Research progress of novel zirconium alloys with high strength and toughness

Authors

  • Na ZHANG Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China
  • Chaoqun XIA Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China; State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China
  • Jiaqian QIN Metallurgy and Materials Science Research Institute, Chulalongkorn University, Bangkok 10330, Thailand
  • Qiang LI Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China
  • Xinyu ZHANG State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China
  • Riping LIU State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China

DOI:

https://doi.org/10.55713/jmmm.v32i4.1526

Keywords:

Zirconium alloy, High strength and toughness, Corrosion resistance, Mechanical properties

Abstract

Atoms of zirconium (Zr) are often known as "first metals of the atomic age". Because of its low cross section for thermal neutron absorption, excellent corrosion resistance, and good mechanical and processing properties, it is extensively used in the nuclear industry. As the properties requirements of materials in chemical, medical and aerospace fields turn out to be higher, the application of Zr alloys in these non-nuclear fields has become more and more widespread due to their excellent properties. In addition to having a high melting point, Zr alloys also have a high specific strength and low thermal expansion coefficient. Therefore, Zr alloys have a very promising application in corrosion-resistant structural materials. This paper mainly introduces the development status of Zr alloys, the design and optimization of Zr alloy compositions, the mechanism of Zr alloy toughening and the prospects of Zr alloy applications in various fields.

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References

C. Liu, B. Qu, and Z. Ma, "Recrystallization,precipitation, and resultant mechanical properties of rolled Al–Zn alloy after aging," Materials Science and Engineering, Part A, vol. 657, pp. 284-290, 2016.

X. Wang, A. Inoue, and F. Kong, "Influence of ejection temperature on structure and glass transition behavior for Zr-based rapidly quenched disordered alloys," Acta Materialia, vol. 116, pp. 370-381, 2016.

W. Xu, M. Brandt, and S. Sun, "Additive manufacturing of strong and ductile Ti–6Al–4V by selective laser melting via in situ martensite decomposition," Acta Materialia, vol. 85, pp. 74-84, 2015.

D. Zander, and U. Köster, "Corrosion of amorphous and nano-crystalline Zr-based alloys," Materials Science and Engineering, Part A, vol. 375, pp. 53-59, 2004.

Z. Feng, X. Jiang, and Y. Zhou, "Influence of beryllium addition on the microstructural evolution and mechanical properties of Zr alloys," Materials & Design (1980-2015), vol. 65, pp. 890-895, 2015.

C. Xia, X. Jiang, and X. Wang, "Microstructure and mechanical properties of hot-rolled ZrB alloys," Materials Science and Engineering, Part A, vol. 628, pp. 168-175, 2015.

R. Kondo, N. Nomura, and Y. Tsutsumi, "Microstructure and mechanical properties of as-cast Zr–Nb alloys," Acta Bio-materialia, vol. 7, no. 12, pp. 4278-4284, 2011.

H. G. Rickover, L. D. Geiger, and B. Lustman, "History of development of zirconium alloys for use in nuclear power reactors," United States Energy Research and Development Administration NR, Part D, 1975.

Q. Fan, "Research on the microstructure of Zr-Sn-Nb-Fe alloy," Chengdu University of Technology, 2015.

W. Liu, M. Lei, and X, Geng, "Effect of heat treatment on microstructure and corrosion resistance for Zr-Sn-Nb zirconium alloy," Atomic Energy Science & Technology, vol. 41, no. 6, pp. 5, 2007.

R. Krishnan, and M. K. Asundi, "Zirconium alloys in nuclear technology," Proceedings of the Indian Academy of Sciences Section C: Engineering Sciences, vol. 4, no. 1, pp. 41-56, 1981.

W. Zhao, B. Zhou, and Z. Miao, "Development of Chinese advanced zirconium alloys," Atomic Energy Science and Technology, vol. 39, no. S1, pp-4-9, 2005.

G. Yuan, H. Li, and D. Wang, "Application of zirconium material for nuclear power station," Rare Metals Letters, vol. 26, no. 1, pp. 14-16, 2007.

C. Wang X, L. Zhongkui, and J. Zhou, "Application and research progress of zirconium alloy in nuclear industry," Hot Working Technology, vol. 41, no. 2, pp. 71-74, 2012.

H. Zhang, Z. Li, and B. Xu, "The effect of α-Zr matrix micro-structure on the formation of oxide film and the corrosion resistance of new zirconium alloys," Gongneng Cailiao/ Journal of Functional Materials, vol. 45, no. 8, pp. 8062-8066, 2014.

M. Shi, Z. Li, and J. Zhang, "Effects of hot rolling temperature on secondary phase particles of NZ2 zirconium alloy," Rare Metal Materials and Engineering, vol. 39, no. 8, pp. 1496-1498, 2010.

