Influence of water content on structural and electrochromic properties of TiO\(_{2}\) nanotube prepared by anodization

Chantana AIEMPANAKIT; Pathomporn JUNBANG; Watchara  SUPHAP; Kamon AIEMPANAKIT

doi:10.55713/jmmm.v33i3.1680

ผู้แต่ง

Chantana AIEMPANAKIT Division of Physics, Faculty of Science and Technology, Rajamangala University of Technology Thanyaburi, Pathumthani, 12110, Thailand
Pathomporn JUNBANG Department of Physics, Faculty of Medicine, Bangkokthonburi University, Thawi Watthana, Bangkok, 10170, Thailand
Watchara SUPHAP Department of Physics, Faculty of Science and Technology, Thammasat University, Pathumthani, 12121, Thailand
Kamon AIEMPANAKIT Department of Physics, Faculty of Science and Technology, Thammasat University

DOI:

https://doi.org/10.55713/jmmm.v33i3.1680

คำสำคัญ:

TNTs, anodization, Annealing, energy gap, electrochromic

บทคัดย่อ

TiO₂ nanotubes (TNTs) and bamboo-type TNTs structure films were synthesized via anodization from sputtered titanium (Ti) films on indium tin oxide (ITO) glass. Herein, the anodization process was adjusted electrolyte with different amounts of deionized water and ethylene glycol. The optical and structural properties of all films before and after annealing were investigated, which affected electrochromic application. The increasing deionized water content in electrolytes resulted in an increase in the average diameter and a decrease in the average length of TNTs. Furthermore, the bamboo-type TNTs structure was produced at the deionized water volume condition of 3 vol%. The crystallite size of annealed TNTs (a-TNTs) was calculated from the Scherrer equation, which was enhanced when increasing deionized water. TNTs conditions before annealing showed that the amorphous structure and high energy band gap (Eg) exhibited more electrochromic phenomena than the crystal structure. Due to the disordered arrangement of structures, it was easy to insert ions in TNTs. The bamboo-like structure with separate tubes increased the surface area of the reaction, thus exhibiting the best electrochromic properties with ΔT equal to 12.58%.

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เอกสารอ้างอิง

Z. Zhang, H. Liu, L. Zhai, J. Wu and L., Li, "Construction of BiOCl-TNTs photoelectrochemical sensor for detection of hydrogen peroxide," Chemical Physics Letters, vol. 811, pp. 140177, 2023.

J. Sivapatarnkun, and K. S. Pudwat, "Effects of active area on UV detection by TiO2-sputtered films, " Materials Today: Proceedings, vol. 47, pp. 3487-3491, 2021.

S. Niu, W. Yang, H. Wei, M. Danilov, I. Rusetskyi, K.C. Popat, Y. Wang, M. J. Kipper, L. A. Belfiore, and J. Tang, "Hetero-structures of cut carbon nanotube-filled array of TiO2 nanotubes for new module of photovoltaic devices," Nanomaterials, vol. 12, pp. 3604, 2022.

X. Qiu, Z. Wan, M. Pu, X. Xu, Y. Ye, and C. Hu, "Synthesis and photocatalytic activity of Pt-deposited TiO2 nanotubes (TNT) for Rhodamine B degradation," Frontiers in Chemistry, vol.10, p. 922701, 2022.

C. Salawan, A. Muakngam, B. Sukbot, K. Aiempanakit, and S. Dumrongrattana, "Effect of DC power on structural and hydrophilic activity of TiO2 films," Advanced Materials Research, vol. 55-57, pp. 925-928, 2008.

J. Xiong, A. Fei, L. Yu, L. Xia, C. Xu, S. Chen, G. Jiang, and S. Yuan, "Crystal phase-dependent electrochromic performance of porous titanium dioxide nanotube films," International Journal of Electrochemical Science, vol. 16, pp.1-12, 2021.

D. D. Yao, M. R. Field, A. P. O'Mullane, K. K.-zadeh, and J. Z. Ou, "Electrochromic properties of TiO2 nanotubes coated with electrodeposited MoO3," Nanoscale, vol. 5, pp. 10353-10359, 2013.

