Fabrication and characterization of Sb-doped MXene prepared by hydrothermal method for use as a sensing electrode for heavy metal detection
DOI:
https://doi.org/10.55713/jmmm.v34i2.2008คำสำคัญ:
Antimony, Electrochemical sensor, Heavy metal detection, Hydrothermal, MXeneบทคัดย่อ
MXene, a two-dimensional material with favorable physicochemical characteristics, has demonstrated outstanding efficiency in a wide range of applications because of their superior properties, such as higher surface area and conductivity, and facile surface modification. In this study, antimony (Sb) doped MXenes were synthesized via a simple hydrothermal method, employing various Sb concentrations ranging from 5%w/w to 25%w/w. The successful preparation of the Sb-doped MXene (Sb@MXene) was confirmed by an X-ray diffraction (XRD) method. Physical morphologies examined through field-emission scanning electron microscopy (FE-SEM) depict the presence of Sb nanoparticles with the size of about 80 nm on the surface and interlayer of MXenes. The Sb@MXene composites demonstrated significant potential as electrochemical sensing materials for heavy metal detection. Both 5%Sb@MXene and 25%Sb@MXene composites were prepared as the screen-printed electrode (SPE) materials via drop-casting method to sense Pb2+, Cd2+, and Zn2+. The 25%Sb@MXene SPE show the highest sensitivity toward Pb2+(3.62 μA∙ppm‒1), Cd2+(2.53 μA∙ppm‒1), and Zn2+ (0.90 μA∙ppm‒1) solution, compared with that of 5%Sb@MXene SPE. This work not only demonstrates a simple preparation of Sb@MXene, but also applies the hybrid materials in electrochemical sensing application.
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R. Wang, W. Young Jang, W. Zhang, C. Venkata Reddy, R. R. Kakarla, C. Li, V. K. Gupta, J. Shim, and T. M. Aminabhavi, "Emerging two-dimensional (2D) MXene-based nanostructured materials: Synthesis strategies, properties, and applications as efficient pseudo-supercapacitors," Chemical Engineering Journal, vol. 472, p. 144913, 2023. DOI: https://doi.org/10.1016/j.cej.2023.144913
M. Naguib, M. W. Barsoum, and Y. Gogotsi, "Ten years of progress in the synthesis and development of MXenes," Advanced Materials, vol. 33, no. 39, p. 2103393, 2021. DOI: https://doi.org/10.1002/adma.202103393
D. Ayodhya, "A review of recent progress in 2D MXenes: Synthesis, properties, and applications," Diamond and Related Materials, vol. 132, p. 109634, 2023. DOI: https://doi.org/10.1016/j.diamond.2022.109634
M. P. Bilibana, "Electrochemical properties of MXenes and applications," Advanced Sensor and Energy Materials, vol. 2, no. 4, p. 100080, 2023. DOI: https://doi.org/10.1016/j.asems.2023.100080
P. Chakraborty, T. Das, and T. Saha-Dasgupta, "1.15 - MXene: A new trend in 2D materials science," in Comprehensive Nano-science and Nanotechnology (Second Edition), D. L. Andrews, R. H. Lipson, and T. Nann Eds. Oxford: Academic Press, 2019, pp. 319-330. DOI: https://doi.org/10.1016/B978-0-12-803581-8.10414-X
A. Sohan, P. Banoth, M. Aleksandrova, A. Grace, and P. Kollu, "Review on MXene synthesis, properties, and recent research exploring electrode architecture for supercapacitor applications," International Journal of Energy Research, vol. 45, 2021. DOI: https://doi.org/10.1002/er.7068
U. Alli, K. McCarthy, I.-A. Baragau, N. P. Power, D. J. Morgan, S. Dunn, S. Killian, T. Kennedy, and S. Kellici, "In-situ continuous hydrothermal synthesis of TiO2 nanoparticles on conductive N-doped MXene nanosheets for binder-free Li-ion battery anodes," Chemical Engineering Journal, vol. 430, p. 132976, 2022. DOI: https://doi.org/10.1016/j.cej.2021.132976
A. Dey, S. Varagnolo, N. P. Power, N. Vangapally, Y. Elias, L. Damptey, B. N. Jaato, S. Gopalan, Z. Golrokhi, P. Sonar, V. Selvaraj, D. Aurbach, and S. Krishnamurthy, "Doped MXenes— A new paradigm in 2D systems: Synthesis, properties and applications," Progress in Materials Science, vol. 139, p. 101166, 2023. DOI: https://doi.org/10.1016/j.pmatsci.2023.101166
G. Qu, Y. Zhou, T. Wu, G. Zhao, F. Li, Y. Kang, and C. Xu, "Phosphorized MXene-phase molybdenum carbide as an earth-abundant hydrogen evolution electrocatalyst," ACS Applied Energy Materials, vol. 1, no. 12, pp. 7206-7212, 2018. DOI: https://doi.org/10.1021/acsaem.8b01642