M. Shi, Z. Li, and F. Tian, "Iodine-induced Stress corrision of NZ2 zirconium alloys," Rare Metal Materiass and Engineering, vol. 42, no. 8, pp. 1722-1725, 2013.

M. Shi, Z. Li, and J. Zhang, "Effects of hot rolling on hydrogen absorption behavior of NZ2 zirconium alloy in 400℃ super-heated steam," Rare Metal Materials and Engineering, vol. 40, no. 10, pp. 1855-1858, 2011.

Z. Yao, "Application of zirconium and its alloy in chemical equipment," Chemical Engineering Design, vol. 13, no. 4, pp. 19-22, 2003.

W. Hua, H. Fan, and S. Ying, "Effect of surface treatment on the properties of zirconium alloys," Heat Treatment of Metals, vol. 31, no. 1, pp. 17-19, 2006.

J. Hao, P. Gou, and Y. Hao, "Study on structure and corrosion resistance of micro-arc Oxidation ceramic coating on zirconium alloy," Hot Working Technology, vol. 42, no. 14, pp. 3, 2013.

D. Wei, W. Yawen, and H. Xiujie, "High-temperature oxidation and tensile behaviors of CrAl coating on zirconium alloy," China Surface Engineering, vol. 7, pp. 1-10, 2019.

C. Luo, "Research on preparation,microstructure and mechanical properties of new biomedical zirconium alloy," Southeast University, 2020.

X. Jia, "Study on The micro-arc oxidation of ultrafine-grained titanium and its biological security," The Fourth Military Medical University, 2015.

M. Long, and H. J. Rack, "Titanium alloys in total joint replacement-a materials science perspective," Biomaterials, vol. 19, no. 18, pp. 1621-1639, 1998.

K. Wang, "The use of titanium for medical applications in the USA," Materials Science and Engineering, Part A, vol. 213, no. 1-2, pp. 134-137, 1996.

M. A. Khan, R. L. Williams, and D. F. Williams, "Conjoint corrosion and wear in titanium alloys," Biomaterials, vol. 20, no. 8, pp. 765-772, 1999.

Z. Yu, C. Xiong, and P. Xue, "Shape memory behavior of Ti-20Zr-10Nb-5Al alloy subjected to annealing treatment," Rare Metals, vol. 35, no. 11, pp. 5, 2016.

E. Kobayashi, H. Doi, and T. Yoneyama, "Evaluation of mechanical properties of dental casting TiZr based alloys," Journal of the Japanese Society for Dental Material&Devices, vol. 14, no. 3, pp. 321-327, 1995.

Y. Zhang, T. Guo, and Z. Li, "New high strength titanium alloy Ti Zr for dental use," West China Journal of Stomatology, vol. 17, no. 4, pp. 329-330.

Suyalatu, N. Nomura, and K. Oya, "Microstructure and magnetic susceptibility of as-cast Zr–Mo alloys," vol. 6, no. 3, pp. 1033-1038, 2010.

M. Niimomi, M. Nakai, and J. Hieda, "Development of new metallic alloys for biomedical applications," Acta Biomaterialia, vol. 8, no. 11, pp. 3888-3903, 2012.

L. Nie, Y. Zhan, and H. Liu, "Novel β-type Zr–Mo–Ti alloys for biological hard tissue replacements," Materials & Design, vol. 53, pp. 8-12, 2014.

R. Jing, "Preparation, structure and properties of high strength TiZr-based alloy," Yanshan University, 2013.

P. Ji, B. Chen, and B. Li, "Influence of Nb addition on micro-structural evolution and compression mechanical properties of Ti-Zr alloys," Journal of Materials Science & Technology, vol. 69, pp. 7-14, 2021.

Y. Ding, S. Liu, and C. Xia, "Thermal oxidation of novel Zr-Ti-Al-V alloy with high strength and toughness and its influence on the corrosion behavior," Surface and Coatings Technology, vol. 423, no. 10 , 2021.

X. Jiang, R. Jing, and C. Liu, "Structure and mechanical properties of TiZr binary alloy after Al addition," Materials Science and Engineering, Part A, vol. 586, pp. 301-305, 2013.

Y. Zhou, S. Liang, and R. Jing, "Microstructure and tensile properties of hot-rolled Zr50-Ti50 binary alloy," Materials Science and Engineering, Part A, vol. 621, pp. 259-264, 2015.

Z. Zhang, Z. Feng, and X. Jiang, "Microstructure and tensile properties of novel Zr–Cr binary alloys processed by hot rolling," Materials Science & Engineering, Part A, vol. 652, pp.77-83, 2016.

H. J. Fecht, G. Han, and Z. Fu, "Metastable phase formation in the Zr–Al binary system induced by mechanical alloying," Journal of Applied Physics, vol. 67, no. 4, pp.1744-1748, 1990.