C. Aiempanakit, and K. Aiempanakit, "Structural development and phase transformation behavior of thermally-oxidization Ti by sputtering power and OAD technique," Materials Chemistry and Physics, vol. 280, p. 125814, 2022.

J. Song, R. Guan, M, Xie, P, Dong, X. Yang, and J. Zhang, “Advances in electrospun TiO2 nanofibers: Design, construction, and applications,”Chemical Engineering Journal, vol. 431,

p. 134343, 2022.

C. Eyovge, C. S. Deenen, F. R.-Zepeda, S. Bartling, Y. Smirnov, M. M.-Masis, A. S.-Arce, and H. Gardeniers, "Color tuning of electrochromic tio2 nanofibrous layers loaded with metal and metal oxide nanoparticles for smart colored windows, " ACS Applied Nano Materials, vol.4, no. 8, pp. 8600-8610, 2021.

B. Dai, C. Wu, and Y. Xie, "Boosting the electrochromic performance of TiO2 nanowire film via successively evolving surface structure, " Science China Chemistry, vol. 64, no. 5, pp. 745-752, 2021.

P. Junbang, C. Aiempanakit, and K. Aiempanakit, "Effects of sputtering power of Ti films on morphology of TiO2 nano-tubes synthesized via anodization process," Journal of Metals, Materials and Minerals, vol. 32, no. 2, pp. 24-33, 2022.

D. Regonini, A. Jaroenworaluck, R. Stevens, and C. R. Bowen, "Effect of heat treatment on the properties and structure of TiO2 nanotubes: phase composition and chemical composition, " Surface and Interface Analysis, vol. 42, no. 3, pp.139-144, 2010.

A. Z. Sadek, H. Zheng, K. Latham,W. Wlodarski, and K. K.-zadeh, "Anodization of Ti thin film deposited on ITO," Langmuir, vol. 25, pp. 509-514, 2009.

M. Szkoda, A. Lisowska, K. Grochowska, L. Skowronski, J. Karczewski, and K. Siuzdak, "Semi – transparent ordered TiO2 nanostructures prepared by anodization of titanium thin films deposited onto the FTO substrate," Applied Surface Science, vol. 381, pp. 36-41, 2016.

V. S. Simi, and N. Rajendran, "Influence of tunable diameter on the electrochemical behavior and antibacterial activity of titania nanotubes arrays for biomedical applications," Materials Characterization, vol. 129, pp. 67-79, 2017.

P. Yang, Y. Liu, S. Chen, J. Ma, J. Gong, T. Zhang, and X. Zhu, "Influence of H2O2 and H2O content on anodizing current and morphology evolution of anodic TiO2 nanotubes," Materials Research Bulletin, vol. 83, pp. 581-589, 2016.

S. P. Albu, D. Kim, and P. Schmuki, "Growth of aligned TiO2 bamboo-type nanotubes and highly ordered nanolace," Angewandte

Chemie International Edition, vol, 47, pp. 1916 -1919, 2008.

V. Sivaprakash, and R. Narayana, "Synthesis of TiO2 nanotubes via electrochemical anodization with different water content, "Materials today: proceeding , vol. 37, no. 2, pp. 142-146, 2021.

D. Kim, A. Ghicov, S. P. Albu, and P. Schmuki, "Bamboo-type TiO2 nanotubes: Improved conversion efficiency in dye-sensitized solar cells," Journal of the American Chemical Society, vol. 130, no. 49, pp. 16454-16455, 2008.

K. Siuzdak, M. Szkoda, M.Sawczak, J. Karczewski, J. Ryl, and A.Cenian, "Ordered titania nanotubes layer selectively annealed by laser beam for high contrast electrochromic switching," Thin Solid Films, vol. 659, pp. 48-56, 2018.

A. Ghicov, H. Tsuchiya, R. Hahn, J. M. Macak,A. G.Muñoz, and P. Schmuki, "TiO2 nanotubes: H+insertion and strong electrochromic effects," Electrochemistry Communications, vol. 8, no. 4, pp. 528-532, 2006.

