DOI: https://doi.org/10.1038/s41598-020-69189-3

J. Sirirak, N. Worawannotai, C. Suwanchawalit, and S. Chayabutra, “Preparation and characterization of lake pigments from sappan wood using Thai local clays,” Journal of Metals, Materials and Minerals, vol. 30, no. 1, pp. 20-28, 2020.

J. Sirirak, P. Suppharatthanya, K. Chantha, S. Girdthep, and S. Chayabutra, “Eco-friendly lake pigment from sappanwood: Adsorption study and its application as natural colorant for natural rubber toy balloon,” Journal of Metals, Materials and Minerals, vol. 31, no. 2, pp. 27-37, 2021.

G. Jiang, K. Geng, Y. Wu, Y. Han, and X. Shen, “High photocatalytic performance of ruthenium complexes sensitizing g-C3N4/TiO2 hybrid in visible light irradiation,” Applied Catalysis B, vol. 227, pp. 366-275. 2018. DOI: https://doi.org/10.1016/j.apcatb.2018.01.034

K. Parul, R. Kaur, P. Badru, P. Singh, and S. Kaushal, “Photodegradation of organic pollutants using heterojunctions: A review,” Journal of Environmental Chemical Engineering, vol. 8, p. 103666, 2020. DOI: https://doi.org/10.1016/j.jece.2020.103666

D. Chatterjee, S. Dasgupta, and N. N. Rao, “Visible light assisted photodegradation of halocarbons on the dye modified TiO2 surface using visible light,” Solar Energy Materials and Solar Cells, vol. 90, pp. 1013-1020, 2006. DOI: https://doi.org/10.1016/j.solmat.2005.05.016

X. Zhang, Y. Wang, F. Hou, H. Li, Y. Yang, X. Zhang, Y. Yang, and Y. Wang, “Effects of Ag loading on structural and photocatalytic properties of flower-likeZnO microspheres,” Applied Surface Science, vol. 391, pp. 476-483, 2017. DOI: https://doi.org/10.1016/j.apsusc.2016.06.109

T. Ganesh, J. H. Kim, S. J. Yoon, B. H. Kil, N. N. Maldar, J. W. Han, and S. H. Han, “Photoactive curcumin-derived dyes with surface anchoring moieties used in ZnO nanoparticle-based dye-sensitized solar cells,” Materials Chemistry and Physics, vol. 123, pp. 62-66, 2010. DOI: https://doi.org/10.1016/j.matchemphys.2010.03.062

S. Buddee, S. Wongnawa, P. Sriprang, and C. Sriwong, “Curcumin-sensitized TiO2 for enhanced photodegrasation of dyes under visible light,” Journal of Nanoparticle Research. vol. 16, p. 2336, 2014. DOI: https://doi.org/10.1007/s11051-014-2336-z

M. A. Dil, A. Haghighatzadeh, and B. Mazinani, “Photosensitization effect on visible-light-induced photocatalytic performance of TiO2/ chlorophyll and flavoniod nanostructures: kinetic and isotherm studies,” Bulletin of Materials Science, vol. 42, p. 248, 2019. DOI: https://doi.org/10.1007/s12034-019-1927-9

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Published

2022-06-30

How to Cite

[1]
M. AIEMPANAKIT, P. SUDJAI, K. SINGSUMPHAN, S. LAKSEE, and C. SUWANCHAWALIT, “Brazilein modified zinc oxide nanorods with enhanced visible light-responsive photocatalytic efficiency”, J Met Mater Miner, vol. 32, no. 2, pp. 70–76, Jun. 2022.

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Original Research Articles