C. Xia, Z. Feng, and Tanc, "Effect of annealing on microstructure and tensile property of a novel ZrB alloy," Materials Science and Engineering, Part A, vol. 674, pp. 1-8, 2016.

Z. Feng, C. Xia, and R. Jing, "Microstructure and mechanical properties of ZrBe alloys processed by hot rolling," Materials Science and Engineering, Part A, vol. 667, pp. 286-292, 2016.

S. Wang, "Study on mechanical properties and corrosion resistance of ZrTa alloy," Yanshan University, 2020.

X. Jiang, "Preparation, structure and properties of high strength TiZrAl alloys," Yanshan University, 2015.

Y. Yang, "The corrosion behavior of TiZrAlV alloys," Yanshan University, 2015.

A. Peker, and W. L. Johnson, "A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5," Applied Physics Letters, vol. 63, pp. 17, 1993.

N. Shirasawa, Y. Takigawa , and T. Uesugi, "The evaluation parameters for glass-forming ability in Ti–Cu system metallic glasses," Materials Letters, vol. 139, pp. 73-76, 2014.

X. Zhang, Z. Yuan, and D. Li, "Microstructural evolution and homogeneous viscous flow behavior of a Cu–Zr based bulk metallicglass composites," Journal of Alloys and Compounds, vol. 617, pp. 670-676, 2015.

K. Ming, Z. Zhu, and W. Zhu, "Enhancing strength and ductility via crystalline-amorphous nanoarchitectures in TiZr-based alloys," Science advances, vol. 8, no. 10, eabm2884, 2022.

N. P. Kovalenko, and Y. P. Krasny, "Physics of amorphous metals," Berlin: WILEY-VCHVer lag, pp. 1-7, 2001.

F. Szuecs, C. P. Kim, and W. L. Johnson, "Mechanical properties of Zr56.2Ti13.8Nb5.0Cu6.9Ni5.6Be12.5 ductile phase reinforced bulk metallic glass composite," Acta Mater, vol. 49, pp. 1507-1513, 2001.

R. Tewari, D. Srivastava, and G. Dey, "Microstructural evolution in zirconium based alloys," Journal of Nuclear Materials, vol. 383, pp. 153-171, 2008.

Z. Feng, C. Xia, and X. Zhang, "Development and applications of zirconium alloys with high strength and toughness," Materials Science and Technology, vol. 26, no. 2, pp. 1-8, 2018.

R. Jing, Y. Wang, and Y. Xi, "Research progress on new high strength and high toughness Ti–Zr alloys," Foundry Technology, vol. 39, no. 10, pp. 5, 2018.

S. Liang, L. Yin, and X. Liu, "Microstructure evolution and mechanical properties response of α-TZAV alloy during combined thermomechanical treatments," Materials Science and Engineering, Part A, vol. 619, pp. 87-94, 2014.

S. Liang, L. Yin, and R. Jiang, "Strengthening mechanism of two-phase titanium alloys with basketweave microstructure," Journal of Alloys and Compounds, vol. 603, pp. 42-47, 2014.

B. Chen, S. Liu, and X. Zhang, "Effect of Al change on micro-structure and mechanical properties of hot-rolled ZrSnAl alloy," Materials Letters, vol. 267, 2020.

S. Liang, L. Yin, and X. Liu, "Effects of annealing treatments on microstructure and mechanical properties of the Zr345Ti35Al33V alloy," Materials Science and Engineering, Part A, vol. 582, pp. 374-378, 2013.

X. Jiang, X. Wang, and Z. Feng, "Effect of rolling temperature on microstructure and mechanical properties of a TiZrAl alloy," Materials Science and Engineering, Part A, vol. 635, pp. 36-42, 2015.

R. Jing, S. Liang, and C. Liu, "Effect of the annealing temperature on the microstructural evolution and mechanical properties of TiZrAlV alloy," Materials & Design, vol. 52, pp. 981-986, 2013.

Z. Sun, S. Guo, and H. Yang, "Nucleation and growth mechanism of α-lamellae of Ti alloy TA15 cooling from an α+β phase field," Acta Materialia, vol. 61, pp. 2057-2064, 2013.

W. Ho, W. Chen, and S. Wu, "Structure, mechanical properties, and grindability of dental Ti–Zr alloys," Journal of Materials Science Materials in Medicine, vol. 19, no. 10, pp. 3179-3186, 2008.

Z. Jin, Y. Yang, and Z. Zhang, "Effect of Hf substitution Cu on glass-forming ability, mechanical properties and corrosion resistance of Ni-free Zr–Ti–Cu–Al bulk metallic glasses," Journal of Alloys and Compounds, vol. 806, no. 4, pp. 668-675, 2019.

J. Luo, J. Wang, and E. Bitzek, "Size-dependent brittle-to-ductile transition in silica glass nanofibers," Nano Lett, vol. 16, pp. 105-113, 2016.