M. Molaei, A. F.-alhosseini, M. Nouri, P. Mahmoodi, and A. Nourian, “Incorporating TiO2 nanoparticles to enhance corrosion resistance, cytocompatibility, and antibacterial properties of PEO ceramic coatings on titanium, " Ceramics International, vol. 48, no. 14, pp. 21005-21024, 2022.

C. Salawan, M. Aiempanakit, K. Aiempanakit, C. Chananonnawathorn, P. Eiamchai, and M. Horprathum, "Effects of oblique angle deposition on optical and morphological properties of WO3 nanorod films for electrochromic application," Materials Today: Proceedings, vol. 4, pp. 6423-6429, 2017.

B. W.-C. Au, A. Tamang, D. Knipp, and K.-Y. Chan, "Post-annealing effect on the electrochromic properties of WO3 films," Optical Materials, vol. 108, p. 110426, 2020.

C. Aiempanakit, R. Momkhunthod and K. Aiempanakit, "Electro-chromism in nanoporous tungsten trioxide films prepared through anodization and thermal oxidation,"Integrated Ferroelectrics, vol. 222, pp. 84-92, 2022.

C. Aiempanakit, A. Chanachai, N. Kanchai, M. Aiempanakit and K. Aiempanakit, "Electrochromic property of tungsten trioxide films prepared by DC magnetron sputtering with oblique angle deposition and thermal oxidation," Journal of Metals, Materials and Minerals, vol. 31, no. 2, pp. 123-128, 2021.

W. Thongjoon, I.Chuasontia, K. Aiempanakit, and C. Aiempanakit, "Morphology and electrochromic property of chemical bath deposited NiO films at different NiSO4 concentration," Journal of Metals, Materials and Minerals, vol. 32, no. 4, pp. 87-92, 2022.

S. Q. Jin, S. S. Wen, M. Y. Li, H. Zhong, Y. W. Chen, and H.G Wang, "Effect of the grain size on the electrochromic properties of NiO films," Optical Materials, vol. 109, pp. 110280-110288, 2020.

J. R. Abenuz Acuña, I. Perez, V. Sosa, F. Gamboa, J. T. Elizalde, R. Farías, D. Carrillo, J. L. Enríquez, A. Burrola, and P. Mani, "Sputtering power effects on the electrochromic properties of NiO films," Optik - International Journal for Light and Electron Optics, vol. 231, pp. 166509-166524, 2021.

P. Li, S. Dai, D. Dai, Z. Zou, R. Wang, P. Zhu, K. Liang, F. Ge, and F. Huang, "Influence of the microstructure of sputtered Ti films on the anodization toward TiO2 nanotube arrays, " Chemical Physics Letters, vol. 826, p. 140675. 2023

D.-J. Won, C.-H. Wang, H.-K. Jang, and D.-J. Choi, "Effects of thermally induced anatase-to-rutile phase transition in MOCVD-grown TiO2 films on structural and optical properties," Applied Physics A, vol. 73, pp. 595-600, 2001.

K. M. Reddy, S. V. Manorama. and A. R. Reddy, "Bandgap studies on anatase titanium dioxide nanoparticles,"Materials Chemistry and Physics, vol. 3, pp. 239-245, 2003.

Z. Tong, J. Hao, K. Zhang, J. Zhao, B.-L. Suc, and Y. Li, "Improved electrochromic performance and lithium diffusion coefficient in three-dimensionally ordered macroporous V2O5 films," Journal of Materials Chemistry C , vol. 2, pp. 3651-3658, 2014.

J. Z. Ou, S. Balendhran, M. R. Field, D. G. McCulloch, A. S. Zoolfakar, R. A. Rani, S. Zhuiykov, A. P. O'Mullane, and K. Kalantar-zadeh, "The anodized crystalline WO3 nanoporous network with enhanced electrochromic properties," Nanoscale, vol. 4, no. 19, pp. 5980-5988, 2012.