V. Thirumal, R. Yuvakkumar, P. S. Kumar, S. P. Keerthana, G. Ravi, M. Thambidurai, C. Dang, and D. Velauthapillai, "Facile hydrothermal synthesis of MXene@antimony nanoneedle composites for toxic pollutants removal," Environmental Research, vol. 210, p. 112904, 2022. DOI: https://doi.org/10.1016/j.envres.2022.112904
S. Arnold, A. Gentile, Y. Li, Q. Wang, S. Marchionna, R. Ruffo, and V. Presser, "Design of high-performance antimony/ MXene hybrid electrodes for sodium-ion batteries," Journal of Materials Chemistry A, vol. 10, no. 19, pp. 10569-10585, 2022. DOI: https://doi.org/10.1039/D2TA00542E
M. Alhabeb, K. Maleski, B. Anasori, P. Lelyukh, L. Clark, S. Sin, and Y. Gogotsi, "Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene)," Chemistry of Materials, vol. 29, no. 18, pp. 7633-7644, 2017. DOI: https://doi.org/10.1021/acs.chemmater.7b02847
Y. Guo, S. Jin, L. Wang, P. He, Q. Hu, L.-Z. Fan, and A. Zhou, "Synthesis of two-dimensional carbide Mo2CTx MXene by hydro-thermal etching with fluorides and its thermal stability," Ceramics International, vol. 46, no. 11, Part B, pp. 19550-19556, 2020. DOI: https://doi.org/10.1016/j.ceramint.2020.05.008
D. Mohanadas, R. Rohani, Y. Sulaiman, S. A. Bakar, E. Mahmoudi, and L.-C. Zhang, "Heavy metal detection in water using MXene and its composites: A review," Materials Today Sustainability, vol. 22, p. 100411, 2023. DOI: https://doi.org/10.1016/j.mtsust.2023.100411
E. Punrat, N. Piyasart, C. Auanphui, R. Thaipratum, S. Motomizu, and W. Wonsawat, "Sequential injection analysis for mercury ion with modified screen – printed carbon electrode," Journal of Metals, Materials and Minerals, vol. 32, no. 3, pp. 101-107, 2022. DOI: https://doi.org/10.55713/jmmm.v32i3.1522
P. Preechaburana, S. Sangnuy, and S. Amloy, "Paper-based colorimetric sensor for mercury ion detection using smartphone digital imaging," Journal of Metals, Materials and Minerals, vol. 33, no. 2, pp. 81-87, 2023. DOI: https://doi.org/10.55713/jmmm.v33i2.1653
E. Tesarova, L. Baldrianova, S. B. Hocevar, I. Svancara, K. Vytras, and B. Ogorevc, "Anodic stripping voltammetric measurement of trace heavy metals at antimony film carbon paste electrode," Electrochimica Acta, vol. 54, no. 5, pp. 1506-1510, 2009. DOI: https://doi.org/10.1016/j.electacta.2008.09.030
E. A. Shalaby, A. M. Beltagi, A. A. Hathoot, and M. A. Azzem, "Simultaneous voltammetric sensing of Zn2+, Cd2+, and Pb2+ using an electrodeposited Bi–Sb nanocomposite modified carbon paste electrode," RSC Advances, vol. 13, no. 11, pp. 7118-7128, 2023. DOI: https://doi.org/10.1039/D3RA00168G
Y. He, L. Ma, L. Zhou, G. Liu, Y. Jiang, and J. Gao, "Preparation and application of bismuth/MXene nano-composite as electro-chemical sensor for heavy metal ions detection," Nanomaterials, vol. 10, no. 5, p. 866, 2020. DOI: https://doi.org/10.3390/nano10050866
M. Naguib, O. Mashtalir, J. Carle, V. Presser, J. Lu, L. Hultman, Y. Gogotsi, and M. W. Barsoum, "Two-dimensional transition metal carbides," ACS Nano, vol. 6, no. 2, pp. 1322-1331, 2012. DOI: https://doi.org/10.1021/nn204153h
M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L. Hultman, Y. Gogotsi, and M. W. Barsoum, "Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2," Advanced Materials, vol. 23, no. 37, pp. 4248-4253, 2011. DOI: https://doi.org/10.1002/adma.201102306
R. Azadvari, S. Mohammadi, A. Habibi, S. Ahmadi, and Z. Sanaee, "Effect of ultra-sonication, vacuum drying, and carbon coating on the super-capacitive behavior of Ti3C2Tx MXene," Journal of Physics D: Applied Physics, vol. 57, no. 4, p. 045501, 2024. DOI: https://doi.org/10.1088/1361-6463/ad056c
W. Luo, S. Lorger, B. Wang, C. Bommier, and X. Ji, "Facile synthesis of one-dimensional peapod-like Sb@C submicron-structures," Chemical Communications, vol. 50, no. 41, pp. 5435-5437, 2014. DOI: https://doi.org/10.1039/c4cc01326c
H. Yin, H. Tang, D. Wang, Y. Gao, and Z. Tang, "Facile synthesis of surfactant-free au cluster/graphene hybrids for high-performance oxygen reduction reaction," ACS Nano, vol. 6, no. 9, pp. 8288-8297, 2012. DOI: https://doi.org/10.1021/nn302984x
X. Guo, H. Gao, S. Wang, G. Yang, X. Zhang, J. Zhang, H. Liu, and G. Wang, "MXene-based aerogel anchored with antimony single atoms and quantum dots for high-performance potassium-ion batteries," Nano Letters, vol. 22, no. 3, pp. 1225-1232, 2022. DOI: https://doi.org/10.1021/acs.nanolett.1c04389
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