K. Zheng, C. Wang, and Y. Cheng, "Electron-beam-assisted superplastic shaping of nanoscale amorphous silica," Nat. Commun, vol. 1, pp. 1-8, 2010.

E. J. Frankberg, J. Kalikka, and F. G. Ferré, "Highly ductile amorphous oxide at room temperature and high strain rate," Science, vol. 366, pp. 864-869, 2019.

G. Wu, K. Chan, and L. Zhu, "Dual-phase nanostructuring as a route to high-strength magnesium alloys," Nature vol. 545, pp. 80-83, 2017.

G. Wu, S. Balachandran, and B. Gault, "Crystal-glass high-entropy nanocomposites with near theoretical compressive strength and large deformability," Advanced Materials, vol. 32, no. 34, p. 2002619, 2020.

J. Zhang, Y. Liu, H. Yang, and Bakhtiari, "Achieving 5.9% elastic strain in kilograms of metallic glasses: Nanoscopic strain engineering goes macro," Materials Today, vol. 37, pp. 18-26, 2020.

E. Ma, and J. Ding, "Tailoring structural inhomogeneities in metallic glasses to enable tensile ductility at room temperature," Materials Today, vol. 19, pp. 568-579, 2016.

G. Wu, C. Liu, and L. Sun, "Hierarchical nanostructured aluminum alloy with ultrahigh strength and large plasticity," Nat. Commun, vol. 10, pp. 1-8, 2019.

D. Zou, B. Luan, and D. Xiao, "Influences of strain rate on the plastic deformation mechanism of zirconium alloy," Rare Metal Materials & Engineering, vol. 43, no. 8, pp.1897-1902, 2014.

B. Luan, H. Yu, and T. Huang, "A review of deformation mechanism of zirconium alloys," Rare Metal Materials & Engineering, vol. 41, pp. 357-360, 2012.

W. Cai, "Tensile and compressive deformation behavior of CP-Zr processed by ECAP at room temperature," Xi'an University of architecture and technology, 2017.

https://kns.cnki.net/kcms/detail/detail.aspx?dbcode=CMFD&dbname=CMFD201801&filename=1017736841.nh&uniplatform=NZKPT&v=FZTv7Ght6QGKNAI19lJva9ArWzzTcm0mdRLcaWqfpYmvnC3vbzq8AYlYArgLna5

C. Yang, "Compression deformation behavior of ultrafine grained pure zirconium processed by ECAP and rotary swaging at room temperature," Xi'an University of architecture and technology, 2018.

https://kns.cnki.net/kcms/detail/detail.aspx?dbcode=CMFD&dbname=CMFD201802&filename=1018862649.nh&uniplatform=NZKPT&v=j4Fmvyzco36f6VPMibt28FzsPY9d_3XJz6CS7ADWzANoLJAWY4B0lqtctXxlbbGI

P. Geng, X. Gong, and J. Ma, "Research on processing technology and application of zirconium alloy material," Forging equipment and manufacturing technology, 2021.

H. Nagano, H. Kajimura, and K. Yamanaka, "Corrosion resistance of zirconium and zirconium-titanium alloy in hot nitric acid," Materials Science and Engineering, Part A, vol. 198, no. 1-2, pp. 127-134, 1995.

Z. Du, L. Zou, and C. Guo, "Phase stability of Fe23Zr6 and thermodynamic reassessment of Fe-Zr system," Journal of Iron and Steel Research International, vol. 28, no. 11, pp. 1-15, 2021.

S. Liang, M. Ma, and R. Jing, "Preparation of the ZrTiAlV alloy with ultra-high strength and good ductility," Materials Science and Engineering, Part A, vol. 539, pp. 42-47, 2012.

M. Shi, C. Liu, and J. Zhou, "Application of zirconium and its alloys in industry," Hot Working Technology, vol. 44, no. 18, pp. 28-30, 2015.

Y. E. Wenjun, and M. I. Xujun, "Martensitic transformation of Ti-18Nb(at.%) alloy with zirconium," Rare Metals, 2012.

Y. Ren, J. Li, and Q. Wang, "A Review: Research on MR-compatible alloys in MRI," Acta Metallurgica Sinica -Chinese Edition-, vol. 53, no. 10, pp. 1323-1330, 2017.

M. Slobodyan, "Resistance, electron- and laser-beam welding of zirconium alloys for nuclear applications: A review," Nuclear Engineering and Technology, vol. 53, no. 4, pp. 1049-1078, 2021.

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Published

2022-12-26

How to Cite

[1]
N. ZHANG, C. XIA, J. QIN, Q. LI, X. ZHANG, and R. LIU, “Research progress of novel zirconium alloys with high strength and toughness ”, J Met Mater Miner, vol. 32, no. 4, pp. 23–36, Dec. 2022.

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Review Articles